Nanyang Polytechnic

ABSTRACT Wound healing is a complicated and continuous process affected by several factors, which needs an appropriate surrounding to achieve accelerated healing. Wound healing process recruits three different phases: inflammation, proliferation, and maturation. Due to the different types of wounds, as well as the advancement in medical technology, various products have been developed to repair different skin lesions. Our objective is to investigate the advancement in wound dressings from traditional to the current methods of treatment. The article presents the characteristics of an ideal wound dressing, the requirements for the appropriate selection of different types of wounds, and a detailed classification of wound dressings. Animal origin, herbal origin, and synthetic dressings are firstly introduced and reviewed. Then, nonmedicated dressings including alginate, hydrogel, and hydrocolloid dressings, as well as medicated dressings are discussed. Finally, the developmental prospectives of the new generations of wound dressings for future researches are presented. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47738.

The temporal development of clear-water local scour depth at cylindrical bridge piers in uniform sand beds is considered. New data are presented and used to quantify the influence of flow duration on the depth of local scour. An equilibrium time scale (t*) is defined. The data show that both t* and the equilibrium scour depth (dse) are subject to similar influences of flow and sediment parameters, as might be expected because they are inherently interdependent. A method is given for determination of the time for development of dse for a given pier, sediment, and approach flow velocity and the concomitant estimation of the scour depth at any stage during development of the equilibrium scour hole. The results show that the scour depth after 10% of the time to equilibrium is between about 50% and 80% of the equilibrium scour depth, depending on the approach flow velocity.

Graphene, one kind of emerging carbon nanomaterial, has attracted increasing attention recently. Due to its fascinating physical and electrochemical properties, graphene as a promising electrode material has been widely used in electrochemical sensing applications. In this review, different approaches for the fabrication of graphene and the preparation of graphene-modified electrodes for electrochemical sensors are introduced. Moreover, recent research results on different graphene-based materials as an electrochemical platform for the detection of various biomolecules and chemicals are reviewed and compared. More electrochemical studies on this novel material should show up in the near future.

A new and simplified formula for predicting the settling velocity of natural sediment particles is developed. The formula proposes an explicit relationship between the particle Reynolds number and a dimensionless particle parameter. It is applicable to a wide range of Reynolds numbers from the Stokes flow to the turbulent regime. The proposed formula has the highest degree of prediction accuracy when compared with other published formulas. It also agrees well with the widely used diagrams and tables proposed by the U.S. Inter-Agency Committee in 1957.

Abstract Halide perovskite quantum dots (QDs) have great potential in photocatalytic applications if their low charge transportation efficiency and chemical instability can be overcome. To circumvent these obstacles, we anchored CsPbBr 3 QDs (CPB) on NH x ‐rich porous g‐C 3 N 4 nanosheets (PCN) to construct the composite photocatalysts via N−Br chemical bonding. The 20 CPB‐PCN (20 wt % of QDs) photocatalyst exhibits good stability and an outstanding yield of 149 μmol h −1 g −1 in acetonitrile/water for photocatalytic reduction of CO 2 to CO under visible light irradiation, which is around 15 times higher than that of CsPbBr 3 QDs. This study opens up new possibilities of using halide perovskite QDs for photocatalytic application.

A new and generic strategy to construct interwoven carbon nanotube (CNT) branches on various metal oxide nanostructure arrays (exemplified by V2 O3 nanoflakes, Co3 O4 nanowires, Co3 O4 -CoTiO3 composite nanotubes, and ZnO microrods), in order to enhance their electrochemical performance, is demonstrated for the first time. In the second part, the V2 O3 /CNTs core/branch composite arrays as the host for Na(+) storage are investigated in detail. This V2 O3 /CNTs hybrid electrode achieves a reversible charge storage capacity of 612 mAh g(-1) at 0.1 A g(-1) and outstanding high-rate cycling stability (a capacity retention of 100% after 6000 cycles at 2 A g(-1) , and 70% after 10 000 cycles at 10 A g(-1) ). Kinetics analysis reveals that the Na(+) storage is a pseudocapacitive dominating process and the CNTs improve the levels of pseudocapacitive energy by providing a conductive network.

Supercapacitor with ultrahigh energy density (e.g., comparable with those of rechargeable batteries) and long cycling ability (>50000 cycles) is attractive for the next-generation energy storage devices. The energy density of carbonaceous material electrodes can be effectively improved by combining with certain metal oxides/hydroxides, but many at the expenses of power density and long-time cycling stability. To achieve an optimized overall electrochemical performance, rationally designed electrode structures with proper control in metal oxide/carbon are highly desirable. Here we have successfully realized an ultrahigh-energy and long-life supercapacitor anode by developing a hierarchical graphite foam-carbon nanotube framework and coating the surface with a thin layer of iron oxide (GF-CNT@Fe2O3). The full cell of anode based on this structure gives rise to a high energy of ∼74.7 Wh/kg at a power of ∼1400 W/kg, and ∼95.4% of the capacitance can be retained after 50000 cycles of charge-discharge. These performance features are superior among those reported for metal oxide based supercapacitors, making it a promising candidate for the next generation of high-performance electrochemical energy storage.

The temporal development of clear-water local scour depth at cylindrical bridge piers in uniform sand beds is considered. New data are presented and used to quantify the influence of flow duration on the depth of local scour. An equilibrium time scale (t*) is defined. The data show that both t* and the equilibrium scour depth (dse) are subject to similar influences of flow and sediment parameters, as might be expected because they are inherently interdependent. A method is given for determination of the time for development of dse for a given pier, sediment, and approach flow velocity and the concomitant estimation of the scour depth at any stage during development of the equilibrium scour hole. The results show that the scour depth after 10% of the time to equilibrium is between about 50% and 80% of the equilibrium scour depth, depending on the approach flow velocity. of local scour d se is rapidly attained in live-bed conditions, but rather more slowly in clear-water conditions (Fig. 1). Clear- water scour occurs for mean flow velocities up to the threshold velocity for bed sediment entrainment, i.e., V # Vc, while live- bed scour occurs for V > Vc. The maximum equilibrium scour depth dse)max occurs at V = Vc. In armored cobble or cohesive sediment bed streams, multiple flood events may be required before the maximum clear-water scour is reached. This may take many years. The equilibrium scour depth in live-bed con- ditions fluctuates due to the effects of bed form migration. The dashed lines in Fig. 1 represent the temporal average scour depth under live-bed conditions. The diagram also shows the time taken, te, for the equilibrium scour depth to develop. The equilibrium time, te, is the focus of this paper. It increases rapidly with flow velocity under clear-water conditions, but then decreases rapidly for live-bed scour. Existing equations for depth of local scour at bridge piers give the equilibrium depth and are therefore conservative re- garding temporal effects. For the live-bed conditions that typ- ically pertain in floods, equilibrium scour depths are appro- priate. However, where clear-water scour conditions exist, the equilibrium depth of scour may be overly conservative. Peak flood flows may last only a number of hours or a few days in the field, and short floods have insufficient time to generate equilibrium depths. For example, bridge piers situated on the floodplain may be wet for periods of less than one day during a flood; typically, clear-water conditions pertain at such sites. The actual scour may be only a small fraction of the equilib- rium scour depth, which could take weeks to fully develop. Johnson and McCuen (1991) developed an analytical model to simulate the temporal process of local scour at piers. The model was applied to a hypothetical bridge pier using a gen- erated sequence of flood flows over a 75 year period, the in- dividual storms being of 24 h duration. At the end of the 75 year period, the scour depth was still increasing.

The low utilization of active sites and sluggish reaction kinetics of MoSe 2 severely impede its commercial application as electrocatalyst for hydrogen evolution reaction (HER). To address these two issues, the first example of introducing 1T MoSe 2 and N dopant into vertical 2H MoSe 2 /graphene shell/core nanoflake arrays that remarkably boost their HER activity is herein described. By means of the improved conductivity, rich catalytic active sites and highly accessible surface area as a result of the introduction of 1T MoSe 2 and N doping as well as the unique structural features, the N‐doped 1T‐2H MoSe 2 /graphene (N‐MoSe 2 /VG) shell/core nanoflake arrays show substantially enhanced HER activity. Remarkably, the N‐MoSe 2 /VG nanoflakes exhibit a relatively low onset potential of 45 mV and overpotential of 98 mV (vs RHE) at 10 mA cm −2 with excellent long‐term stability (no decay after 20 000 cycles), outperforming most of the recently reported Mo‐based electrocatalysts. The success of improving the electrochemical performance via the introduction of 1T phase and N dopant offers new opportunities in the development of high‐performance MoSe 2 ‐based electrodes for other energy‐related applications.

Abstract Increasing the utilization efficiency of sulfur electrodes and suppressing the “shuttle effect” of intermediate polysulfides are the key challenge for high‐performance lithium–sulfur batteries (LSBs). Herein a facile combined strategy is reported to fabricate novel porous carbon fibers/vanadium nitride arrays (PCF/VN) composite scaffold for the storage of sulfur via a facile chemical etching united solvothermal–supercritical fluid method. More active sulfur can be stored in the PCF/VN backbone and dual blocking effects associated with “physical block and chemical absorption” for polysulfides are achieved in the PCF/VN/S integrated electrode. The PCF with highly porous structure provides large space to accommodate active sulfur and possesses cross‐linked maze channels to physically immobilize the polysulfide species. The VN nanobelt arrays demonstrate strong ability for chemically anchoring the polysulfides, thus retarding the shuttle effect. Due to the unique structure and dual confining effect, the designed PCF/VN/S electrode shows a high reversible capacity of 1310.8 mA h g −1 at 0.1 C, an extended cycle life (1052.5 mA h g −1 after 250 cycles) as well as enhanced rate capability, much better than other counterparts (CF/VN/S, PCF/S, and CF/S). This work opens a new door for fabricating high‐performance integrated electrodes for LSBs.

BACKGROUND: Research in the west has shown that job satisfaction, productivity and organizational commitment are affected by leadership behaviours. The purpose of this study is to determine the effect of leadership behaviours on employee outcomes in Singapore. Very little research related to this subject has been done in health care settings in this country. The comparison of the results of the different types of settings and samples will allow a better understanding of the relationship between leadership behaviours and employee outcomes and thus help to determine if leadership is worth the extra effort. METHOD: The study explored the relationships between five leadership behaviours identified by Kouzes and Posner and the employee outcomes of registered nurses practising in the general wards, intensive care units and the coronary care unit in an acute hospital. Survey questionnaires were used to elicit responses from 100 registered nurses and 20 managers belonging to the organization. Data collected included demographic characteristics and the degree to which the five types of leadership behaviours were used as perceived by the nurse managers and the registered nurses. In addition, the level of nurse job satisfaction, the degree of productivity and the extent of organizational commitment are described. FINDINGS: The findings show a similar trend to the original studies in the United States of America. Use of leadership behaviours and employee outcomes were significantly correlated. The regression results indicate that 29% of job satisfaction, 22% of organizational commitment and 9% of productivity were explained by the use of leadership behaviours. Recommendations are made in the light of these findings.

Abstract Scrupulous design and smart hybridization of bespoke electrode materials are of great importance for the advancement of sodium ion batteries (SIBs). Graphene‐based nanocomposites are regarded as one of the most promising electrode materials for SIBs due to the outstanding physicochemical properties of graphene and positive synergetic effects between graphene and the introduced active phase. In this review, the recent progress in graphene‐based electrode materials for SIBs with an emphasis on the electrode design principle, different preparation methods, and mechanism, characterization, synergistic effects, and their detailed electrochemical performance is summarized. General design rules for fabrication of advanced SIB materials are also proposed. Additionally, the merits and drawbacks of different fabrication methods for graphene‐based materials are briefly discussed and summarized. Furthermore, multiscale forms of graphene are evaluated to optimize electrochemical performance of SIBs, ranging from 0D graphene quantum dots, 2D vertical graphene and reduced graphene oxide sheets, to 3D graphene aerogel and graphene foam networks. To conclude, the challenges and future perspectives on the development of graphene‐based materials for SIBs are also presented.

Mammalian genomes harbor a larger than expected number of complex loci, in which multiple genes are coupled by shared transcribed regions in antisense orientation and/or by bidirectional core promoters. To determine the incidence, functional significance, and evolutionary context of mammalian complex loci, we identified and characterized 5,248 cis-antisense pairs, 1,638 bidirectional promoters, and 1,153 chains of multiple cis-antisense and/or bidirectionally promoted pairs from 36,606 mouse transcriptional units (TUs), along with 6,141 cis-antisense pairs, 2,113 bidirectional promoters, and 1,480 chains from 42,887 human TUs. In both human and mouse, 25% of TUs resided in cis-antisense pairs, only 17% of which were conserved between the two organisms, indicating frequent species specificity of antisense gene arrangements. A sampling approach indicated that over 40% of all TUs might actually be in cis-antisense pairs, and that only a minority of these arrangements are likely to be conserved between human and mouse. Bidirectional promoters were characterized by variable transcriptional start sites and an identifiable midpoint at which overall sequence composition changed strand and the direction of transcriptional initiation switched. In microarray data covering a wide range of mouse tissues, genes in cis-antisense and bidirectionally promoted arrangement showed a higher probability of being coordinately expressed than random pairs of genes. In a case study on homeotic loci, we observed extensive transcription of nonconserved sequences on the noncoding strand, implying that the presence rather than the sequence of these transcripts is of functional importance. Complex loci are ubiquitous, host numerous nonconserved gene structures and lineage-specific exonification events, and may have a cis-regulatory impact on the member genes.

A current question in biofilm research is whether biofilm-specific genetic processes can lead to differentiation in physiology and function among biofilm cells. In Pseudomonas aeruginosa, phenotypic variants which exhibit a small-colony phenotype on agar media and a markedly accelerated pattern of biofilm development compared to that of the parental strain are often isolated from biofilms. We grew P. aeruginosa biofilms in glass flow cell reactors and observed that the emergence of small-colony variants (SCVs) in the effluent runoff from the biofilms correlated with the emergence of plaque-forming Pf1-like filamentous phage (designated Pf4) from the biofilm. Because several recent studies have shown that bacteriophage genes are among the most highly upregulated groups of genes during biofilm development, we investigated whether Pf4 plays a role in SCV formation during P. aeruginosa biofilm development. We carried out immunoelectron microscopy using anti-Pf4 antibodies and observed that SCV cells, but not parental-type cells, exhibited high densities of Pf4 filaments on the cell surface and that these filaments were often tightly interwoven into complex latticeworks surrounding the cells. Moreover, infection of P. aeruginosa planktonic cultures with Pf4 caused the emergence of SCVs within the culture. These SCVs exhibited enhanced attachment, accelerated biofilm development, and large regions of dead and lysed cells inside microcolonies in a manner identical to that of SCVs obtained from biofilms. We concluded that Pf4 can mediate phenotypic variation in P. aeruginosa biofilms. We also performed partial sequencing and analysis of the Pf4 replicative form and identified a number of open reading frames not previously recognized in the genome of P. aeruginosa, including a putative postsegregational killing operon.

Abstract Accessibility to abundant sources of high‐quality water is integral to the production of safe and wholesome fresh produce. However, access to safe water is becoming increasingly difficult in many parts of the world, and this can lead to the production of fresh produce contaminated with pathogenic microorganisms, resulting in increased risk of human disease. Water, an important raw material in the fresh produce chain, is used in considerable amounts in many operations, including irrigation and application of pesticides and fertilizers, but also as a transport medium and for cooling and washing in postharvest practices. In several reported outbreaks related to uncooked fruit and vegetable products, water has been identified as a likely source of the outbreak. The present study, initiated by the ILSI Europe Emerging Microbiological Issues Task Force in collaboration with 8 other ILSI branches and support of WHO/FAO, was undertaken to review the status of, and provide suggestions for, consideration by different stakeholders on water and sanitation and its impact on food safety and public health. A limited number of guidelines and regulations on water quality for agricultural production are available, and many of them are still heavily based on microbial standards and (debated) parameters such as fecal coliforms. Data gaps have been identified with regard to baseline studies of microbial pathogens in water sources in many regions, the need for agreement on methods and microbial parameters to be used in assessing water quality, the fate of pathogens in water, and their transfer and persistence on irrigated/processed produce.

The coloration of some butterflies, Pachyrhynchus weevils, and many chameleons are notable examples of natural organisms employing photonic crystals to produce colorful patterns. Despite advances in nanotechnology, we still lack the ability to print arbitrary colors and shapes in all three dimensions at this microscopic length scale. Here, we introduce a heat-shrinking method to produce 3D-printed photonic crystals with a 5x reduction in lattice constants, achieving sub-100-nm features with a full range of colors. With these lattice structures as 3D color volumetric elements, we printed 3D microscopic scale objects, including the first multi-color microscopic model of the Eiffel Tower measuring only 39 µm tall with a color pixel size of 1.45 µm. The technology to print 3D structures in color at the microscopic scale promises the direct patterning and integration of spectrally selective devices, such as photonic crystal-based color filters, onto free-form optical elements and curved surfaces.

A practical method using spreadsheets is proposed for calculating the Hasofer-Lind second moment reliability index β. Two example problems involving correlated normals and correlated nonnormals, respectively, are solved and compared with established mathematical approach. The proposed method is based on the perspective of an ellipsoid that is tangent to the failure surface in the original space of the random variables; concepts of transformed space or reduced variates are not required. Correlation is accounted for by setting up the quadratic form in the spreadsheet. Nonnormals are dealt with using established relationships between nonnormal distribution and its equivalent normal distribution. Iterative searching is performed automatically by invoking a spreadsheet's optimization tool. An advantage of the spreadsheet method is that partial derivatives are not part of the input; the method may therefore be especially attractive for cases with complicated or nonexplicit performance functions.

Smart hybridization of active materials into tailored electrode structure is highly important for developing advanced electrochemical energy storage devices. With the help of sandwiched design, herein a powerful strategy is developed to fabricate three‐layer sandwiched composite core/shell arrays via combined hydrothermal and polymerization approaches. In such a unique architecture, wrinkled MoSe 2 nanosheets are sandwiched by vertical graphene (VG) core and N‐doped carbon (N‐C) shell forming sandwiched core/shell arrays. Interesting advantages including high electrical conductivity, strong mechanical stability, and large porosity are combined in the self‐supported VG/MoSe 2 /N‐C sandwiched arrays. As a preliminary test, the sodium ion storage properties of VG/MoSe 2 /N‐C sandwiched arrays are characterized and demonstrated with high capacity (540 mA h g −1 ), enhanced high rate capability, and long‐term cycling stability (298 mA h g −1 at 2.0 A g −1 after 1000 cycles). The sandwiched core/shell structure plays positive roles in the enhancement of electrochemical performances due to dual conductive carbon networks, good volume accommodation, and highly porous structure with fast ion diffusion. The directional electrode design protocol provides a general method for synthesis of high‐performance ternary core/shell electrodes.

Abstract Two‐dimensional (2D) organic–inorganic hybrid perovskite nanosheets (NSs) are attracting increasing research interest due to their unique properties and promising applications. Here, for the first time, we report the facile synthesis of single‐ and few‐layer free‐standing phenylethylammonium lead halide perovskite NSs, that is, (PEA) 2 PbX 4 (PEA=C 8 H 9 NH 3 , X=Cl, Br, I). Importantly, their lateral size can be tuned by changing solvents. Moreover, these ultrathin 2D perovskite NSs exhibit highly efficient and tunable photoluminescence, as well as superior stability. Our study provides a simple and general method for the controlled synthesis of 2D perovskite NSs, which may offer a new avenue for their fundamental studies and optoelectronic applications.

article Remark on "Algorithm 500: Minimization of Unconstrained Multivariate Functions [E4]" Share on Authors: D. F. Shanno Department of Management Information Systems, College of Business and Public Administration, The University of Arizona, Tucson, AZ Department of Management Information Systems, College of Business and Public Administration, The University of Arizona, Tucson, AZView Profile , K. H. Phua Department of Computer Science, Nanyang University, Upper Jurong Road, Singapore 22, Republic of Singapore Department of Computer Science, Nanyang University, Upper Jurong Road, Singapore 22, Republic of SingaporeView Profile Authors Info & Claims ACM Transactions on Mathematical SoftwareVolume 6Issue 4Dec. 1980 pp 618–622https://doi.org/10.1145/355921.355933Published:01 December 1980 178citation975DownloadsMetricsTotal Citations178Total Downloads975Last 12 Months9Last 6 weeks2 Get Citation AlertsNew Citation Alert added!This alert has been successfully added and will be sent to:You will be notified whenever a record that you have chosen has been cited.To manage your alert preferences, click on the button below.Manage my AlertsNew Citation Alert!Please log in to your account Save to BinderSave to BinderCreate a New BinderNameCancelCreateExport CitationPublisher SiteGet Access