GNS Science
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Research output, citation impact, and the most-cited recent papers from GNS Science (New Zealand). Aggregated across the NobleBlocks index of 300M+ scholarly works.
Top-cited papers from GNS Science
The phase relationships contained in the magnetotelluric (MT) impedance tensor are shown to be a second-rank tensor. This tensor expresses how the phase relationships change with polarization in the general case where the conductivity structure is 3-D. Where galvanic effects produced by heterogeneities in near-surface conductivity distort the regional MT response the phase tensor preserves the regional phase information. Calculation of the phase tensor requires no assumption about the dimensionality of the underlying conductivity distribution and is applicable where both the heterogeneity and regional structure are 3-D.\nFor 1-D regional conductivity structures, the phase tensor is characterized by a single coordinate invariant phase equal to the 1-D impedance tensor phase. If the regional conductivity structure is 2- D, the phase tensor is symmetric with one of its principal axes aligned parallel to the strike axis of the regional structure. In the 2- D case, the principal values (coordinate invariants) of the phase tensor are the transverse electric and magnetic polarization phases. The orientation of the phase tensor's principal axes can be determined directly from the impedance tensor components in both 2-D and 3-D situations. In the 3-D case, the phase tensor is nonsymmetric and has a third coordinate invariant that is a distortion-free measure of the asymmetry of the regional MT response. The phase tensor can be depicted graphically as an ellipse, the major and minor axes representing the principal axes of the tensor. 3-D model studies show that the orientations of the phase tensor principal axes reflect lateral variations (gradients) in the underlying regional conductivity structure. Maps of the phase tensor ellipses provide a method of visualizing this variation.
The inverse problem of three‐dimensional (3‐D) local earthquake tomography is formulated as a linear approximation to a nonlinear function. Thus the solutions obtained and the reliability estimates depend on the initial reference model. Inappropriate models may result in artifacts of significant amplitude. Here, we advocate the application of the same inversion formalism to determine hypocenters and one‐dimensional (1‐D) velocity model parameters, including station corrections, as the first step in the 3‐D modeling process. We call the resulting velocity model the minimum 1‐D model. For test purposes, a synthetic data set based on the velocity structure of the San Andreas fault zone in central California was constructed. Two sets of 3‐D tomographic P velocity results were calculated with identical travel time data and identical inversion parameters. One used an initial 1‐D model selected from a priori knowledge of average crustal velocities, and the other used the minimum 1‐D model. Where the data well resolve the structure, the 3‐D image obtained with the minimum 1‐D model is much closer to the true model than the one obtained with the a priori reference model. In zones of poor resolution, there are fewer artifacts in the 3‐D image based on the minimum 1‐D model. Although major characteristics of the 3‐D velocity structure are present in both images, proper interpretation of the results obtained with the a priori 1‐D model is seriously compromised by artifacts that distort the image and that go undetected by either resolution or covariance diagnostics.
With regard to their utility in predicting the adoption of household hazard preparations, traditional approaches to public education directed at increasing awareness and/or risk perception have proven ineffective. Discusses reasons why this may have occurred from public education, vulnerability analysis, and community resilience perspectives and outlines strategies for enhancing preparedness. Describes a model of resilience to hazard effects that has been tested in different communities and for different hazards (toxic waste, environmental degradation and volcanic hazards). Drawing upon the health education literature, introduces a model for promoting the adoption on preparatory behaviour. Discusses links between these models, and the need for their implementation within a community development framework.
A spectral acceleration attenuation model for Japan is presented in the present study. The data set includes a very large number of strong ground-motion records up to the 2003 Off Tokach main and aftershocks. Site class terms, instead of individual site correction terms, are used. The site classes of recording stations are from a recent study on site classification for strong-motion recording stations in Japan according to a classification scheme that has been used in Japanese engineering design. The use of site class terms enables tectonic source-type effects to be identified and accounted for in the present model. The effects of a faulting mechanism for crustal earthquakes also are accounted for. For crustal and interface earthquakes, a simple form of an attenuation model (with respect to distance) is able to capture the main strong-motion characteristics and achieves unbiased estimates. For subduction slab events, a simple distance modification factor is employed to achieve plausible and unbiased predictions. The effects of source depth, tectonic source type, and faulting mechanism of crustal earthquakes are significant. The need for magnitude- squared terms is evaluated, and the use of magnitude-squared terms reduces the interevent error further.
The GPS velocity field in the North Island of New Zealand is dominated by the long‐term tectonic rotation of the eastern North Island and elastic strain from stress buildup on the subduction zone thrust fault. We simultaneously invert GPS velocities, earthquake slip vectors, and geological fault slip rates in the North Island for the angular velocities of elastic crustal blocks and the spatially variable degree of coupling on faults separating the blocks. This approach allows us to estimate the distribution of interseismic coupling on the subduction zone interface beneath the North Island and the kinematics of the tectonic block rotations. In agreement with previous studies we find that the subduction zone interface beneath the southern North Island has a high slip rate deficit during the interseismic period, and the slip rate deficit decreases northward along the margin. Much of the North Island is rotating as several, distinct tectonic blocks (clockwise at 0.5–3.8 deg Myr −1 ) about nearby axes relative to the Australian Plate. This rotation accommodates much of the margin‐parallel component of motion between the Pacific and Australian plates. On the basis of our estimation of the block kinematics we suggest that rotation of the eastern North Island occurs because of the southward increasing thickness of the subducting Hikurangi Plateau. These results have implications for our understanding of convergent margin plate boundary zones around the world, particularly with regard to our knowledge of mechanisms for rapid tectonic block rotations at convergent margins and the role of block rotations in the slip partitioning process.
Recent physiological and ecological studies have challenged the long-held belief that microbial metabolism of molecular hydrogen (H2) is a niche process. To gain a broader insight into the importance of microbial H2 metabolism, we comprehensively surveyed the genomic and metagenomic distribution of hydrogenases, the reversible enzymes that catalyse the oxidation and evolution of H2. The protein sequences of 3286 non-redundant putative hydrogenases were curated from publicly available databases. These metalloenzymes were classified into multiple groups based on (1) amino acid sequence phylogeny, (2) metal-binding motifs, (3) predicted genetic organisation and (4) reported biochemical characteristics. Four groups (22 subgroups) of [NiFe]-hydrogenase, three groups (6 subtypes) of [FeFe]-hydrogenases and a small group of [Fe]-hydrogenases were identified. We predict that this hydrogenase diversity supports H2-based respiration, fermentation and carbon fixation processes in both oxic and anoxic environments, in addition to various H2-sensing, electron-bifurcation and energy-conversion mechanisms. Hydrogenase-encoding genes were identified in 51 bacterial and archaeal phyla, suggesting strong pressure for both vertical and lateral acquisition. Furthermore, hydrogenase genes could be recovered from diverse terrestrial, aquatic and host-associated metagenomes in varying proportions, indicating a broad ecological distribution and utilisation. Oxygen content (pO2) appears to be a central factor driving the phylum- and ecosystem-level distribution of these genes. In addition to compounding evidence that H2 was the first electron donor for life, our analysis suggests that the great diversification of hydrogenases has enabled H2 metabolism to sustain the growth or survival of microorganisms in a wide range of ecosystems to the present day. This work also provides a comprehensive expanded system for classifying hydrogenases and identifies new prospects for investigating H2 metabolism.
Abstract Fine‐grained sediment is a natural and essential component of river systems and plays a major role in the hydrological, geomorphological and ecological functioning of rivers. In many areas of the world, the level of anthropogenic activity is such that fine‐grained sediment fluxes have been, or are being, modified at a magnitude and rate that cause profound, and sometimes irreversible, changes in the way that river systems function. This paper examines how anthropogenic activity has caused significant changes in the quantity and quality of fine‐grained sediment within river systems, using examples of: land use change in New Zealand; the effects of reservoir construction and management in different countries; the interaction between sediment dynamics and fish habitats in British Columbia, Canada; and the management of contaminated sediment in USA rivers. The paper also evaluates present programmes and initiatives for the management of fine sediment in river systems and suggests changes that are needed if management strategies are to be effective and sustainable. Copyright © 2005 John Wiley & Sons, Ltd.
A global Earth Magnetic Anomaly Grid (EMAG2) has been compiled from satellite, ship, and airborne magnetic measurements. EMAG2 is a significant update of our previous candidate grid for the World Digital Magnetic Anomaly Map. The resolution has been improved from 3 arc min to 2 arc min, and the altitude has been reduced from 5 km to 4 km above the geoid. Additional grid and track line data have been included, both over land and the oceans. Wherever available, the original shipborne and airborne data were used instead of precompiled oceanic magnetic grids. Interpolation between sparse track lines in the oceans was improved by directional gridding and extrapolation, based on an oceanic crustal age model. The longest wavelengths (>330 km) were replaced with the latest CHAMP satellite magnetic field model MF6. EMAG2 is available at http://geomag.org/models/EMAG2 and for permanent archive at http://earthref.org/cgi-bin/er.cgi?s=erda.cgi?n=970 .
) 7.8 earthquake. Field observations, in conjunction with interferometric synthetic aperture radar, Global Positioning System, and seismology data, reveal this to be one of the most complex earthquakes ever recorded. The rupture propagated northward for more than 170 kilometers along both mapped and unmapped faults before continuing offshore at the island's northeastern extent. Geodetic and field observations reveal surface ruptures along at least 12 major faults, including possible slip along the southern Hikurangi subduction interface; extensive uplift along much of the coastline; and widespread anelastic deformation, including the ~8-meter uplift of a fault-bounded block. This complex earthquake defies many conventional assumptions about the degree to which earthquake ruptures are controlled by fault segmentation and should motivate reevaluation of these issues in seismic hazard models.
Understanding how people interpret risks and choose actions based on their interpretations is vital to any strategy for disaster reduction. We review relevant literature with the aim of developing a conceptual framework to guide future research in this area. We stress that risks in the context of natural hazards always involve interactions between natural (physical) and human (behavioural) factors. Decision-making under conditions of uncertainty is inadequately described by traditional models of 'rational choice'. Instead, attention needs to be paid to how people's interpretations of risks are shaped by their own experience, personal feelings and values, cultural beliefs and interpersonal and societal dynamics. Furthermore, access to information and capacity for self-protection are typically distributed unevenly within populations. Hence trust is a critical moderator of the effectiveness of any policy for risk communication and public engagement.
The discovery of metal-depositing hot springs on the sea floor, and especially their link to chemosynthetic life, was among the most compelling and significant scientific advances of the twentieth century. More than 300 sites of hydrothermal activity and sea-floor mineralization are known on the ocean floor. About 100 of these are sites of high-temperature venting and polymetallic sulfide deposits. They occur at mid-ocean ridges (65%), in back-arc basins (22%), and on submarine volcanic arcs (12%). Although high-temperature, 350°C, black smoker vents are the most recognizable features of sea-floor hydrothermal activity, a wide range of different styles of mineralization has been found. Different volcanic substrates, including mid-ocean ridge basalt, ultramafic intrusive rocks, and more evolved volcanic suites in both oceanic and continental crust, as well as temperature-dependent solubility controls, account for the main geochemical associations found in the deposits. Although end-member hydrothermal fluids mainly originate in the deep volcanic basement, the presence of sediments and other substrates can have a large effect on the compositions of the vent fluids. In arc and backarc settings, vent fluid compositions are broadly similar to those at mid-ocean ridges, but the arc magmas also supply a number of components to the hydrothermal fluids. \nThe majority of known black smoker vents occur on fast-spreading mid-ocean ridges, but the largest massive sulfide deposits are located at intermediate- and slow-spreading centers, at ridge-axis volcanoes, in deep backarc basins, and in sedimented rifts adjacent to continental margins. The range of deposit sizes in these settings is similar to that of ancient volcanic-associated massive sulfide (VMS) deposits. Detailed mapping, and in some cases drilling, indicates that a number of deposits contain 1 to 5 million tons (Mt) of massive sulfide (e.g., TAG hydrothermal field on the Mid-Atlantic Ridge, deposits of the Galapagos Rift, and at 13°N on the East Pacific Rise). Two sediment-hosted deposits, at Middle Valley on the Juan de Fuca Ridge and in the Atlantis II Deep of the Red Sea, are much larger (up to 15 and 90 Mt, respectively). \nIn the western Pacific, high-temperature hydrothermal systems occur mainly at intraoceanic back-arc spreading centers (e.g., Lau basin, North Fiji basin, Mariana trough) and in arc-related rifts at continental margins (e.g., Okinawa trough). In contrast to the mid-ocean ridges, convergent margin settings are characterized by a range of different crustal thicknesses and compositions, variable heat flow regimes, and diverse magma types. These variations result in major differences in the compositions and isotopic systematics of the hydrothermal fluids and the mineralogy and bulk compositions of the associated mineral deposits. Intraoceanic back-arc basin spreading centers host black smoker vents that, for the most part, are very similar to those on the mid-ocean ridges. However, isotopic data from both the volcanic rocks and the sulfide deposits highlight the importance of subduction recycling in the origin of the magmas and hydrothermal fluids. Back-arc rifts in continental margin settings are typically sediment-filled basins, which derive their sediment load from the adjacent continental shelf. This has an insulating effect that enhances the high heat flow associated with rifting of the continental crust and also helps to preserve the contained sulfide deposits. Large hydrothermal systems have developed where initial rifting of continental crust or locally thickened arc crust has formed large calderalike sea-floor depressions, similar to those that contained major VMS-forming systems in the geologic record. Hydrothermal vents also occur in the summit calderas of submarine volcanoes at the volcanic fronts of arcs. However, this contrasts with the interpreted settings of most ancient VMS deposits, which are considered to have formed mainly during arc rifting. Hydrothermal vents associated with arc volcanoes show clear evidence of the direct input of magmatic volatiles, similar to magmatic-hydrothermal systems in subaerial volcanic arcs. Several compelling examples of submarine epithermal-style mineralization, including gold-base metal veins, have been found on submarine arc volcanoes,and this type of mineralization may be more common than is presently recognized. \nMapping and sampling of the sea floor has dramatically improved geodynamic models of different submarine volcanic and tectonic settings and has helped to establish a framework for the characterization of many similar ancient terranes. Deposits forming at convergent margins are considered to be the closest analogs of ancient VMS. However, black smokers on the mid-ocean ridges continue to provide critically important information about metal transport and deposition in sea-floor hydrothermal systems of all types. Ongoing sea-floor exploration in other settings is providing clues to the diversity of mineral deposit types that occur in different environments and the conditions that are favorable for their formation.
Reproducible climate reconstructions of the Common Era (1 CE to present) are key to placing industrial-era warming into the context of natural climatic variability. Here we present a community-sourced database of temperature-sensitive proxy records from the PAGES2k initiative. The database gathers 692 records from 648 locations, including all continental regions and major ocean basins. The records are from trees, ice, sediment, corals, speleothems, documentary evidence, and other archives. They range in length from 50 to 2000 years, with a median of 547 years, while temporal resolution ranges from biweekly to centennial. Nearly half of the proxy time series are significantly correlated with HadCRUT4.2 surface temperature over the period 1850-2014. Global temperature composites show a remarkable degree of coherence between high- and low-resolution archives, with broadly similar patterns across archive types, terrestrial versus marine locations, and screening criteria. The database is suited to investigations of global and regional temperature variability over the Common Era, and is shared in the Linked Paleo Data (LiPD) format, including serializations in Matlab, R and Python.
Abstract The International Bathymetric Chart of the Southern Ocean (IBCSO) Version 1.0 is a new digital bathymetric model (DBM) portraying the seafloor of the circum‐Antarctic waters south of 60°S. IBCSO is a regional mapping project of the General Bathymetric Chart of the Oceans (GEBCO). The IBCSO Version 1.0 DBM has been compiled from all available bathymetric data collectively gathered by more than 30 institutions from 15 countries. These data include multibeam and single‐beam echo soundings, digitized depths from nautical charts, regional bathymetric gridded compilations, and predicted bathymetry. Specific gridding techniques were applied to compile the DBM from the bathymetric data of different origin, spatial distribution, resolution, and quality. The IBCSO Version 1.0 DBM has a resolution of 500 × 500 m, based on a polar stereographic projection, and is publicly available together with a digital chart for printing from the project website ( www.ibcso.org ) and at http://dx.doi.org/10.1594/PANGAEA.805736 .
Abstract. Ice flow models of the Antarctic ice sheet are commonly used to simulate its future evolution in response to different climate scenarios and assess the mass loss that would contribute to future sea level rise. However, there is currently no consensus on estimates of the future mass balance of the ice sheet, primarily because of differences in the representation of physical processes, forcings employed and initial states of ice sheet models. This study presents results from ice flow model simulations from 13 international groups focusing on the evolution of the Antarctic ice sheet during the period 2015–2100 as part of the Ice Sheet Model Intercomparison for CMIP6 (ISMIP6). They are forced with outputs from a subset of models from the Coupled Model Intercomparison Project Phase 5 (CMIP5), representative of the spread in climate model results. Simulations of the Antarctic ice sheet contribution to sea level rise in response to increased warming during this period varies between −7.8 and 30.0 cm of sea level equivalent (SLE) under Representative Concentration Pathway (RCP) 8.5 scenario forcing. These numbers are relative to a control experiment with constant climate conditions and should therefore be added to the mass loss contribution under climate conditions similar to present-day conditions over the same period. The simulated evolution of the West Antarctic ice sheet varies widely among models, with an overall mass loss, up to 18.0 cm SLE, in response to changes in oceanic conditions. East Antarctica mass change varies between −6.1 and 8.3 cm SLE in the simulations, with a significant increase in surface mass balance outweighing the increased ice discharge under most RCP 8.5 scenario forcings. The inclusion of ice shelf collapse, here assumed to be caused by large amounts of liquid water ponding at the surface of ice shelves, yields an additional simulated mass loss of 28 mm compared to simulations without ice shelf collapse. The largest sources of uncertainty come from the climate forcing, the ocean-induced melt rates, the calibration of these melt rates based on oceanic conditions taken outside of ice shelf cavities and the ice sheet dynamic response to these oceanic changes. Results under RCP 2.6 scenario based on two CMIP5 climate models show an additional mass loss of 0 and 3 cm of SLE on average compared to simulations done under present-day conditions for the two CMIP5 forcings used and display limited mass gain in East Antarctica.
A team of earthquake geologists, seismologists, and engineering seismologists has collectively produced an update of the national probabilistic seismic hazard (PSH) model for New Zealand (National Seismic Hazard Model, or NSHM). The new NSHM supersedes the earlier NSHM published in 2002 and used as the hazard basis for the New Zealand Loadings Standard and numerous other end‐user applications. The new NSHM incorporates a fault source model that has been updated with over 200 new onshore and offshore fault sources and utilizes new New Zealand‐based and international scaling relationships for the parameterization of the faults. The distributed seismicity model has also been updated to include post‐1997 seismicity data, a new seismicity regionalization, and improved methodology for calculation of the seismicity parameters. Probabilistic seismic hazard maps produced from the new NSHM show a similar pattern of hazard to the earlier model at the national scale, but there are some significant reductions and increases in hazard at the regional scale. The national‐scale differences between the new and earlier NSHM appear less than those seen between much earlier national models, indicating that some degree of consistency has been achieved in the national‐scale pattern of hazard estimates, at least for return periods of 475 years and greater.
Manufacturing industries and investors are always seeking to improve techniques to lower cost, energy and expand their capability. Additive manufacturing, started in the 1960s, has since had a rapid and continuous growth, bringing to light novel techniques to expand manufacturing capability and reinvent the wheel. At this stage, research and industry interest lie in determining where AM can replace or create new manufacturing systems. Traditional manufacturing refers to subtractive and long-established manufacturing methods, quality assured and implemented in the commercial space. This paper reviews the capability of AM and its current development to compete or add to established traditional manufacturing regions. Literature reveals the capability of AM to fit into established manufacturing regions for low and high production volume products. The paper comparison focuses on the similarities, differences, advantages and disadvantages found in AM vs SM studying the economic and quality management status of the industry today.
In the event of a natural disaster, remote sensing is a valuable source of spatial information and its utility has been proven on many occasions around the world. However, there are many different types of hazards experienced worldwide on an annual basis and their remote sensing solutions are equally varied. This paper addresses a number of data types and image processing techniques used to map and monitor earthquakes, faulting, volcanic activity, landslides, flooding, and wildfire, and the damages associated with each. Remote sensing is currently used operationally for some monitoring programs, though there are also difficulties associated with the rapid acquisition of data and provision of a robust product to emergency services as an end-user. The current status of remote sensing as a rapid-response data source is discussed, and some perspectives given on emerging airborne and satellite technologies.
Aerobic methanotrophic bacteria are capable of utilizing methane as their sole energy source. They are commonly found at the oxic/anoxic interfaces of environments such as wetlands, aquatic sediments, and landfills, where they feed on methane produced in anoxic zones of these environments. Until recently, all known species of aerobic methanotrophs belonged to the phylum Proteobacteria, in the classes Gammaproteobacteria and Alphaproteobacteria. However, in 2007-2008 three research groups independently described the isolation of thermoacidophilic methanotrophs that represented a distinct lineage within the bacterial phylum Verrucomicrobia. Isolates were obtained from geothermal areas in Italy, New Zealand and Russia. They are by far the most acidophilic methanotrophs known, with a lower growth limit below pH 1. Here we summarize the properties of these novel methanotrophic Verrucomicrobia, compare them with the proteobacterial methanotrophs, propose a unified taxonomic framework for them and speculate on their potential environmental significance. New genomic and physiological data are combined with existing information to allow detailed comparison of the three strains. We propose the new genus Methylacidiphilum to encompass all three newly discovered bacteria.
Other| August 01, 1985 The importance of CO 2 on freezing point measurements of fluid inclusions; evidence from active geothermal systems and implications for epithermal ore deposition Jeffrey W. Hedenquist; Jeffrey W. Hedenquist DSIR Chem. Div., Taupo, New Zealand Search for other works by this author on: GSW Google Scholar Richard W. Henley Richard W. Henley Search for other works by this author on: GSW Google Scholar Author and Article Information Jeffrey W. Hedenquist DSIR Chem. Div., Taupo, New Zealand Richard W. Henley Publisher: Society of Economic Geologists First Online: 02 Mar 2017 Online ISSN: 1554-0774 Print ISSN: 0361-0128 GeoRef, Copyright 2004, American Geological Institute. Reference includes data supplied by Institute of Geological and Nuclear Sciences (SIRIS), Lower Hutt, New Zealand Economic Geology (1985) 80 (5): 1379–1406. https://doi.org/10.2113/gsecongeo.80.5.1379 Article history First Online: 02 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn Email Permissions Search Site Citation Jeffrey W. Hedenquist, Richard W. Henley; The importance of CO 2 on freezing point measurements of fluid inclusions; evidence from active geothermal systems and implications for epithermal ore deposition. Economic Geology 1985;; 80 (5): 1379–1406. doi: https://doi.org/10.2113/gsecongeo.80.5.1379 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyEconomic Geology Search Advanced Search Abstract In studies of epithermal precious and base metal ore deposits, estimates of salinity (total dissolved salts) are frequently in error when based on fluid inclusion ice melting measurements in the absence of an independent determination of the CO 2 content of the inclusion fluid. For a fluid of known composition the melting pint of ice (T m ) may be calculated from T m = -sigma K i m i where K i is the molal freezing (or melting) point depression constant and m i is the molality of a component i (i = Na (super +) , K (super +) , Cl (super -) , CO 2 etc) for fully dissociated solute species such as Cl (super -) , in the salinity range considered here K = 1.72 Kelvin/molal, and for undissociated, nonpolar species such as CO 2 , K = 1.86 Kelvin/molal. Fluid inclusion ice-melting data from New Zealand geothermal fields correlate well with values calculated using the above equation and the measured compositions of discharges from wells from which the inclusion samples were obtained. Loss of the dominant dissolved gas, CO 2 during boiling at depth results in large, systematic decreases in apparent salinity (in terms of T m ) in the Broadlands field. Misinterpretation of fluid inclusion freezing data may lead to substantial errors in the reconstruction of the physico-chemical environment of ore formation in fossil systems. For example in the absence of CO 2 analyses, inclusion fluids similar in gas content to the Broadlands geothermal fluid (NaCl 0.2 wt %, CO 2 up to 4.4 wt %) may be interpreted to have salinities of 0.85 wt percent NaCl leading to errors of 23% in the estimated depth of formation at 280 degrees C -0.5 unit in the estimated pH of the ore fluid, and on the order of 200 times in the estimated solubility of an ore component such as lead. Such errors may be transmitted into subsequent estimation of fluid flux or duration of ore formation. This content is PDF only. Please click on the PDF icon to access. First Page Preview Close Modal You do not have access to this content, please speak to your institutional administrator if you feel you should have access.
Abstract To photo-catalytically degrade RhB dye using solar irradiation, CeO 2 doped TiO 2 nanocomposites were synthesized hydrothermally at 700 °C for 9 hrs. All emission spectra showed a prominent band centered at 442 nm that was attributed to oxygen related defects in the CeO 2 -TiO 2 nanocrystals. Two sharp absorption bands at 1418 cm −1 and 3323 cm −1 were attributed to the deformation and stretching vibration, and bending vibration of the OH group of water physisorbed to TiO 2 , respectively. The photocatalytic activities of Ce-TiO 2 nanocrystals were investigated through the degradation of RhB under UV and UV+ visible light over a period of 8 hrs. After 8 hrs, the most intense absorption peak at 579 nm disappeared under the highest photocatalytic activity and 99.89% of RhB degraded under solar irradiation. Visible light-activated TiO 2 could be prepared from metal-ion incorporation, reduction of TiO 2 , non-metal doping or sensitizing of TiO 2 using dyes. Studying the antibacterial activity of Ce-TiO 2 nanocrystals against E. coli revealed significant activity when 10 μg was used, suggesting that it can be used as an antibacterial agent. Its effectiveness is likely related to its strong oxidation activity and superhydrophilicity. This study also discusses the mechanism of heterogeneous photocatalysis in the presence of TiO 2 .