Pedagogical University

We determine the number counts and z=0-5 luminosity function for a well-defined, homogeneous sample of quasars from the Sloan Digital Sky Survey (SDSS). We conservatively define the most uniform statistical sample possible, consisting of 15,343 quasars within an effective area of 1622 deg^2 that was derived from a parent sample of 46,420 spectroscopically confirmed broad-line quasars in the 5282 deg^2 of imaging data from SDSS Data Release Three. The sample extends from i=15 to i=19.1 at z<3 and to i=20.2 for z>3. The number counts and luminosity function agree well with the results of the 2dF QSO Survey, but the SDSS data probe to much higher redshifts than does the 2dF sample. The number density of luminous quasars peaks between redshifts 2 and 3, although uncertainties in the selection function in this range do not allow us to determine the peak redshift more precisely. Our best fit model has a flatter bright end slope at high redshift than at low redshift. For z<2.4 the data are best fit by a redshift-independent slope of beta = -3.1 (Phi(L) propto L^beta). Above z=2.4 the slope flattens with redshift to beta=-2.37 at z=5. This slope change, which is significant at a >5-sigma level, must be accounted for in models of the evolution of accretion onto supermassive black holes.

We present five new satellites of the Milky Way discovered in Sloan Digital Sky Survey (SDSS) imaging data, four of which were followed up with either the Subaru or the Isaac Newton Telescopes. They include four probable new dwarf galaxies-one each in the constellations of Coma Berenices, Canes Venatici, Leo, and Hercules-together with one unusually extended globular cluster, Segue 1. We provide distances, absolute magnitudes, half-light radii, and color-magnitude diagrams for all five satellites. The morphological features of the color-magnitude diagrams are generally well described by the ridge line of the old, metal-poor globular cluster M92. In the past two years, a total of 10 new Milky Way satellites with effective surface brightness muv&gt;~28 mag arcsec-2 have been discovered in SDSS data. They are less luminous, more irregular, and apparently more metal-poor than the previously known nine Milky Way dwarf spheroidals. The relationship between these objects and other populations is discussed. We note that there is a paucity of objects with half-light radii between ~40 and ~100 pc. We conjecture that this may represent the division between star clusters and dwarf galaxies. Based in part on data collected at Subaru Telescope, which is operated by the National Astronomical Observatory of Japan.

This paper describes the Third Data Release of the Sloan Digital Sky Survey (SDSS). This release, containing data taken up through 2003 June, includes imaging data in five bands over 5282 deg 2 , photometric and astrometric catalogs of the 141 million objects detected in these imaging data, and spectra of 528,640 objects selected over 4188 deg 2 . The pipelines analyzing both images and spectroscopy are unchanged from those used in our Second Data Release.

The nonextensivity parameter q occurring in some of the applications of Tsallis statistics (known also as index of the corresponding Levy distribution) is shown to be given, in the q>1 case, entirely by the fluctuations of the parameters of the usual exponential distribution.

Leung and colleagues have revealed a five-dimensional structure of social axioms across individuals from five cultural groups. The present research was designed to reveal the culture level factor structure of social axioms and its correlates across 41 nations. An ecological factor analysis on the 60 items of the Social Axioms Survey extracted two factors: Dynamic Externality correlates with value measures tapping collectivism, hierarchy, and conservatism and with national indices indicative of lower social development. Societal Cynicism is less strongly and broadly correlated with previous values measures or other national indices and seems to define a novel cultural syndrome. Its national correlates suggest that it taps the cognitive component of a cultural constellation labeled maleficence, a cultural syndrome associated with a general mistrust of social systems and other people. Discussion focused on the meaning of these national level factors of beliefs and on their relationships with individual level factors of belief derived from the same data set.

Hydrogen peroxide (H2O2) is produced predominantly in plant cells during photosynthesis and photorespiration, and to a lesser extent, in respiration processes. It is the most stable of the so-called reactive oxygen species (ROS), and therefore plays a crucial role as a signalling molecule in various physiological processes. Intra- and intercellular levels of H2O2 increase during environmental stresses. Hydrogen peroxide interacts with thiol-containing proteins and activates different signalling pathways as well as transcription factors, which in turn regulate gene expression and cell-cycle processes. Genetic systems controlling cellular redox homeostasis and H2O2 signalling are discussed. In addition to photosynthetic and respiratory metabolism, the extracellular matrix (ECM) plays an important role in the generation of H2O2, which regulates plant growth, development, acclimatory and defence responses. During various environmental stresses the highest levels of H2O2 are observed in the leaf veins. Most of our knowledge about H2O2 in plants has been obtained from obligate C3 plants. The potential role of H2O2 in the photosynthetic mode of carbon assimilation, such as C4 metabolism and CAM (Crassulacean acid metabolism) is discussed. We speculate that early in the evolution of oxygenic photosynthesis on Earth, H2O2 could have been involved in the evolution of modern photosystem II.

We present a new semi-empirical potential suitable for molecular dynamics simulations of liquid and amorphous Cu–Zr alloys. To provide input data for developing the potential, new experimental measurements of the structure factors for amorphous Cu64.5Zr35.5 alloy were performed. In this work, we propose a new method to include diffraction data in the potential development procedure, which also includes fitting to first-principles and liquid density and enthalpy of mixing data. To refine the new potential, we used first-principles and liquid enthalpy of mixing data published earlier combined with the densities of liquid Cu64.5Zr35.5 measured over a range of temperatures. We show that the potential predicts a liquid-to-glass transition temperature that agrees reasonably well with experimental data. Finally, we compare the new potential with two previously developed semi-empirical potentials for Cu–Zr alloys and examine their comparative and contrasting descriptions of structure and properties for Cu64.5Zr35.5 liquids and glasses.

BACKGROUND: Due to demographic changes the world's population is progressively ageing. The physiological decay of the elderly adult may lead to a reduction in the ability to balance and an increased risk of falls becoming an important issue among the elderly. In order to counteract the decay in the ability to balance, physical activity has been proven to be effective. The aim of this study is to systematically review the scientific literature in order to identify physical activity programs able to increase balance in the elderly. METHODS: This review is based on the data from Medline-NLM, Pubmed, ScienceDirect, and SPORTDiscuss and includes randomized control trials that have analyzed balance and physical activity in healthy elderly over 65 years of age during the last decade. A final number of 8 manuscripts were included in the qualitative synthesis, which comprised 200 elderly with a mean age of 75.1 ± 4.4 years. The sample size of the studies varied from 9 to 61 and the intervention periods from 8 to 32 weeks. RESULTS: Eight articles were considered eligible and included in the quantitative synthesis. The articles investigated the effects of resistance and aerobic exercise, balance training, T-bow© and wobble board training, aerobic step and stability ball training, adapted physical activity and Wii Fit training on balance outcomes. Balance measures of the studies showed improvements between 16% and 42% compared to baseline assessments. CONCLUSIONS: Balance is a multifactorial quality that can be effectively increased by different exercise training means. It is fundamental to promote physical activity in the aging adult, being that a negative effect on balance performance has been seen in the no-intervention control groups.

In this Letter, we announce the discovery of a new dwarf satellite of the Milky Way, located in the constellation Canes Venatici. It was found as a stellar overdensity in the north Galactic cap using Sloan Digital Sky Survey Data Release 5 (SDSS DR5). The satellite's color-magnitude diagram shows a well-defined red giant branch as well as a horizontal branch. As judged from the tip of the red giant branch, it lies at a distance of ~220 kpc. Based on the SDSS data, we estimate an absolute magnitude of MV~-7.9, a central surface brightness of mu0,V~28 mag arcsec-2, and a half-light radius of ~8.5 arcmin (~550 pc at the measured distance). The outer regions of Canes Venatici appear extended and distorted. The discovery of such a faint galaxy in proximity to the Milky Way strongly suggests that more such objects remain to be found.

The Active Healthy Kids Canada (AHKC) Report Card on Physical Activity for Children and Youth has been effective in powering the movement to get kids moving by influencing priorities, policies, and practice in Canada. The AHKC Report Card process was replicated in 14 additional countries from 5 continents using 9 common indicators (Overall Physical Activity, Organized Sport Participation, Active Play, Active Transportation, Sedentary Behavior, Family and Peers, School, Community and Built Environment, and Government Strategies and Investments), a harmonized process and a standardized grading framework. The 15 Report Cards were presented at the Global Summit on the Physical Activity of Children in Toronto on May 20, 2014. The consolidated findings are summarized here in the form of a global matrix of grades. There is a large spread in grades across countries for most indicators. Countries that lead in certain indicators lag in others. Overall, the grades for indicators of physical activity (PA) around the world are low/poor. Many countries have insufficient information to assign a grade, particularly for the Active Play and Family and Peers indicators. Grades for Sedentary Behaviors are, in general, better in low income countries. The Community and Built Environment indicator received high grades in high income countries and notably lower grades in low income countries. There was a pattern of higher PA and lower sedentary behavior in countries reporting poorer infrastructure, and lower PA and higher sedentary behavior in countries reporting better infrastructure, which presents an interesting paradox. Many surveillance and research gaps and weaknesses were apparent. International cooperation and cross-fertilization is encouraged to tackle existing challenges, understand underlying mechanisms, derive innovative solutions, and overcome the expanding childhood inactivity crisis.

Modern nanotechnology allows obtaining zinc oxide nanomaterials with unique properties that let its use in a wide range of commercial applications. Direct contact with these particles as well as their release into the environment is almost inevitable. This review aims to consider whether the toxicity of zinc oxide nanoparticles found in numerous test models is a real threat to humans and plants. Emerging reports indicated both the risks and benefits associated with the use of zinc oxide nanoparticles in a manner dependent on the concentration and a method of synthesis, as well as the tested object. The amounts needed to achieve the antibacterial activity of ZnO-NPs, and the reported amounts of these nanoparticles in consumer products are sufficient to have a negative impact on living organisms. The most sensitive to their action are human cells, and the mechanism of cytotoxicity is mainly associated with the formation of oxidative stress caused by the action of zinc ions. ZnO-NPs in small concentration can have positive affect to plants, but it poses a threat to more sensitive ones.

Lack of physical activity is a global public health problem causing not only morbidity and premature mortality, but it is also a major economic burden worldwide. One of the cornerstones of a physically active lifestyle is Motor Competence (MC). MC is a complex biocultural attribute and therefore, its study requires a multi-sectoral, multi-, inter- and transdisciplinary approach. MC is a growing area of research, especially in children and adolescents due to its positive association with a plethora of health and developmental outcomes. Many questions, however, remain to be answered in this field of research, with regard to: (i) Health and Developmental-related Associations of MC; (ii) Assessment of MC; (iii) Prevalence and Trends of MC; (iv) Correlates and Determinants of MC; (v) MC Interventions, and (vi) Translating MC Research into Practice and Policy. This paper presents a narrative review of the literature, summarizing current knowledge, identifying key research gaps and presenting questions for future investigation on MC in children and adolescents. This is a collaborative effort from the International Motor Competence Network (IMCNetwork) a network of academics and researchers aiming to promote international collaborative research and knowledge translation in the expansive field of MC. The knowledge and deliverables generated by addressing and answering the aforementioned research questions on MC presented in this review have the potential to shape the ways in which researchers and practitioners promote MC and physical activity in children and adolescents across the world.

Changes in present-day society such as diets with more sugar, salt, and saturated fat, bad habits and unhealthy lifestyles contribute to the likelihood of the involvement of the microbiota in inflammatory diseases, which contribute to global epidemics of obesity, depression, and mental health concerns. The microbiota is presently one of the hottest areas of scientific and medical research, and exerts a marked influence on the host during homeostasis and disease. Fermented foods and beverages are generally defined as products made by microbial organisms and enzymatic conversions of major and minor food components. Further to the commonly-recognized effects of nutrition on the digestive health (e.g., dysbiosis) and well-being, there is now strong evidence for the impact of fermented foods and beverages (e.g., yoghurt, pickles, bread, kefir, beers, wines, mead), produced or preserved by the action of microorganisms, on general health, namely their significance on the gut microbiota balance and brain functionality. Fermented products require microorganisms, i.e., Saccharomyces yeasts and lactic acid bacteria, yielding alcohol and lactic acid. Ingestion of vibrant probiotics, especially those contained in fermented foods, is found to cause significant positive improvements in balancing intestinal permeability and barrier function. Our guts control and deal with every aspect of our health. How we digest our food and even the food sensitivities we have is linked with our mood, behavior, energy, weight, food cravings, hormone balance, immunity, and overall wellness. We highlight some impacts in this domain and debate calls for the convergence of interdisciplinary research fields from the United Nations’ initiative. Worldwide human and animal medicine are practiced separately; veterinary science and animal health are generally neither considered nor inserted within national or international Health discussions. The absence of a clear definition and subsequent vision for the future of One Health may act as a barrier to transdisciplinary collaboration. The point of this mini review is to highlight the role of fermented foods and beverages on gut microbiota and debate if the need for confluence of transdisciplinary fields of One Health is feasible and achievable, since they are managed by separate sectors with limited communication.

Density functional theory and the quasiharmonic approximation have been used to study the phase diagram of aluminum nitride. AlN was exposed to pressures ranging from $\ensuremath{-}20\phantom{\rule{0.3em}{0ex}}\text{to}\phantom{\rule{0.3em}{0ex}}20\phantom{\rule{0.3em}{0ex}}\mathrm{GPa}$. The phonon dispersion relations and phonon density of states have been calculated for the wurtzite, zinc blende, and rocksalt phases of AlN. The pressure-temperature phase diagram of AlN was constructed and compared with the available experimental data. It shows that at ambient temperature and pressure the most stable phase of AlN is the hexagonal wurtzite structure, while at high pressures and temperatures the rocksalt phase becomes more stable.

In this study we modelled possible causes and consequences of student burnout and engagement on academic efficacy and dropout intention in university students. Further we asked, can student engagement protect against the effects of burnout? In total 4,061 university students from Portugal, Brazil, Mozambique, the United Kingdom, the United States of America, Finland, Serbia, and Macao SAR, Taiwan participated in this study. With the data collected we analyzed the influence of Social Support, Coping Strategies, and school/course related variables on student engagement and burnout using structural equation modeling. We also analyzed the effect of student engagement, student burnout, and their interaction, on Academic Performance and Dropout Intention. We found that both student engagement and burnout are good predictors of subjective academic performance and dropout intention. However, student burnout suppresses the effect of student engagement on these variables. This result has strong implications for practitioners and administrators. To prevent student dropout, it is not enough to promote student engagement-additionally, and importantly, levels of student burnout must be kept low. Other variables such as social support and coping strategies are also relevant predictors of student engagement and burnout and should be considered when implementing preventive actions, self-help and guided intervention programs for college students.

This article argues that strong ethnocentrism exists in TESOL teacher education in the Western English-speaking countries, and that teacher educators in these countries have by and large neglected the special needs of international students enrolled in their programmes. The article specifies the major needs of international TESOL students, and provides suggestions about what TESOL teacher education programmes should do to help meet these needs.

Acrylamide (AA) is a highly reactive organic compound capable of polymerization to form polyacrylamide, which is commonly used throughout a variety of industries. Given its toxic effect on humans and animals, the last 20 years have seen an increased interest in research devoted to the AA. One of the main sources of AA is food. AA appears in heated food following the reaction between amino acids and reduced sugars. Large concentrations of AA can be found in popular staples such as coffee, bread or potato products. An average daily consumption of AA is between 0.3-2.0 microg/kg b.w. Inhalation of acrylamide is related with occupational exposure. AA delivered with food is metabolized in the liver by cytochrome P450. AA biotransformation and elimination result in formation of toxic glycidamide (GA). Both, AA and GA can be involved in the coupling reaction with the reduced glutathione (GSH) forming glutathione conjugates which are excreted with urine. Biotransformation of AA leads to the disturbance in the redox balance. Numerous research proved that AA and GA have significant influence on physiological functions including signal propagation in peripheral nerves, enzymatic and hormonal regulation, functions of muscles, reproduction etc. In addition AA and GA show neurotoxic, genotoxic and cancerogenic properties. In 1994, International Agency for Research on Cancer (IARC) classified acrylamide as a potentially carcinogenic substance to human.

This study investigates the association between objective and subjective characteristics of childhood sexual abuse and psychopathology in later life. The sample consists of 404 Dutch female adults who had been sexually abused in their childhood or adolescence. The participants were recruited by means of articles about childhood sexual abuse in major Dutch newspapers. The characteristics and severity of the sexual abuse were assessed with the Questionnaire Unwanted Sexual Experiences in the Past (QUSEP). General psychopathology was measured with the Symptom Checklist (SCL-90), the degree of dissociation was measured with the Dissociation Questionnaire (DIS-Q). Stepwise multiple regression analyses showed a moderate association between psychopathology and objective characteristics of the abuse, such as number of different types of abusive events and the duration of the abuse. However, more strongly associated with later psychopathology were variables reflecting coping style, such as the degree of self-blame, and circumstantial factors, such as the emotional atmosphere in the family of origin and the reactions after disclosure. Whether or not the abuse was incestuous did not explain additional variance in later psychopathology.

Visible photoluminescence (PL) broad bands are observed in the Raman spectra of SiC nanoparticles (np-SiC) with diameters ranging from 10 to 25 nm. The phenomenon is studied versus the particle size, chemical composition, annealing, and oxidation treatments. In the case of quasistoichiometric np-SiC, excitation by 514-nm radiation gives rise to broad red PL emissions mainly enhanced by the amorphous fraction of the particles and by the surface chemical disorder induced by oxidation. The PL spectra are quantitatively analyzed using numerical methods based on cluster approaches. PL bands are calculated as a function of the cluster geometry and defects (carbon and silicon vacancies), as well as the oxygen location within np-SiC sites. The relevance of this numerical analysis is discussed to account for the main features of the PL broad structure. The PL signature in SiC nanopowders can be used to monitor the physical organization of the np-SiC and to point out their amorphous structure fraction, surface states, and the defect contents.

In a celebrated work by Hoeffding [ J. Amer. Statist. Assoc. 58 (1963) 13–30], several inequalities for tail probabilities of sums Mn={X}1+⋯+{X}n of bounded independent random variables Xj were proved. These inequalities had a considerable impact on the development of probability and statistics, and remained unimproved until 1995 when Talagrand [Inst. Hautes Études Sci. Publ. Math. 81 (1995a) 73–205] inserted certain missing factors in the bounds of two theorems. By similar factors, a third theorem was refined by Pinelis [Progress in Probability 43 (1998) 257–314] and refined (and extended) by me. In this article, I introduce a new type of inequality. Namely, I show that ℙ{Mn≥x}≤cℙ{Sn≥x}, where c is an absolute constant and Sn={ɛ}1+⋯+{ɛ}n is a sum of independent identically distributed Bernoulli random variables (a random variable is called Bernoulli if it assumes at most two values). The inequality holds for those x∈ℝ where the survival function x↦ℙ{Sn≥x} has a jump down. For the remaining x the inequality still holds provided that the function between the adjacent jump points is interpolated linearly or log-linearly. If it is necessary, to estimate ℙ{Sn≥x} special bounds can be used for binomial probabilities. The results extend to martingales with bounded differences. It is apparent that Theorem 1.1 of this article is the most important. The inequalities have applications to measure concentration, leading to results of the type where, up to an absolute constant, the measure concentration is dominated by the concentration in a simplest appropriate model, such results will be considered elsewhere.