Atomic Energy (Canada)

Kinetic data for the radicals H⋅ and ⋅OH in aqueous solution,and the corresponding radical anions, ⋅O− and eaq−, have been critically pulse radiolysis, flash photolysis and other methods. Rate constants for over 3500 reaction are tabulated, including reaction with molecules, ions and other radicals derived from inorganic and organic solutes.

Abstract Relations between the elastic and plastic properties of pure polycrystalline metals are discussed and a systematic relation between shear modulus, Burgers vector and plastic shear strength of metals possessing the same lattice structure is proposed. In addition reasons are given for believing that in a limited temperature range malleability is related to Poisson's ratio.

Abstract The application of thermal neutron scattering to the study of the structure and dynamics of condensed matter requires a knowledge of the scattering lengths and the corresponding scattering and absorption cross sections of the elements. Ln some cases, values for the individual isotopes are needed as well. This information is required to obtain an absolute normalization ofthe scatteredneutron distributions, tocalculate unit-cell structure factors in neutron crystallography, and to correct for effects such as absorption, self-shielding, extinction, multiple scattering, incoherent scattering, and detector efficiency.

Observations of neutral-current $\ensuremath{\nu}$ interactions on deuterium in the Sudbury Neutrino Observatory are reported. Using the neutral current (NC), elastic scattering, and charged current reactions and assuming the standard ${}^{8}\mathrm{B}$ shape, the ${\ensuremath{\nu}}_{e}$ component of the ${}^{8}\mathrm{B}$ solar flux is ${\ensuremath{\varphi}}_{e}{\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}1.76}_{\ensuremath{-}0.05}^{+0.05}(\mathrm{stat}{)}_{\ensuremath{-}0.09}^{+0.09}(\mathrm{syst})\ifmmode\times\else\texttimes\fi{}{10}^{6}\phantom{\rule{0ex}{0ex}}{\mathrm{cm}}^{\ensuremath{-}2}{\mathrm{s}}^{\ensuremath{-}1}$ for a kinetic energy threshold of 5 MeV. The non- ${\ensuremath{\nu}}_{e}$ component is ${\ensuremath{\varphi}}_{\ensuremath{\mu}\ensuremath{\tau}}{\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}3.41}_{\ensuremath{-}0.45}^{+0.45}(\mathrm{stat}{)}_{\ensuremath{-}0.45}^{+0.48}(\mathrm{syst})\ifmmode\times\else\texttimes\fi{}{10}^{6}\phantom{\rule{0ex}{0ex}}{\mathrm{cm}}^{\ensuremath{-}2}{\mathrm{s}}^{\ensuremath{-}1}$, $5.3\ensuremath{\sigma}$ greater than zero, providing strong evidence for solar ${\ensuremath{\nu}}_{e}$ flavor transformation. The total flux measured with the NC reaction is ${\ensuremath{\varphi}}_{\mathrm{NC}}{\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}5.09}_{\ensuremath{-}0.43}^{+0.44}(\mathrm{stat}{)}_{\ensuremath{-}0.43}^{+0.46}(\mathrm{syst})\ifmmode\times\else\texttimes\fi{}{10}^{6}\phantom{\rule{0ex}{0ex}}{\mathrm{cm}}^{\ensuremath{-}2}{\mathrm{s}}^{\ensuremath{-}1}$, consistent with solar models.

Abstract Below 1000°C the oxidation of nickel cannot be controlled by the diffusion of ions through the bulk crystal lattice of the pure oxide, because the measured oxidation rates are several orders of magnitude faster than would be predicted on this basis. Short-circuit diffusion through oxide grain boundaries or dislocations has usually been held responsible, but there has hitherto been no proper quantitative confirmation of this mechanism. We report measurements of the oxide scale thickness and oxide grain size as a function of time during the oxidation of high-purity nickel in the temperature range 500–800°C. All the oxidation experiments were carried out in pure oxygen at a pressure of one atmosphere. The measured parabolic oxidation rate constants have been compared with those calculated from grain boundary diffusion data obtained in our previous work, using a grain boundary diffusion model for the oxidation process. The quantitative agreement between measured and calculated oxidation rates shows convincingly that the diffusion of nickel along oxide grain boundaries controls the oxidation of nickel in these experiments. Oxidation data in the literature can also be accounted for with this model.

Abstract A unified field theory of mesons and their particle sources is proposed and considered in its classical aspects. The theory has static solutions of a singular nature, but finite energy,characterized by spin directions; the number of such entities is a rigorously conserved constant of motion; they interact with an external meson field through a derivative-type coupling with the spins, akin to the formalism of strong-coupling meson theory. There is a conserved current identifiable with isobaric spin, and another that may be related to hyper-charge. The postulates include one constant of the dimensions of length, and another that is conjectured necessarily to have the value ђc, or perhaps ½ђc, in the quantized theory.

Abstract A more accurate solution of the model (of an 8-band of interacting electrons) discussed in paper I is obtained. The new solution predicts a finite lifetime for the pseudo-particles and also the ‘Mott’ insulator-conductor transition. A physical interpretation of the theory based upon an analogy with the theory of alloys is given, and a special case in which the predictions of the theory can be worked out in some detail is studied.

Solar neutrinos from ${}^{8}\mathrm{B}$ decay have been detected at the Sudbury Neutrino Observatory via the charged current (CC) reaction on deuterium and the elastic scattering (ES) of electrons. The flux of ${\ensuremath{\nu}}_{e}$'s is measured by the CC reaction rate to be ${\ensuremath{\varphi}}^{\mathrm{CC}}({\ensuremath{\nu}}_{e})\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}1.75\ifmmode\pm\else\textpm\fi{}0.07(\mathrm{stat}{)}_{\ensuremath{-}0.11}^{+0.12}(\mathrm{syst})\ifmmode\pm\else\textpm\fi{}0.05(\mathrm{theor})\ifmmode\times\else\texttimes\fi{}{10}^{6}{\mathrm{cm}}^{\ensuremath{-}2}{\mathrm{s}}^{\ensuremath{-}1}$. Comparison of ${\ensuremath{\varphi}}^{\mathrm{CC}}({\ensuremath{\nu}}_{e})$ to the Super-Kamiokande Collaboration's precision value of the flux inferred from the ES reaction yields a $3.3\ensuremath{\sigma}$ difference, assuming the systematic uncertainties are normally distributed, providing evidence of an active non- ${\ensuremath{\nu}}_{e}$ component in the solar flux. The total flux of active ${}^{8}\mathrm{B}$ neutrinos is determined to be $5.44\ifmmode\pm\else\textpm\fi{}0.99\ifmmode\times\else\texttimes\fi{}{10}^{6}{\mathrm{cm}}^{\ensuremath{-}2}{\mathrm{s}}^{\ensuremath{-}1}$.

A least-mean-square (LMS) adaptive filter with a variable step size is introduced. The step size increases or decreases as the mean-square error increases or decreases, allowing the adaptive filter to track changes in the system as well as produce a small steady state error. The convergence and steady-state behavior of the algorithm are analyzed. The results reduce to well-known results when specialized to the constant-step-size case. Simulation results are presented to support the analysis and to compare the performance of the algorithm with the usual LMS algorithm and another variable-step-size algorithm. They show that its performance compares favorably with these existing algorithms.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">&gt;</ETX>

Journal Article The Chemical Basis of Heredity Get access The Chemical Basis of Heredity . Edited by McElroy William D. Glass Bentley . 848 pgs., illus. The Johns Hopkins Press , Baltimore, Md . ( 1957 ) $12.50 H. B. Newcombe H. B. Newcombe Atomic Energy of Canada , Chalk River , Canada . Search for other works by this author on: Oxford Academic Google Scholar AIBS Bulletin, Volume 7, Issue 5, November 1957, Page 55, https://doi.org/10.2307/1292482 Published: 01 November 1957

This paper contains a critical evaluation of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in middle atmosphere chemistry (10–55 km altitude). The work has been carried out by the authors under the auspices of the CODATA Task Group on Chemical Kinetics. Data sheets have been prepared for 148 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each reaction a preferred value of the rate coefficient at 298 K is given together with a temperature dependency where possible. The selection of the preferred value is discussed, and estimates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction. The data sheets are intended to provide the basic physical chemical data needed as input for calculations which model atmospheric chemistry. A table summarizing the preferred rate data is provided, together with an Appendix listing the available data on enthalpies of formation of the reactant and product species.

Abstract To understand how collective motion can develop in the shell-model framework it is necessary to study configuration interaction. With this in mind, group-theoretical methods are used to investigate the possible classification schemes for a number of nucleons in m xed configurations. One particular coupling scheme, which is associated with the degeneracy of a harmonic oscillator potential and which, in a following paper, will be shown to have collective properties is described in detail. The wave functions in this scheme are seen to be very similar to those resulting from an actual shell-model calculation with configurational mixing.

The Sudbury Neutrino Observatory (SNO) has measured day and night solar neutrino energy spectra and rates. For charged current events, assuming an undistorted ${}^{8}\mathrm{B}$ spectrum, the night minus day rate is $14.0%\ifmmode\pm\else\textpm\fi{}6.3{%}_{\ensuremath{-}1.4}^{+1.5}%$ of the average rate. If the total flux of active neutrinos is additionally constrained to have no asymmetry, the ${\ensuremath{\nu}}_{e}$ asymmetry is found to be $7.0%\ifmmode\pm\else\textpm\fi{}4.9{%}_{\ensuremath{-}1.2}^{+1.3}%$. A global solar neutrino analysis in terms of matter-enhanced oscillations of two active flavors strongly favors the large mixing angle solution.

Abstract The effect of combined hydrostatic pressure, P, and of uniaxial tension, [sgrave], on the rupture time of polycrystalline copper wire in the temperature range 400° to 500°c has been determined. All the specimens broke by intergranular fracture, due to the growth of voids along grain boundaries. Preliminary experiments indicated that the voids grow by the addition of vacancies under the action of the applied stress. A theory has been developed assuming that failure results from the growth of void nuclei on the grain boundary, which requires that the activation energy for failure is that of grain boundary diffusion and that the rupture time, tr, depends only on ([sgrave]-P). The experiments show that the activation energy is close to the expected value, and provided that [sgrave] is constant tr agrees with theory. Changes in [sgrave], when ([sgrave] - P) is constant, affect tr appreciably, and the results suggest that many of the void nuclei are stress induced.

Abstract The theory developed in a previous paper is applied to calculate the correlation energy of a free-electron gas. The theory involves no cut-off and gives a uniform description of collective motion effects in the long-range limit and of particle motion effects in the short-range limit. It is shown that in the lowest order the theory agrees with Bohm &amp; Pines’s plasma oscillation theory in the long-range limit, but is inadequate in the short-range limit. The theory is approximately evaluated to the next order, which is correct in the short-range limit, and is applied to calculate the correlation energy at several gas densities; the results are in good agreement with those of Bohm &amp; Pines.

Abstract A new method is described for setting up the effective potential for electrons in non-transition metals, including liquid metals and alloys. It is based on a model potential fitted to the spectroscopically measured energy levels of the free ions. The potential between the atomic cores is obtained from the dielectric screening calculation of Cohen and Phillips (1961) with some refinements. The method is tested on the band structures of the (solid) alkali metals. The Fermi surfaces of K, Rb and Cs are found to be considerably less distorted than calculated by Ham (1962), and thus in better agreement with experiment.

Abstract It is shown that there are three components in a mixing process: convection, diffusion and shear. The concepts involved in analysing complete and partial mixtures are examined and a statistically satisfactory expression evolved for the state of a mixture. A number of theories of mixing rate are examined and compared with the few published experimental results, and a new theoretical treatment is offered based on diffusion theory. This is shown to be in at least as good agreement with fact as existing theories, and to provide a better basis for extension to more complex cases.

Abstract The basic ideas of Brueckner's self-consistent nuclear model are applied in a simplified, approximate form to the case of a finite nucleus. It is shown that it is possible to reconcile the observed values of surface energy and surface thickness, to explain the greater extension of the nuclear potential compared with the charge distribution, and also to fit the well-depth of the optical model for nucleon scattering.

Abstract Formulae are obtained for the concentration in a poorly diffusing half space bisected by a thin well-diffusing slab, at different times after the edge of the half-space has been suddenly raised from zero to unit concentration. This represents a simplified model for studying 'grain boundary' diffusion of one metal into another. The problem also has obvious application to the study of heat flow in a poorly conducting solid with a metallic fin.

Cardis, E., Vrijheid, M., Blettner, M., Gilbert, E., Hakama, M., Hill, C., Howe, G., Kaldor, J., Muirhead, C. R., Schubauer-Berigan, M., Yoshimura, T., Bermann, F., Cowper, G., Fix, J., Hacker, C., Heinmiller, B., Marshall, M., Thierry-Chef, I., Utterback, D., Ahn, Y-O., Amoros, E., Ashmore, P., Auvinen, A., Bae, J-M., Bernar, J. S., Biau, A., Combalot, E., Deboodt, P., Diez Sacristan, A., Eklöf, M., Engels, H., Engholm, G., Gulis, G., Habib, R. R., Holan, K., Hyvonen, H., Kerekes, A., Kurtinaitis, J., Malker, H., Martuzzi, M., Mastauskas, A., Monnet, A., Moser, M., Pearce, M. S., Richardson, D. B., Rodriguez-Artalejo, F., Rogel, A., Tardy, H., Telle-Lamberton, M., Turai, I., Usel, M. and Veress, K. The 15-Country Collaborative Study of Cancer Risk among Radiation Workers in the Nuclear Industry: Estimates of Radiation-Related Cancer Risks. Radiat. Res. 167, 396– 416 (2007).A 15-Country collaborative cohort study was conducted to provide direct estimates of cancer risk following protracted low doses of ionizing radiation. Analyses included 407,391 nuclear industry workers monitored individually for external radiation and 5.2 million person-years of follow-up. A significant association was seen between radiation dose and all-cause mortality [excess relative risk (ERR) 0.42 per Sv, 90% CI 0.07, 0.79; 18,993 deaths]. This was mainly attributable to a dose-related increase in all cancer mortality (ERR/Sv 0.97, 90% CI 0.28, 1.77; 5233 deaths). Among 31 specific types of malignancies studied, a significant association was found for lung cancer (ERR/Sv 1.86, 90% CI 0.49, 3.63; 1457 deaths) and a borderline significant (P = 0.06) association for multiple myeloma (ERR/Sv 6.15, 90% CI <0, 20.6; 83 deaths) and ill-defined and secondary cancers (ERR/Sv 1.96, 90% CI −0.26, 5.90; 328 deaths). Stratification on duration of employment had a large effect on the ERR/Sv, reflecting a strong healthy worker survivor effect in these cohorts. This is the largest analytical epidemiological study of the effects of low-dose protracted exposures to ionizing radiation to date. Further studies will be important to better assess the role of tobacco and other occupational exposures in our risk estimates.