State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation

Abstract New velocity data in addition to literature data derived from sonic log, seismic, and laboratory measurements are analyzed for clastic silicate rocks. These data demonstrate simple systematic relationships between compressional and shear wave velocities. For water-saturated clastic silicate rocks, shear wave velocity is approximately linearly related to compressional wave velocity and the compressional-to-shear velocity ratio decreases with increasing compressional velocity. Laboratory data for dry sandstones indicate a nearly constant compressional-to-shear velocity ratio with rigidity approximately equal to bulk modulus. Ideal models for regular packings of spheres and cracked solids exhibit behavior similar to the observed water-saturated and dry trends. For dry rigidity equal to dry bulk modulus, Gassmann's equations predict velocities in close agreement with data from the water-saturated rock.

Great progress has been made in the preparation and application of multi-shelled hollow micro-/nanostructures during the past decade. However, the synthetic methodologies and potential applications of these novel and interesting materials have not been reviewed comprehensively in the literature. In the current review we first describe different synthetic methodologies for multi-shelled hollow micro-/nanostructures as well as their compositional and geometric manipulation and then review their applications in energy conversion and storage, sensors, photocatalysis, and drug delivery. The correlation between the geometric properties of multi-shelled hollow micro-/nanostructures and their specific performance in relevant applications are highlighted. These results demonstrate that the geometry has a direct impact on the properties and potential applications of such materials. Finally, the emerging challenges and future development of multi-shelled hollow micro-/nanostructures are further discussed.

The surface uplift history of the Tibetan Plateau (TP) offers a key testing ground for evaluating models of collisional tectonics and holds important implications for processes ranging from global cooling to the onset of the Asian monsoon. Various models have been proposed to reveal the surface uplift history of the TP, but controversies remain. We evaluate these models using data from sedimentology and stratigraphy, structural geology, magmatism, exhumation, and paleoaltimetry studies. Structural analyses indicate that thrust belts, which spread from the central TP outward toward its surrounding margins, accommodated most of the India–Asia convergence, and facilitated crustal shortening and thickening in the central TP. Eocene adakitic rocks located in the Qiangtang and the Lhasa blocks likely were generated by partial melting of an eclogitic source. Paleogene (50–30 Ma) potassic rocks only occur in the Qiangtang block, whereas Late Oligocene–Late Miocene (26–8 Ma) potassic rocks occur both in the Qiangtang and Lhasa blocks. Low-temperature thermochronologic ages in the central TP are older than 40–35 Ma, whereas those in the margins are younger than 20 Ma (mostly Late Miocene, and Pliocene/Pleistocene in age). Independent paleoaltimetry estimates suggest that the Lhasa and Qiangtang terranes attained their current elevations during the Eocene, most likely due to the initial collision between India and Lhasa, whereas the Hoh Xil basin area to the north and Himalayas to the south were still low, even below sea level in the latter case. We argue for an inside-out growth pattern for the Tibetan Plateau. The TP grew southward and northward from a nucleus of high topography and is likely to continue expanding along the Mazar Tagh fault to the northwest, the Kuantai Shan-Hei Shan-Longshou Shan to the northeast, the Longquan Shan to the east and the Shillong plateau to the south if the northward force of India would not diminished.

Abstract Synthesizing H 2 O 2 from water and air via a photocatalytic approach is ideal for efficient production of this chemical at small‐scale. However, the poor activity and selectivity of the 2 e − water oxidation reaction (WOR) greatly restricts the efficiency of photocatalytic H 2 O 2 production. Herein we prepare a bipyridine‐based covalent organic framework photocatalyst (denoted as COF‐TfpBpy) for H 2 O 2 production from water and air. The solar‐to‐chemical conversion (SCC) efficiency at 298 K and 333 K is 0.57 % and 1.08 %, respectively, which are higher than the current reported highest value. The resulting H 2 O 2 solution is capable of degrading pollutants. A mechanistic study revealed that the excellent photocatalytic activity of COF‐TfpBpy is due to the protonation of bipyridine monomer, which promotes the rate‐determining reaction (2 e − WOR) and then enhances Yeager‐type oxygen adsorption to accelerate 2 e − one‐step oxygen reduction. This work demonstrates, for the first time, the COF‐catalyzed photosynthesis of H 2 O 2 from water and air; and paves the way for wastewater treatment using photocatalytic H 2 O 2 solution.

The steep, high‐relief eastern margin of the Tibetan Plateau has undergone rapid Cenozoic cooling and denudation yet shows little evidence for large‐magnitude shortening or accommodation generation in the foreland basin. We address this paradox by using a variety of geomorphic observations to place constraints on the kinematics and slip rates of several large faults that parallel the plateau margin. The Beichuan and Pengguan faults are active, dominantly dextral‐slip structures that can be traced continuously for up to 200 km along the plateau margin. Both faults offset fluvial fill terraces that yield inheritance‐corrected, cosmogenic 10 Be exposure ages of <15 kyr, indicating latest Pleistocene activity. The Pengguan fault appears to have been active in the Holocene at two sites along strike. Latest Quaternary apparent throw rates on both faults are variable along strike but are typically <1 mm yr −1 . Rates of strike‐slip displacement are likely to be several times higher, probably ∼1–10 mm yr −1 but remain poorly constrained. Late Quaternary folding and dextral strike‐slip has also occurred along the western margin of the Sichuan Basin, particularly associated with the present‐day mountain front. These observations support models for the formation and maintenance of the eastern plateau margin that do not involve major upper crustal shortening. They also suggest that activity on the margin‐parallel faults in eastern Tibet may represent a significant seismic hazard to the densely populated Sichuan Basin.

Abstract The surface electron density significantly affects the photocatalytic efficiency, especially the photocatalytic CO 2 reduction reaction, which involves multi-electron participation in the conversion process. Herein, we propose a conceptually different mechanism for surface electron density modulation based on the model of Au anchored CdS. We firstly manipulate the direction of electron transfer by regulating the vacancy types of CdS. When electrons accumulate on vacancies instead of single Au atoms, the adsorption types of CO 2 change from physical adsorption to chemical adsorption. More importantly, the surface electron density is manipulated by controlling the size of Au nanostructures. When Au nanoclusters downsize to single Au atoms, the strong hybridization of Au 5 d and S 2 p orbits accelerates the photo-electrons transfer onto the surface, resulting in more electrons available for CO 2 reduction. As a result, the product generation rate of Au SA /Cd 1−x S manifests a remarkable at least 113-fold enhancement compared with pristine Cd 1−x S.

ABSTRACT The lacustrine shale of the Upper Cretaceous Qingshankou Formation is the principal prospective unconventional target lithology, acting as source, reservoir, and seal. Lithofacies and associated storage capacity are two significant factors in shale oil prospectivity. This paper describes an investigation of the lower Qingshankou Formation lacustrine shale based on detailed description and analysis of cores, shale lithofacies characteristics, depositional setting, and stacking patterns. Seven lithofacies are recognized based on organic matter content, sedimentary structure, and mineralogy, all exhibiting rapid vertical and lateral changes controlled by the depositional setting and basin evolution. An overall trend from shallow-water to deep-water depositional environments is interpreted from the characteristics of the infilling sequences, characterized by increasing total organic carbon (TOC) and total clay content and decreasing layer thickness (i.e., from bedded to laminated then to massive sedimentary structures). Periods of deposition during shallowing cycles show a reverse trend in the sedimentary characteristics described above. The sedimentary rocks in the studied interval show three complete short-term cycles, each one containing progressive and regressive system tracts. Massive siliceous mudstones with both high and moderate TOC are considered to have the best hydrocarbon generation potential. Laminated siliceous mudstones, bedded siltstones, and calcareous mudstones with moderate and low TOC could have the same high hydrocarbon saturations as the high-TOC massive siliceous mudstones, but these lithologies contain more brittle minerals than the massive mudstones. Several siltstone samples show low or zero saturation of in situ hydrocarbons; this is considered to be related to a combination of fair to poor hydrocarbon generation potential and extremely low permeability, limiting migration. Moderate-TOC laminated siliceous mudstones were also observed to have connective pore-fracture networks. It can be demonstrated that successive thick sequences of moderate-TOC laminated siliceous mudstones, showing high volumes of hydrocarbon in situ, a high mineral brittleness index, and good permeability, combine to form shale oil exploration “sweet spots.”

Bismuth-rich bismuth oxyhalides (Bi–O–X; X = Cl, Br, I) display high photocatalytic reduction activity due to the promoting conduction band potential. In this work, two Bi5O7I nanosheets with different dominant facets were synthesized using either molecular precursor hydrolysis or calcination. Crystal structure characterizations, included X-ray diffraction patterns (XRD), field emission electron microscopy and fast Fourier transformation (FFT) images, showed that hydrolysis and calcination resulted in the dominant exposure of {100} and {001} facets, respectively. Photocatalytic data revealed that Bi5O7I–001 had a higher activity than Bi5O7I–100 for N2 fixation and dye degradation. Photoelectrochemical data revealed that Bi5O7I–001 had higher photoinduced carrier separation efficiency than Bi5O7I–100. The band structure analysis also used to explain the underlying photocatalytic mechanism based on the different conduction band position. This work presents the first report about the facet-dependent photocatalytic performance of bismuth-rich Bi–O–X photocatalysts.

Graphitic carbon nitride (g-C3N4) is a visible light photocatalyst, limited by low activity mainly caused by rapid recombination of charge carriers. In the present work, honeycomb-like g-C3N4 was synthesized via thermal condensation of urea with addition of water at 450 °C for 1 h. Prolonging the condensation time caused the morphology of g-C3N4 to change from a porous honeycomb structure to a velvet-like nanoarchitecture. Unlike in previous studies, the photocatalytic activity of g-C3N4 decreased with increasing surface area. The honeycomb-like g-C3N4 with a relatively low surface area showed highly enhanced photocatalytic activity with an NO removal ratio of 48%. The evolution of NO2 intermediate was dramatically inhibited over the honeycomb-like g-C3N4. The short and long lifetimes of the charge carriers for honeycomb-like g-C3N4 were unprecedentedly prolonged to 22.3 and 165.4 ns, respectively. As a result, the honeycomb-like g-C3N4 was highly efficient and stable in activity and could be used repeatedly. Addition of water had the following multiple positive effects on g-C3N4: (1) formation of the honeycomb structure, (2) promotion of charge separation and migration, (3) enlargement of the band gap, (4) increase in production yield, and (5) decrease in energy cost. These advantages make the present preparation method for highly efficient g-C3N4 extremely appealing for large-scale applications. The active species produced from g-C3N4 under illumination were confirmed using DMPO-ESR spin-trapping, the reaction intermediate was monitored, and the reaction mechanism of photocatalytic NO oxidation by g-C3N4 was revealed. This work could provide an attractive alternative method for mass-production of highly active g-C3N4-based photocatalysts for environmental and energetic applications.

The eastern margin of the Tibetan Plateau combines very high relief with almost no Tertiary foreland sedimentation and little evidence of Cenozoic tectonic shortening. While river incision and landscape development at the plateau margin have received significant attention over the last decade, little is known about the Cenozoic development of the adjacent Sichuan Basin. Here we assess the Cenozoic thermal history of this basin using detrital apatite fission track (AFT) and (U‐Th)/He techniques and establish the presence of an exhumed AFT paleopartial annealing zone across much of the basin. This observation, combined with stratigraphic and borehole sections and inverse modeling of confined apatite fission tracks, indicates that the strata within the basin have undergone accelerated cooling after ∼40 Ma, consistent with the widespread erosion of ∼1 to 4 km of overlying sedimentary material. This regional‐scale erosion is most likely a response to changes in the Yangtze River system draining and removing sediment from the basin. The base‐level fall associated with this erosion contributed to a relative increase in relief across the Longmen Shan and may have helped drive Miocene‐Recent incision and unloading of the plateau margin.

Silver, known and utilized since ancient times, is a coinage metal, which has been widely used for various organic transformations in the past few decades. Currently, the silver-catalyzed reaction is one of the frontier areas in organic chemistry, and the progress of research in this field is very rapid. Compared with other transition metals, silver has long been believed to have low catalytic efficiency, and most commonly, it is used as either a cocatalyst or a Lewis acid. Interestingly, the discovery of Ag-catalysis has been significantly improved in recent years. Especially, Ag(i) has been demonstrated as an important and versatile catalyst for a variety of organic transformations. However, so far, there has been no systematic review on Ag-catalyzed C-H/C-C bond functionalization. In this review, we will focus on the development of Ag-catalyzed C-H/C-C bond functionalization and the corresponding mechanism.

The purpose of this article was to quantitatively investigate the pore structure and fractal characteristics of different lithofacies in the upper Permian Dalong Formation marine shale. Shale samples in this study were collected from well GD1 in the Lower Yangtze region for mineral composition, X-ray diffraction (XRD), and nitrogen adsorption–desorption analysis, as well as broad-ion beam scanning electron microscopy (BIB-SEM) observation. Experimental results showed that the TOC (total organic carbon) content and vitrinite reflectance (Ro) of the investigated shale samples were in the ranges 1.18–6.45% and 1.15–1.29%, respectively, showing that the Dalong Formation shale was in the mature stage. XRD results showed that the Dalong Formation shale was dominated by quartz ranging from 38.4% to 54.3%, followed by clay minerals in the range 31.7–37.5%, along with carbonate minerals (calcite and dolomite), with an average value of 9.6%. Based on the mineral compositions of the studied samples, the Dalong Formation shale can be divided into two types of lithofacies, namely siliceous shale facies and clay–siliceous mixed shale facies. In siliceous shale facies, which were mainly composed of organic pores, the surface area (SA) and pore volume (PV) were in the range of 5.20–10.91 m2/g and 0.035–0.046 cm3/g, respectively. Meanwhile, the pore size distribution (PSD) and fractal dimensions were in the range 14.2–26.1 nm and 2.511–2.609, respectively. I/S (illite-smectite mixed clay) was positively correlated with SA, PV, and fractal dimensions, while illite had a negative relationship with SA, PV, and fractal dimensions. I/S had a strong catalytic effect on organic matter for hydrocarbon generation, which was beneficial to the development of organic micropores, so I/S was conducive to pore structure complexity and the increase in SA and PV, while illite easily filled organic pores, which was not beneficial to the improvement of pore space. In clay–siliceous mixed shale facies, which mainly develop inorganic pores such as intergranular pores, SA and PV were in the range of 6.71–11.38 m2/g and 0.030–0.041 cm3/g, respectively. Meanwhile, PSD and fractal dimensions were in the range of 14.3–18.9 nm and 2.563–2.619, respectively. Quartz and I/S showed weak positive correlations with SA, PV, and fractal dimensions. The various compact modes between quartz particles and the disorder of I/S were conducive to the complexity of pore structure and the improvement of SA and PV. The research findings can provide a reference for the optimization and evaluation of shale gas favorable area of the Lower Yangtze Platform.

The current simple nanofluid flooding method for tertiary or enhanced oil recovery is inefficient, especially when used with low nanoparticle concentration. We have designed and produced a nanofluid of graphene-based amphiphilic nanosheets that is very effective at low concentration. Our nanosheets spontaneously approached the oil-water interface and reduced the interfacial tension in a saline environment (4 wt % NaCl and 1 wt % CaCl2), regardless of the solid surface wettability. A climbing film appeared and grew at moderate hydrodynamic condition to encapsulate the oil phase. With strong hydrodynamic power input, a solid-like interfacial film formed and was able to return to its original form even after being seriously disturbed. The film rapidly separated oil and water phases for slug-like oil displacement. The unique behavior of our nanosheet nanofluid tripled the best performance of conventional nanofluid flooding methods under similar conditions.

Oxygen vacancies induced exciton dissociation of flexible BiOCl nanosheets for effective photocatalytic CO₂ conversion <italic>via</italic> the CO₂ hydrogenation pathway.

Based on the current research status of shale oil exploration and development at home and abroad, combing the field observations, dissection of typical shale oil regions, analysis and testing of organic-rich shale samples, etc., we compare the differences in geological and engineering characteristics of shale oil reservoirs in marine and continental basins between China and the United States. We put forward 8 issues worthy of attention in the exploration and development of lacustrine shale oil in typical basins of China, including the concept of tight oil and shale oil, differences between continental and marine shale oil reservoirs, medium-low maturity and medium-high maturity, vertical permeability and horizontal permeability, source-reservoir and source-caprock, geology and engineering, selection criteria of favorable areas and “sweet spots”, and basic scientific research and application research. By comparing and analyzing organic-rich shales in the Triassic Yanchang Formation of the Ordos Basin, the Permian Lucaogou Formation in the Jimsar Sag of the Junggar Basin, the Permian Fengcheng Formation in the Mahu Sag, the Cretaceous Qingshankou & Nenjiang Formation in the Songliao Basin and the Paleogene Kongdian & Shahejie Formation in the Bohai Bay Basin, from shale oil exploration to development, three key scientific issues must be studied in-depth in the future: (1) the physical, chemical and biological processes during the deposition of terrestrial fine-grained sediments and the formation mechanism of terrestrial organic-rich shale; (2) diagenesis-hydrocarbon-generation and storage dynamics, hydrocarbon occurrence and enrichment mechanism; (3) the fracturing mechanisms of terrestrial shale layers in different diagenetic stages and the multi-phase and multi-scale flow mechanism of shale oil in shale layers of different maturities. Clarifying the main controlling factors of shale oil reservoir characterization, oil-bearing properties, compressibility and fluidity of shale oil with different maturities and establishing a lacustrine shale oil enrichment model and the evaluation methodology can provide effective development methods, and theoretical foundation, and technical support for the large scale economical exploration and development of lacustrine shale oil resources in China.

Nanocellulose, extracted from the most abundant biomass material cellulose, has proved to be an environmentally friendly material with excellent mechanical performance owing to its unique nano-scaled structure, and has been used in a variety of applications as engineering and functional materials. The great biocompatibility and biodegradability, in particular, render nanocellulose promising in biomedical applications. In this review, the structure, treatment technology and properties of three different nanocellulose categories, i.e., nanofibrillated cellulose (NFC), nanocrystalline cellulose (NCC) and bacterial nanocellulose (BNC), are introduced and compared. The cytotoxicity, biocompatibility and frontier applications in biomedicine of the three nanocellulose categories were the focus and are detailed in each section. Future prospects concerning the cytotoxicity, applications and industrial production of nanocellulose are also discussed in the last section.

The process of using solar energy to split water to produce hydrogen assisted by an inorganic semiconductor is crucial for solving our energy crisis and environmental problems in the future. However, most semiconductor photocatalysts would not exhibit excellent photocatalytic activity without loading suitable co-catalysts. Generally, the noble metals have been widely applied as co-catalysts, but always agglomerate during the loading process or photocatalytic reaction. Therefore, the utilization efficiency of the noble co-catalysts is still very low on a per metal atom basis if no obvious size effect exists, because heterogeneous catalytic reactions occur on the surface active atoms. Here, for the first time, we have synthesized isolated metal atoms (Pt, Pd, Rh, or Ru) stably by anchoring on TiO2 , a model photocatalystic system, by a facile one-step method. The isolated metal atom based photocatalysts show excellent stability for H2 evolution and can lead to a 6-13-fold increase in photocatalytic activity over the metal clusters loaded on TiO2 by the traditional method. Furthermore, the configurations of isolated atoms as well as the originality of their unusual stability were analyzed by a collaborative work from both experiments and theoretical calculations.

This analysis aims to generate landslide susceptibility maps (LSMs) using various machine learning methods, namely random forest (RF), alternative decision tree (ADTree) and Fisher’s Linear Discriminant Function (FLDA). The results of the FLDA, RF and ADTree models were compared with regard to their applicability for creating an LSM of the Gallicash river watershed in the northern part of Iran close to the Caspian Sea. A landslide inventory map was created using GPS points obtained in a field analysis, high-resolution satellite images, topographic maps and historical records. A total of 249 landslide sites have been identified to date and were used in this study to model and validate the LSMs of the study region. Of the 249 landslide locations, 70% were used as training data and 30% for the validation of the resulting LSMs. Sixteen factors related to topographical, hydrological, soil type, geological and environmental conditions were used and a multi-collinearity test of the landslide conditioning factors (LCFs) was performed. Using the natural break method (NBM) in a geographic information system (GIS), the LSMs generated by the RF, FLDA, and ADTree models were categorized into five classes, namely very low, low, medium, high and very high landslide susceptibility (LS) zones. The very high susceptibility zones cover 15.37% (ADTree), 16.10% (FLDA) and 11.36% (RF) of the total catchment area. The results of the different models (FLDA, RF, and ADTree) were explained and compared using the area under receiver operating characteristics (AUROC) curve, seed cell area index (SCAI), efficiency and true skill statistic (TSS). The accuracy of models was calculated considering both the training and validation data. The results revealed that the AUROC success rates are 0.89 (ADTree), 0.92 (FLDA) and 0.97 (RF) and predication rates are 0.82 (ADTree), 0.79 (FLDA) and 0.98 (RF), which justifies the approach and indicates a reasonably good landslide prediction. The results of the SCAI, efficiency and TSS methods showed that all models have an excellent modeling capability. In a comparison of the models, the RF model outperforms the boosted regression tree (BRT) and ADTree models. The results of the landslide susceptibility modeling could be useful for land-use planning and decision-makers, for managing and controlling the current and future landslides, as well as for the protection of society and the ecosystem.

Lithium-ion batteries (LIBs) have been demonstrated as one of the most promising energy storage devices for applications in electric vehicles, smart grids, large-scale energy storage systems, and portable electronics.

The big success in marine shale gas exploration and production made China the third country worldwide to commercialize shale gas development. However, the Upper Ordovician Wufeng Formation and the Lower Silurian Longmaxi Formation in and around the Sichuan Basin are currently the only targets that have realized shale gas industrial development. Great challenges are emerging since tremendous shale gas resources of marine facies, continental facies, and transitional facies that are trapped in new areas and multiple other formations are yet to be successfully developed. Thus, we find it a great necessity to provide suggestions on shale gas exploration and development in China, which hopefully can be helpful for global shale gas exploitation. To meet this goal, this work provides a critical review on the history and current status of China’s shale gas exploration and development and summarizes key practical experiences. In the light of characteristic analysis of typical industrial gas fields and wells, research status, problems and challenges, along with suggestions on pivotal scientific issues are addressed including the development of organic-rich shales, reservoir types and characteristics, shale gas content, and the main controlling factors on shale gas enrichment. Further, future directions of shale gas exploration and development are nailed down, incorporating three levels: areas to improve development technology, areas to seek exploration breakthrough, and areas to conduct preliminary studies. The normal-pressure and deep shale gas retained in the Wufeng and Longmaxi Formations in and around the Sichuan Basin are the first level, which are the most realistic resources that can be commercially developed. For the normal-pressure shale gas, detailed research on the sweet spot selection, drilling–encounter ratio enhancement, and cost minimization by advanced technologies are most imperative; for the deep shale gas, state-of-the-art technology to maximize the stimulated reservoir volume of lateral wells is the key. Gas resources in other shale formations in the Sichuan Basin and its periphery such as the Cambrian marine shales, Permian transitional shales, and Jurassic continental shales are the second level, which have the greatest prospective to claim exploration breakthroughs, while shale gas resources in other basins or regions still demand grand scientific and technological tasks for exploration and development preparation. All in all, as a country with diverse shale gas types and such intricate geological and surface conditions, the summary of China’s shale gas exploration and development practices is of vital significance that will not only shed light on China’s shale gas development directions but also provide references for the shale gas industry in other countries and regions.