Kazan State Technical University named after A. N. Tupolev

The mutual influence of superconductivity and magnetism in F/S systems, i.e. systems of alternating ferromagnetic (F) and superconducting (S) layers, is comprehensively reviewed. For systems with ferromagnetic metal (FM) layers, a theory of the proximity effect in the dirty limit is constructed based on the Usadel equations. For an FM/S bilayer and an FM/S superlattice, a boundary-value problem involving finite FM/S boundary transparency and the diffusion and wave modes of quasi-particle motion is formulated; and the critical temperature Tc is calculated as a function of FM- and S-layer thicknesses. A detailed analysis of a large amount of experimental data amply confirms the proposed theory. It is shown that the superconducting state of an FM/S system is a superposition of two pairing mechanisms, Bardin – Cooper – Schrieffer's in S layers and Larkin – Ovchinnikov – Fulde – Ferrell's in FM ones. The competition between ferromagnetic and antiferromagnetic spontaneous moment orientations in FM layers is explored for the 0- and π-phase superconductivity in FM/S systems. For FI/S structures, where FI is a ferromagnetic insulator, a model for exchange interactions is proposed, which, along with direct exchange inside FI layers, includes indirect Ruderman – Kittel – Kasuya – Yosida exchange between localized spins via S-layer conduction electrons. Within this framework, possible mutual accommodation scenarios for superconducting and magnetic order parameters are found, the corresponding phase diagrams are plotted, and experimental results are explained. The results of the theory of the Josephson effect for S/F/S junctions are presented and the application of the theory of spin-dependent transport to F/S/F junctions is discussed. Application aspects of the subject are examined.

Gold nanoparticles (AuNPs) are extremely promising objects for solving a wide range of biomedical problems. The gold nanoparticles production by biological method ("green synthesis") is eco-friendly and allows minimization of the amount of harmful chemical and toxic byproducts. This review is devoted to the AuNPs biosynthesis peculiarities using various living organisms (bacteria, fungi, algae, and plants). The participation of various biomolecules in the AuNPs synthesis and the influence of size, shapes, and capping agents on the functionalities are described. The proposed action mechanisms on target cells are highlighted. The biological activities of "green" AuNPs (antimicrobial, anticancer, antiviral, etc.) and the possibilities of their further biomedical application are also discussed.

Silver nanoparticles (AgNPs) are a promising tool in the fight against pathogenic microorganisms. "Green" nanoparticles are especially valuable due to their environmental friendliness and lower energy consumption during production, as well as their ability to minimize the number of toxic by-products. This review focuses on the features of AgNP synthesis using living organisms (bacteria, fungi, plants) and the involvement of various biological compounds in this process. The mechanism of antibacterial activity is also discussed in detail with special attention given to anti-biofilm and anti-quorum sensing activities. The toxicity of silver nanoparticles is considered in light of their further biomedical applications.

Selenium nanoparticles (SeNPs) are extremely popular objects in nanotechnology. "Green" synthesis has special advantages due to the growing necessity for environmentally friendly, non-toxic, and low-cost methods. This review considers the biosynthesis mechanism of bacteria, fungi, algae, and plants, including the role of various biological substances in the processes of reducing selenium compounds to SeNPs and their further packaging. Modern information and approaches to the possible biomedical use of selenium nanoparticles are presented: antimicrobial, antiviral, anticancer, antioxidant, anti-inflammatory, and other properties, as well as the mechanisms of these processes, that have important potential therapeutic value.

The two faces of gold: the reduction of oxygen on gold electrodes in alkaline solutions has been investigated theoretically. The most favorable reaction leads directly to adsorbed O(2)(-), but the activation energy for a two-step pathway, in which the first step is an outer-sphere electron transfer to give solvated O(2)(-), is only slightly higher. d-band catalysis, which dominates oxygen reduction in acid media, plays no role. The reason why the reaction is slow in acid media is also explained.

We present high-resolution, all-optical thermometry based on ensembles of germanium-vacancy (GeV) color center in diamond and implement this method of thermometry in the fiber-optic format. Due to the unique properties of diamond, an all-optical approach using this method opens a way to produce back-action-free temperature measurements with resolution below 0.1 K in a wide range of temperatures.

Fiber Bragg grating (FBG) sensors have emerged as advanced tools for monitoring a wide range of physical parameters in various fields, including structural health, aerospace, biochemical, and environmental applications. This review provides a comprehensive overview of FBG sensor technology, focusing on their operating principles, key advantages such as high sensitivity and immunity to electromagnetic interference, and common challenges like temperature-strain cross-sensitivity and the high cost of interrogation systems. Additionally, this review compares FBG sensors with other sensing technologies and highlights recent innovations in design, packaging, and implementation techniques. Finally, future research directions are discussed to enhance the performance, scalability, and long-term reliability of FBG-based sensing systems.

Modern structural engineering is impossible without the use of materials and structures with high strength and low specific weight. This work carries out a quantitative and qualitative analysis of articles for 2016-2021 on the topic of welding of dissimilar alloys. It is found that laser welding is most widely used for such metal pairs as Al/Fe, Al/Ti, and Al/Cu. The paper analyzes the influence of the basic techniques, methods, and means of laser welding of Al/Fe, Al/Ti, and Al/Cu on the mechanical properties and thickness of the intermetallic compound (IMC). When welding the lap joint or spike T-joint configuration of Al/Fe, it is preferable to melt the steel, which will be heated or melted, by the laser beam, and through thermal conduction, it will heat the aluminum. When welding the butt-welded joint of Al/Fe, the most preferable is to melt the aluminum by the laser beam (150-160 MPa). When welding the butt-welded joint of Al/Ti, it is possible to obtain the minimum IMC and maximum mechanical properties by offsetting the laser beam to aluminum. Whereas when the laser beam is offset to a titanium alloy, the mechanical properties are 40-50% lower than when the laser beam is offset to an aluminum alloy. When lap welding the Al/Cu joint, under the impact of the laser beam on the aluminum, using defocusing or wobbling (oscillation) of a laser beam, it is possible to increase the contact area of electrical conductivity with the tensile shear strength of 95-128 MPa.

An experimental setup for investigating the immunity of computer equipment to the power-line electromagnetic interference has been developed. The results of quantitative investigations of the performance of the computer equipment subjected to the action of nanosecond and microsecond electromagnetic pulses propagated through the power line as well as the results of investigations of the efficiency of external devices for protecting the computer equipment from the action of electromagnetic pulses propagated through the power line are presented.

Additive manufacturing is especially suitable for complex-shaped 3D parts with integrated and optimized functionality realized by filigree geometries. Such designs benefit from low safety factors in mechanical layout. This demands ductile materials that reduce stress peaks by predictable plastic deformation instead of failure. Al–Cu wrought alloys are established materials meeting this requirement. Additionally, they provide high specific strengths. As the designation “Wrought Alloys” implies, they are intended for manufacturing by hot or cold working. When cast or welded, they are prone to solidification cracks. Al–Si fillers can alleviate this, but impair ductility. Being closely related to welding, Laser Beam Melting in Powder Bed (LBM) of Al–Cu wrought alloys like EN AW-2219 can be considered challenging. In LBM of aluminium alloys, only easily-weldable Al–Si casting alloys have succeeded commercially today. This article discusses the influences of boundary conditions during LBM of EN AW-2219 on sample porosity and tensile test results, supported by metallographic microsections and fractography. Load direction was varied relative to LBM build-up direction. T6 heat treatment was applied to half of the samples. Pronounced anisotropy was observed. Remarkably, elongation at break of T6 specimens loaded along the build-up direction exceeded the values from literature for conventionally manufactured EN AW-2219 by a factor of two.

The concept of eutectic solvents as a platform technology for a variety of applications including gas separation has become a popular approach. To date, the number of known deep eutectic solvents (DESs) is limited mainly to halide salts easily interacting with a hydrogen-bond donor (HBD) and resulting in the formation of a liquid phase. Actually, the DESs properties may be tuned by selecting the appropriate HBD, while the structure of the anion is not a decisive factor. However, the presence of other anions may be favorable for certain applications; therefore, expanding the range of deep eutectic solvents seems a relevant issue of chemistry and material science. In this study, we report the high absorption properties of the DES based on 1-butyl-3-methyl imidazolium methanesulfonate–urea toward ammonia. The structure features investigations have revealed the major contribution of C(2)-H to hydrogen bonding. To assess the possibility of selective separation, the solubility of ammonia and two acidic gases (H 2 S and CO 2 ) in the absorbent has been measured. A superior gas sorption capacity was observed for ammonia, for which the Henry’s law constant was equal to 1.52 bar. The obtained results exceeded the solubility data reported in the literature for various ILs containing hydrogen-donating groups. The DESs demonstrated lower yet acceptable solubility toward hydrogen sulfide, whereas the solubility of CO 2 was relatively poor. The thermostimulated desorption has demonstrated that the ability of gases to bind with DES molecules can be ranked as follows: NH 3 > H 2 S > CO 2 . The physical sorption mechanism of ammonia, hydrogen sulfide, and carbon dioxide in the DES was proven by FTIR and thermal desorption analysis. The absorption was totally reversible, and the solubility of gases remains almost unchanged after three cycles.

Abstract Thermogenetics is a promising innovative neurostimulation technique, which enables robust activation of neurons using thermosensitive transient receptor potential (TRP) cation channels. Broader application of this approach in neuroscience is, however, hindered by a limited variety of suitable ion channels, and by low spatial and temporal resolution of neuronal activation when TRP channels are activated by ambient temperature variations or chemical agonists. Here, we demonstrate rapid, robust and reproducible repeated activation of snake TRPA1 channels heterologously expressed in non-neuronal cells, mouse neurons and zebrafish neurons in vivo by infrared (IR) laser radiation. A fibre-optic probe that integrates a nitrogen−vacancy (NV) diamond quantum sensor with optical and microwave waveguide delivery enables thermometry with single-cell resolution, allowing neurons to be activated by exceptionally mild heating, thus preventing the damaging effects of excessive heat. The neuronal responses to the activation by IR laser radiation are fully characterized using Ca2+ imaging and electrophysiology, providing, for the first time, a complete framework for a thermogenetic manipulation of individual neurons using IR light.

Molecular dynamics simulations of liquid ethylene glycol described by the OPLS-AA force field were performed to gain insight into its hydrogen-bond structure. We use the population correlation function as a statistical measure for the hydrogen-bond lifetime. In an attempt to understand the complicated hydrogen-bonding, we developed new molecular visualization tools within the Vish Visualization shell and used it to visualize the life of each individual hydrogen-bond. With this tool hydrogen-bond formation and breaking as well as clustering and chain formation in hydrogen-bonded liquids can be observed directly. Liquid ethylene glycol at room temperature does not show significant clustering or chain building. The hydrogen-bonds break often due to the rotational and vibrational motions of the molecules leading to an H-bond half-life time of approximately 1.5 ps. However, most of the H-bonds are reformed again so that after 50 ps only 40% of these H-bonds are irreversibly broken due to diffusional motion. This hydrogen-bond half-life time due to diffusional motion is 80.3 ps. The work was preceded by a careful check of various OPLS-based force fields used in the literature. It was found that they lead to quite different angular and H-bond distributions.

In this paper, we compared the quality of processing handwritten digits by a fully connected feedforward neural network and a convolutional neural network. Examples of training and use of both a fully connected neural network and a convolutional neural network are given. The ways of image segmentation and finding the boundaries of handwritten digits for their further analysis are considered. Algorithms affecting the accuracy of learning, the speed of learning are considered. The general principles of the structure and principles of operation of a feed-forward neural network and a convolutional neural network are presented.

The article describes the theory and technique of addressed fiber Bragg structures and a new class of microwave-photonic sensory systems based thereon, the distinctive feature of which is that the fiber Bragg structure forms two ultra-narrowband frequency components separated by a unique address frequency spacing. The offset of the central frequencies of the Bragg structures is determined via processing a beat signal of the address frequencies on the photodetector, with its parameters making it possible to evaluate the physical fields applied. We formulate and solve a problem of unambiguously determining the central (Bragg) frequency shift of the addressed fiber Bragg structures with unique address frequencies and the same Bragg frequency. These are then combined into a single multi-sensor system with multiplexed response reception on a single photodetector.

Organized systems based on amphiphiles are discussed from the viewpoint of their application as solubilizing agents and drug and gene delivery systems with structure–activity relationships and stimuli responsibility emphasized. Special attention is paid to cationic surfactants, including gemini and naturally originated compounds. Practically important lipid formulations, i.e., liposomes and solid lipid nanoparticles, are discussed in terms of their stability, loading capacity, surface modification and therapeutic efficacy. The stimuli responsibility of formulations is analyzed and exemplified by smart supramolecular systems based on a calixarene platform.

A new optical method for determining flow-velocity vector fields that allows investigations of unsteady and fast processes is described. The method is based on measuring the displacements of turbulent structures, which are visualized in a light sheet, within a fixed time interval between consecutive video frames. The method was tested using measurements of pulsating-flow velocity. It was shown that the difference between the mean flow velocity in the investigated flow measured using this method and a hot-wire anemometer does not exceed 1%, while the deviation of the rms velocity pulsations is within 4.5%.

The article discusses the development of a system that provides more throughput up to 40 Gbit instead of 10 Gbit using the TWDM-PON (Time and Wavelength Division-Multiplexed Passive Optical Network) system, which was chosen by the international companies FSAN (Full-Service Access Network) and the ITU-T (Telecommunication Standardization Sector of the International Telecommunication Union) group. This system uses the time and frequency division of channels. In this article, this system is developed, and its operation is simulated at a distance of 40 km and with data transfer up to 40 Gbit/s. Also, the system was optimized and the optimal bandwidths for the optical and electrical filters were selected, as well as the optical power of the laser, etc.

This work presents the design and simulation of an all-optical sensor for detection of cancer cells. The proposed device is based on the surface plasmon resonance effect on a spiral shaped photonic crystal fiber structure. The finite element method (FEM) based simulations are carried out for the different cancer cells, such as HELA, Basal, Jurkat, and MDA-MB-231, MCF7, and PC12 detection. The sensor has shown the maximum sensitivity of −289 RIU−1 for the refractive index of the detection of breast cancer cell with the resolution of 2.33 × 10−4. The sensor is effective for the refractive index range of 1.36 to 1.401.The structure is based on spiral shaped photonic crystal fiber, and has shown promising linear sensing response to support the practical feasibility of the device. The proposed sensor design is effective in detecting cervical cancer, skin cancer, blood cancer, breast cancer type 1, breast cancer type 2, and adrenal gland cancer.

We have proposed and demonstrated in recent years an unique technique to synthesize the two-frequency radiation by manipulating the amplitude and the phase of initial one-frequency lightwave. The output frequencies are symmetrical relatively to suppressed initial one and have strongly equal amplitudes and alternative phases. In this paper the principle of two-frequency radiation synthesis is summarized. The information structure of two-frequency radiation is examined and key aspects of its application are discussed concerning to the theory of precision spectral characterization of resonant structures and theory of quasi-harmonic oscillations and potential noise immunity.