Northeast Petroleum University

Abstract In view of the sluggish kinetics suppressing the oxygen evolution reaction (OER), developing efficient and robust OER catalysts is urgent and essential for developing efficient energy conversion technologies. Herein, hybrid amorphous/crystalline FeCoNi layered double hydroxide (LDH)‐supported single Ru atoms (Ru SAs/AC‐FeCoNi) are developed for enabling a highly efficient electrocatalytic OER. The amorphous outer layer in Ru SAs/AC‐FeCoNi is composed of abundant defect sites and unsaturated coordination sites, which can serve as anchoring sites to stabilize single Ru atoms. The crystalline inner has a highly symmetric rigid structure, thereby strengthening the stability of support for a long‐lasting OER. The synergistic effects endow this hybrid catalyst with extremely low overpotential (205 mV at 10 mA cm −2 ). Density functional theory calculation indicates that single Ru atoms stabilized by hybrid amorphous/crystalline FeCoNi LDH facilitate the formation of Ru–O* (rate‐determining step), thus accelerating the OER process.

A novel carbon nanotubes reinforced polyurethane sponge with superhydrophobic, superoleophilic and high mechanical properties shows potential for applications in oil–water separation.

ABSTRACT The lacustrine shale of the Upper Cretaceous Qingshankou Formation is the principal prospective unconventional target lithology, acting as source, reservoir, and seal. Lithofacies and associated storage capacity are two significant factors in shale oil prospectivity. This paper describes an investigation of the lower Qingshankou Formation lacustrine shale based on detailed description and analysis of cores, shale lithofacies characteristics, depositional setting, and stacking patterns. Seven lithofacies are recognized based on organic matter content, sedimentary structure, and mineralogy, all exhibiting rapid vertical and lateral changes controlled by the depositional setting and basin evolution. An overall trend from shallow-water to deep-water depositional environments is interpreted from the characteristics of the infilling sequences, characterized by increasing total organic carbon (TOC) and total clay content and decreasing layer thickness (i.e., from bedded to laminated then to massive sedimentary structures). Periods of deposition during shallowing cycles show a reverse trend in the sedimentary characteristics described above. The sedimentary rocks in the studied interval show three complete short-term cycles, each one containing progressive and regressive system tracts. Massive siliceous mudstones with both high and moderate TOC are considered to have the best hydrocarbon generation potential. Laminated siliceous mudstones, bedded siltstones, and calcareous mudstones with moderate and low TOC could have the same high hydrocarbon saturations as the high-TOC massive siliceous mudstones, but these lithologies contain more brittle minerals than the massive mudstones. Several siltstone samples show low or zero saturation of in situ hydrocarbons; this is considered to be related to a combination of fair to poor hydrocarbon generation potential and extremely low permeability, limiting migration. Moderate-TOC laminated siliceous mudstones were also observed to have connective pore-fracture networks. It can be demonstrated that successive thick sequences of moderate-TOC laminated siliceous mudstones, showing high volumes of hydrocarbon in situ, a high mineral brittleness index, and good permeability, combine to form shale oil exploration “sweet spots.”

Summary Preformed particle gel (PPG) is a particled superabsorbent crossklinking polymer that can swell up to 200 times its orginal size in brine. The use of PPG as a fluid-diverting agent to control conformance is a novel process designed to overcome some distinct drawbacks inherent in in-situ gelation systems. This paper introduces the effect of gelant compositions and reservoir environments on the two properties of PPG: swollen gel strength and swelling capacity. Results have shown that PPG properties are influenced by gelant compositions, temperature, brine salinity, and pH below 6. Temperature increases PPG swelling capacity but decreases its swollen gel strength. Salinity decreases PPG swelling capacity but increases its swollen gel strength. PPG is thermostable at an elevated temperature of 120°C if a special additive agent is added into its gelant as a composition. PPG is strength- and size-controlled, environmentally friendly, and not sensitive to reservoir minerals and formation water salinity. Two field applications are introduced to illustrate the criteria of well candidate selection and the design and operation process of PPG treatments. Field applications show that PPG treatment is a cost-effective method to correct permeability heterogeneity for the reservoirs with fractures or channels, both of which are widely found in mature waterflooded oil fields.

This paper addresses the distributed resilient filtering problem for a class of power systems subject to denial-of-service (DoS) attacks. A novel distributed filter is first constructed to practically reflect the impact from both cyber-attacks and gain perturbations. For all possible occurrence of DoS attacks and gain perturbations, an upper bound of filtering error covariance is derived by resorting to some typical matrix inequalities. Furthermore, the desired filter gain relying on the solution of two Riccati-like difference equations is obtained with the help of the gradient-based approach and the mathematical induction. The developed algorithm with a recursive form is independent of the global information and thus satisfies the requirements of scalability and distributed implementation online. Finally, a benchmark simulation test is exploited to check the usefulness of the designed filter.

The lithology, lithofacies, reservoir properties and shale oil enrichment model of the fine-grained sedimentary system in a lake basin with terrigenous clastics of large depression are studied taking the organic-rich shale in the first member of Cretaceous Qingshankou Formation (shortened as Qing 1 Member) in the Changling Sag, southern Songliao Basin as an example. A comprehensive analysis of mineralogy, thin section, test, log and drilling geologic data shows that lamellar shale with high TOC content of semi-deep lake to deep lake facies has higher hydrocarbon generation potential than the massive mudstone facies with medium TOC content, and has bedding-parallel fractures acting as effective reservoir space under over pressure. The sedimentary environments changing periodically and the undercurrent transport deposits in the outer delta front give rise to laminated shale area. The laminated shale with medium TOC content has higher hydrocarbon generation potential than the laminated shale with low TOC content, and the generated oil migrates a short distance to the sandy laminae to retain and accumulate in situ. Ultra-low permeability massive mudstone facies as the top and bottom seals, good preservation conditions, high pressure coefficient, and lamellar shale facies with high TOC are the conditions for “lamellation type” shale oil enrichment in some sequences and zones. The sequence and zone with laminated shale of medium TOC content in oil window and with micro-migration of expelled hydrocarbon are the condition for the enrichment of “lamination type” shale oil. The tight oil and “lamination type” shale oil are in contiguous distribution.

In this work, we contribute a new multi-layer neural network architecture named ONCF to perform collaborative filtering. The idea is to use an outer product to explicitly model the pairwise correlations between the dimensions of the embedding space. In contrast to existing neural recommender models that combine user embedding and item embedding via a simple concatenation or element-wise product, our proposal of using outer product above the embedding layer results in a two-dimensional interaction map that is more expressive and semantically plausible. Above the interaction map obtained by outer product, we propose to employ a convolutional neural network to learn high-order correlations among embedding dimensions. Extensive experiments on two public implicit feedback data demonstrate the effectiveness of our proposed ONCF framework, in particular, the positive effect of using outer product to model the correlations between embedding dimensions in the low level of multi-layer neural recommender model.

RIU can be obtained. Our analysis shows that the PCF-SPR sensor is suitable for mid-infrared detection.

In this paper, the robust H <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> filtering problem is studied for a class of uncertain nonlinear networked systems with both multiple stochastic time-varying communication delays and multiple packet dropouts. A sequence of random variables, all of which are mutually independent but obey Bernoulli distribution, are introduced to account for the randomly occurred communication delays. The packet dropout phenomenon occurs in a random way and the occurrence probability for each sensor is governed by an individual random variable satisfying a certain probabilistic distribution in the interval. The discrete-time system under consideration is also subject to parameter uncertainties, state-dependent stochastic disturbances and sector-bounded nonlinearities. We aim to design a linear full-order filter such that the estimation error converges to zero exponentially in the mean square while the disturbance rejection attenuation is constrained to a give level by means of the H <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> performance index. Intensive stochastic analysis is carried out to obtain sufficient conditions for ensuring the exponential stability as well as prescribed H <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> performance for the overall filtering error dynamics, in the presence of random delays, random dropouts, nonlinearities, and the parameter uncertainties. These conditions are characterized in terms of the feasibility of a set of linear matrix inequalities (LMIs), and then the explicit expression is given for the desired filter parameters. Simulation results are employed to demonstrate the effectiveness of the proposed filter design technique in this paper.

We present a novel, structurally simple, multifunctional broadband absorber. It consists of a patterned vanadium dioxide film and a metal plate spaced by a dielectric layer. Temperature control allows flexible adjustment of the absorption intensity from 0 to 0.999. The modulation mechanism of the absorber stems from the thermogenic phase change properties of the vanadium dioxide material. The absorber achieves total reflection properties in the terahertz band when the vanadium dioxide is in the insulated state. When the vanadium dioxide is in its metallic state, the absorber achieves near-perfect absorption in the ultra-broadband range of 3.7 THz-9.7 THz. Impedance matching theory and the analysis of electric field are also used to illustrate the mechanism of operation. Compared to previous reports, our structure utilizes just a single cell structure (3 layers only), and it is easy to process and manufacture. The absorption rate and operating bandwidth of the absorber are also optimised. In addition, the absorber is not only insensitive to polarization, but also very tolerant to the angle of incidence. Such a design would have great potential in wide-ranging applications, including photochemical energy harvesting, stealth devices, thermal emitters,

Lithium–sulfur (Li–S) batteries suffer from multiple complex and often interwoven issues, such as the low electronic conductivity of sulfur and Li2S/Li2S2, shuttle effect, and sluggish electrochemical kinetics of lithium polysulfides (LiPSs). Guided by theoretical calculations, a multifunctional catalyst of isolated single-atom nickel in an optimal Ni–N5 active moiety incorporated in hollow nitrogen-doped porous carbon (Ni–N5/HNPC) is constructed and acts as an ideal host for a sulfur cathode. The host improved electrical conductivity, enhanced physical-chemical dual restricting capability toward LiPSs, and, more importantly, boosted the redox reaction kinetics by the Ni–N5 active moiety. Therefore, the Ni–N5/HNPC/S cathode exhibits superior rate performance, long-term cycling stability, and good areal capacity at high sulfur loading. This work highlights the important role of the coordination number of active centers in single-atom catalysts and provides a strategy to design a hollow nanoarchitecture with single-atom active sites for high-performance Li–S batteries.

RIU. The characteristics of a single D-shape PCF-SPR sensor with the same structural parameters are compared with those of the dual PCFs sensor and the latter has distinct advantages concerning the spectral sensitivity, resolution, amplitude sensitivity, and figure of merits (FOM).

Research on the evaluation criteria of shale oil and gas is conducted to accurately assess the resource potential of shale oil and gas. Statistic analysis of the geochemical index of hydrocarbon source rocks in five areas such as Songliao, Hailaer, Jiyang, based on the characteristic of triple-division between the oil content and TOC of source rock, suggests that shale oil and gas can be categorized into three levels of resource enrichment: scattered (ineffective) resources, low efficient resources and enriched resources. The mature stage, at which organic matter generates oil and gas in large amounts, corresponds to the shale oil and gas enrichment window. Furthermore, recoverable index is defined and its computation formula is proposed to provide a quantitative index for recoverability evaluation, considering the brittle mineral content, thickness and depth of shale, etc. In practice, TOC variable values in well profile obtained by TOC-logging correspondence can be used to draw TOC isopach maps and calculate the amount of resources at different levels. Then combined with the evaluation criteria, TOC and Ro isopach maps are superimposed to identify the favorable shale oil and gasareas.

Abstract The development of rechargeable zinc–air batteries is heavily dependent on bifunctional oxygen electrocatalysts to offer exceptional oxygen reduction/evolution reaction (ORR/OER) activities. However, the design of such electrocatalysts with high activity and durability is challenging. Herein, a strategy is proposed to create an electrocatalyst comprised of copper‐cobalt diatomic sites on a highly porous nitrogen‐doped carbon matrix (Cu‐Co/NC) with abundantly accessible metal sites and optimal geometric and electronic structures. Experimental findings and theoretical calculations demonstrate that the synergistic effect of Cu‐Co dual‐metal sites with metal‐N 4 coordination induce asymmetric charge distributions with moderate adsorption/desorption behavior with oxygen intermediates. This electrocatalyst exhibits extraordinary bifunctional oxygen electrocatalytic activities in alkaline media, with a half‐wave potential of 0.92 V for ORR and a low overpotential of 335 mV at 10 mA cm −2 for OER. In addition, it demonstrates exceptional ORR activity in acidic (0.85 V) and neutral (0.74 V) media. When applied to a zinc–air battery, it achieves extraordinary operational performance and outstanding durability (510 h), ranking it as one of the most efficient bifunctional electrocatalysts reported to date. This work demonstrates the importance of geometric and electronic engineering of isolated dual‐metal sites for boosting bifunctional electrocatalytic activity in electrochemical energy devices.

Abstract Rechargeable zinc–air batteries typically require efficient, durable, and inexpensive bifunctional electrocatalysts to support oxygen reduction/evolution reactions (ORR/OER). However, sluggish kinetics and mass transportation challenges must be addressed if the performance of these catalysts is to be enhanced. Herein, a strategy to fabricate a catalyst comprising atomically dispersed iron atoms supported on a mesoporous nitrogen‐doped carbon support (Fe SAs/NC) with accessible metal sites and optimized electronic metal–support interactions is developed. Both the experimental results and theoretical calculations reveal that the engineered electronic structures of the metal active sites can regulate the charge distribution of Fe centers to optimize the adsorption/desorption of oxygenated intermediates. The Fe SAs/NC containing Fe 1 N 4 O 1 sites achieves remarkable ORR activity over the entire pH range, with half‐wave potentials of 0.93, 0.83, and 0.75 V (vs reversible hydrogen electrode) in alkaline, acidic, and neutral electrolytes, respectively. In addition, it demonstrates a promising low overpotential of 320 mV at 10 mA cm −2 for OER in alkaline conditions. The zinc–air battery assembled with Fe SAs/NC exhibits superior performance than that of Pt/C+RuO 2 counterpart in terms of peak power density, specific capacity, and cycling stability. These findings demonstrate the importance of the electronic structure engineering of metal sites in directing catalytic activity.

In this paper, the robust <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> -control problem is investigated for a class of uncertain discrete-time fuzzy systems with both multiple probabilistic delays and multiple missing measurements. A sequence of random variables, all of which are mutually independent but obey the Bernoulli distribution, is introduced to account for the probabilistic communication delays. The measurement-missing phenomenon occurs in a random way. The missing probability for each sensor satisfies a certain probabilistic distribution in the interval. Here, the attention is focused on the analysis and design of <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> fuzzy output-feedback controllers such that the closed-loop Takagi-Sugeno (T-S) fuzzy-control system is exponentially stable in the mean square. The disturbance-rejection attenuation is constrained to a given level by means of the <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> -performance index. Intensive analysis is carried out to obtain sufficient conditions for the existence of admissible output feedback controllers, which ensures the exponential stability as well as the prescribed <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> performance. The cone-complementarity-linearization procedure is employed to cast the controller-design problem into a sequential minimization one that is solved by the semi-definite program method. Simulation results are utilized to demonstrate the effectiveness of the proposed design technique in this paper.

In this paper, a new <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> filtering approach is developed for a class of discrete time-varying systems subject to missing measurements and quantization effects. The missing measurements are modeled via a diagonal matrix consisting of a series of mutually independent random variables satisfying certain probabilistic distributions on the interval [0,1] . The measured output is quantized by a logarithmic quantizer. Attention is focused on the design of a stochastic <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> filter such that the <i xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">H</i> <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">∞</sub> estimation performance is guaranteed over a given finite-horizon in the simultaneous presence of probabilistic missing measurements, quantization effects as well as external non-Gaussian disturbances. A necessary and sufficient condition is first established for the existence of the desired time-varying filters in virtue of the solvability of certain coupled recursive Riccati difference equations (RDEs). Owing to its recursive nature, the proposed RDE approach is shown to be suitable for online application without the need of increasing the problem size. The simulation experiment is carried out for the mobile robot localization problem with non-Gaussian disturbances, missing measurements and quantization effects. The effectiveness of the proposed method is demonstrated in the numerical example.

Polarization manipulations of electromagnetic waves can be obtained by chiral and anisotropic metamaterials routinely, but the dynamic and high-efficiency modulations of chiral properties still remain challenging at the terahertz range. Here, we theoretically demonstrate a new scheme for realizing thermal-controlled chirality using a hybrid terahertz metamaterial with embedded vanadium dioxide (VO2) films. The phase transition of VO2 films in 90° twisted E-shaped resonators enables high-efficiency thermal modulation of linear polarization conversion. The asymmetric transmission of linearly polarized wave and circular dichroism simultaneously exhibit a pronounced switching effect dictated by temperature-controlled conductivity of VO2 inclusions. The proposed hybrid metamaterial design opens exciting possibilities to achieve dynamic modulation of terahertz waves and further develop tunable terahertz polarization devices.

Summary In this paper, the reservoir characteristics and fluid properties of a reservoir of the Bohai Sea oil field were taken as the research platform. It was confirmed that there exists compatibility between hydrophobically-associating-polymer (HAP) molecular aggregation and pore-throat size. The experiment for oil displacement in heterogeneous cores indicated that there exists applicability of HAP for a heterogeneous reservoir and the applicability can be influenced by polymer concentration. The experiment for oil displacement of parallel cores demonstrated the effect of polymer concentration on the applicability of HAP for reservoir heterogeneity from two aspects of the dynamic behavior of oil displacement and the effectiveness of oil displacement. The results show that with the increase of HAP concentration, the association degree between polymer molecules increases, molecular-clew dimension enlarges, and the compatible size of pore throats of the core increases. The change of HAP concentration not only has an effect on the amount of liquid suctioned by different permeability layers and on the time of profile inversion, but also has an effect on the displacement ability of polymer solution within different layers. As polymer concentration changes, the adaptability of HAP for reservoir heterogeneity changes and the oil-recovery efficiency also changes.

Water industries worldwide consider coagulation/flocculation to be one of the major treatment methods for improving the overall efficiency and cost effectiveness of water and wastewater treatment. Enhancing the coagulation process is currently a popular research topic. In this review article, the latest developments in enhanced coagulation are summarized. In addition, the mechanisms of enhanced coagulation and the effect of process parameters on processing efficiency are discussed from the perspective of ballast-enhanced coagulation, preoxidation, ultrasound, and composite coagulants. Finally, improvements and new directions for enhanced coagulation are proposed.