Indian Institute of Technology Kharagpur

Abstract The Astropy Project supports and fosters the development of open-source and openly developed Python packages that provide commonly needed functionality to the astronomical community. A key element of the Astropy Project is the core package astropy , which serves as the foundation for more specialized projects and packages. In this article, we provide an overview of the organization of the Astropy project and summarize key features in the core package, as of the recent major release, version 2.0. We then describe the project infrastructure designed to facilitate and support development for a broader ecosystem of interoperable packages. We conclude with a future outlook of planned new features and directions for the broader Astropy Project.

AUTORES: Daniel J Klionsky1745,1749*, Kotb Abdelmohsen840, Akihisa Abe1237, Md Joynal Abedin1762, Hagai Abeliovich425,
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\nXiangmei Chen1133, Yau-Hung Chen1157, Ye-Guang Chen1250, Yin Chen1447, Yingyu Chen953,955, Yongshun Chen2135,
\nYu-Jen Chen712, Yue-Qin Chen1145, Yujie Chen1208, Zhen Chen339, Zhong Chen2123, Alan Cheng1702,
\nChristopher HK Cheng184, Hua Cheng1728, Heesun Cheong814, Sara Cherry1836, Jason Chesney1703,
\nChun Hei Antonio Cheung817, Eric Chevet1359, Hsiang Cheng Chi140, Sung-Gil Chi656, Fulvio Chiacchiera308,
\nHui-Ling Chiang958, Roberto Chiarelli1826, Mario Chiariello235,567,577, Marcello Chieppa835, Lih-Shen Chin290,
\nMario Chiong1285, Gigi NC Chiu878, Dong-Hyung Cho676, Ssang-Goo Cho650, William C Cho982, Yong-Yeon Cho105,
\nYoung-Seok Cho1064, Augustine MK Choi2095, Eui-Ju Choi656, Eun-Kyoung Choi387,400,685, Jayoung Choi1563,
\nMary E Choi2093, Seung-Il Choi2116, Tsui-Fen Chou412, Salem Chouaib395, Divaker Choubey1574, Vinay Choubey1936,
\nKuan-Chih Chow822, Kamal Chowdhury730, Charleen T Chu1856, Tsung-Hsien Chuang827, Taehoon Chun657,
\nHyewon Chung652, Taijoon Chung978, Yuen-Li Chung1194, Yong-Joon Chwae18, Valentina Cianfanelli254,
\nRoberto Ciarcia1775, Iwona A Ciechomska886, Maria Rosa Ciriolo1876, Mara Cirone1042, Sofie Claerhout1694,
\nMichael J Clague1698, Joan Cl aria1457, Peter GH Clarke1687, Robert Clarke361, Emilio Clementi1045,1398, C edric Cleyrat1781,
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\nDavid Colecchia235,567,577, Luisa Coletto25, N uria S Coll123, Emma Colucci-Guyon516, Sergio Comincini1829,
\nMaria Condello578, Katherine L Cook2073, Graham H Coombs1929, Cynthia D Cooper2076, J Mark Cooper1395,
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\nPaola Costelli1993, Safia Costes1518, Susan L Cotman721, Ana Coto-Montes946, Sandra Cottet566,1688, Eduardo Couve1301,
\nLori R Covey1015, L Ashley Cowart762, Jeffery S Cox1536, Fraser P Coxon1427, Carolyn B Coyne1846, Mark S Cragg1919,
\nRolf J Craven1679, Tiziana Crepaldi1995, Jose L Crespo1300, Alfredo Criollo1285, Valeria Crippa558, Maria Teresa Cruz1576,
\nAna Maria Cuervo26, Jose M Cuezva1277, Taixing Cui1907, Pedro R Cutillas987, Mark J Czaja27, Maria F Czyzyk-Krzeska1572,
\nRuben K Dagda2068, Uta Dahmen1404, Chunsun Dai800, Wenjie Dai1187, Yun Dai2059, Kevin N Dalby1940,
\nLuisa Dalla Valle1822, Guillaume Dalmasso1340, Marcello D’Amelio557, Markus Damme188, Arlette Darfeuille-Michaud1340,
\nCatherine Dargemont950, Victor M Darley-Usmar1433, Srinivasan Dasarathy205, Biplab Dasgupta202, Srikanta Dash1254,
\nCrispin R Dass242, Hazel Marie Davey8, Lester M Davids1560, David D avila227, Roger J Davis1731, Ted M Dawson604,
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInterparticle Coupling Effect on the Surface Plasmon Resonance of Gold Nanoparticles: From Theory to ApplicationsSujit Kumar Ghosh and Tarasankar PalView Author Information Department of Chemistry, Raidighi College, Raidighi-743383, South 24-Parganas, India, and Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India Cite this: Chem. Rev. 2007, 107, 11, 4797–4862Publication Date (Web):November 14, 2007Publication History Received3 November 2006Published online14 November 2007Published inissue 1 November 2007https://pubs.acs.org/doi/10.1021/cr0680282https://doi.org/10.1021/cr0680282research-articleACS PublicationsCopyright © 2007 American Chemical SocietyRequest reuse permissionsArticle Views41633Altmetric-Citations2303LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Aggregation,Gold,Metal nanoparticles,Nanoparticles,Plasmonic nanoparticles Get e-Alerts

The metaverse has the potential to extend the physical world using augmented and virtual reality technologies allowing users to seamlessly interact within real and simulated environments using avatars and holograms. Virtual environments and immersive games (such as, Second Life, Fortnite, Roblox and VRChat) have been described as antecedents of the metaverse and offer some insight to the potential socio-economic impact of a fully functional persistent cross platform metaverse. Separating the hype and “meta…” rebranding from current reality is difficult, as “big tech” paints a picture of the transformative nature of the metaverse and how it will positively impact people in their work, leisure, and social interaction. The potential impact on the way we conduct business, interact with brands and others, and develop shared experiences is likely to be transformational as the distinct lines between physical and digital are likely to be somewhat blurred from current perceptions. However, although the technology and infrastructure does not yet exist to allow the development of new immersive virtual worlds at scale - one that our avatars could transcend across platforms, researchers are increasingly examining the transformative impact of the metaverse. Impacted sectors include marketing, education, healthcare as well as societal effects relating to social interaction factors from widespread adoption, and issues relating to trust, privacy, bias, disinformation, application of law as well as psychological aspects linked to addiction and impact on vulnerable people. This study examines these topics in detail by combining the informed narrative and multi-perspective approach from experts with varied disciplinary backgrounds on many aspects of the metaverse and its transformational impact. The paper concludes by proposing a future research agenda that is valuable for researchers, professionals and policy makers alike.

The ‘4 per mille Soils for Food Security and Climate’ was launched at the COP21 with an aspiration to increase global soil organic matter stocks by 4 per 1000 (or 0.4 %) per year as a compensation for the global emissions of greenhouse gases by anthropogenic sources. This paper surveyed the soil organic carbon (SOC) stock estimates and sequestration potentials from 20 regions in the world (New Zealand, Chile, South Africa, Australia, Tanzania, Indonesia, Kenya, Nigeria, India, China Taiwan, South Korea, China Mainland, United States of America, France, Canada, Belgium, England & Wales, Ireland, Scotland, and Russia). We asked whether the 4 per mille initiative is feasible for the region. The outcomes highlight region specific efforts and scopes for soil carbon sequestration. Reported soil C sequestration rates globally show that under best management practices, 4 per mille or even higher sequestration rates can be accomplished. High C sequestration rates (up to 10 per mille) can be achieved for soils with low initial SOC stock (topsoil less than 30 t C ha− 1), and at the first twenty years after implementation of best management practices. In addition, areas which have reached equilibrium will not be able to further increase their sequestration. We found that most studies on SOC sequestration only consider topsoil (up to 0.3 m depth), as it is considered to be most affected by management techniques. The 4 per mille number was based on a blanket calculation of the whole global soil profile C stock, however the potential to increase SOC is mostly on managed agricultural lands. If we consider 4 per mille in the top 1m of global agricultural soils, SOC sequestration is between 2-3 Gt C year− 1, which effectively offset 20–35% of global anthropogenic greenhouse gas emissions. As a strategy for climate change mitigation, soil carbon sequestration buys time over the next ten to twenty years while other effective sequestration and low carbon technologies become viable. The challenge for cropping farmers is to find disruptive technologies that will further improve soil condition and deliver increased soil carbon. Progress in 4 per mille requires collaboration and communication between scientists, farmers, policy makers, and marketeers.

This correspondence discusses an extension of the well-known phase correlation technique to cover translation, rotation, and scaling. Fourier scaling properties and Fourier rotational properties are used to find scale and rotational movement. The phase correlation technique determines the translational movement. This method shows excellent robustness against random noise.

Highly photoluminescent carbon dots with a PL quantum yield of 26% have been prepared in one step by hydrothermal treatment of orange juice. Due to high photostability and low toxicity these carbon dots are demonstrated as excellent probes in cellular imaging.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrophilicity IndexPratim Kumar Chattaraj, Utpal Sarkar, and Debesh Ranjan RoyView Author Information Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India Cite this: Chem. Rev. 2006, 106, 6, 2065–2091Publication Date (Web):May 25, 2006Publication History Received12 August 2005Published online25 May 2006Published inissue 1 June 2006https://pubs.acs.org/doi/10.1021/cr040109fhttps://doi.org/10.1021/cr040109fresearch-articleACS PublicationsCopyright © 2006 American Chemical SocietyRequest reuse permissionsArticle Views7269Altmetric-Citations1377LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Electrical energy,Hardness,Molecules,Reactivity,Substitution reactions Get e-Alerts

SymPy is an open source computer algebra system written in pure Python. It is built with a focus on extensibility and ease of use, through both interactive and programmatic applications. These characteristics have led SymPy to become a popular symbolic library for the scientific Python ecosystem. This paper presents the architecture of SymPy, a description of its features, and a discussion of select submodules. The supplementary material provide additional examples and further outline details of the architecture and features of SymPy.

Summary Internet of Things (IoT) aims to bring every object (eg, smart cameras, wearable, environmental sensors, home appliances, and vehicles) online, hence generating massive volume of data that can overwhelm storage systems and data analytics applications. Cloud computing offers services at the infrastructure level that can scale to IoT storage and processing requirements. However, there are applications such as health monitoring and emergency response that require low latency, and delay that is caused by transferring data to the cloud and then back to the application can seriously impact their performances. To overcome this limitation, Fog computing paradigm has been proposed, where cloud services are extended to the edge of the network to decrease the latency and network congestion. To realize the full potential of Fog and IoT paradigms for real‐time analytics, several challenges need to be addressed. The first and most critical problem is designing resource management techniques that determine which modules of analytics applications are pushed to each edge device to minimize the latency and maximize the throughput. To this end, we need an evaluation platform that enables the quantification of performance of resource management policies on an IoT or Fog computing infrastructure in a repeatable manner. In this paper we propose a simulator, called iFogSim , to model IoT and Fog environments and measure the impact of resource management techniques in latency, network congestion, energy consumption, and cost. We describe two case studies to demonstrate modeling of an IoT environment and comparison of resource management policies. Moreover, scalability of the simulation toolkit of RAM consumption and execution time is verified under different circumstances.

This paper reviews the first challenge on single image super-resolution (restoration of rich details in an low resolution image) with focus on proposed solutions and results. A new DIVerse 2K resolution image dataset (DIV2K) was employed. The challenge had 6 competitions divided into 2 tracks with 3 magnification factors each. Track 1 employed the standard bicubic downscaling setup, while Track 2 had unknown downscaling operators (blur kernel and decimation) but learnable through low and high res train images. Each competition had ∽100 registered participants and 20 teams competed in the final testing phase. They gauge the state-of-the-art in single image super-resolution.

‘Water is life,’ so central to human life, yet over one billion people across the world have no access to safe drinking water. Of late, there has been increasing global attention focused on resolving water quality problems especially in developing countries, as the lack of access to clean water denies the most essential of all rights, the right to life. The latest estimates suggest that around 200 million people, from among 25 nations the world over, are under the dreadful fate of fluorosis. India and China, the two most populous countries of the world, are the worst affected. India is plagued with numerous water quality problems due to prolific contaminants mainly of geogenic origin and fluoride stands first among them. The weathering of primary rocks and leaching of fluoride-containing minerals in soils yield fluoride rich groundwater in India which is generally associated with low calcium content and high bicarbonate ions. The unfettered ground water tapping exacerbates the failure of drinking water sources and accelerates the entry of fluoride into groundwater. Most of the scientific literature substantiates the benefits of low fluoride concentrations in preventing dental decay. However, as a surprising paradox, incidence of dental, skeletal and crippling skeletal fluorosis was reported in India with average fluoride concentrations as low as 0.5, 0.7 and 2.8 ppm respectively. Fluorosis, turns out to be the most widespread geochemical disease in India, affecting more than 66 million people including 6 million children under 14 years age. Though fluoride has spread its tentacles in 36,988 habitations and the number of people falling prey to fluoride poisoning have been steadily increasing, an exact exposure-health relationship is yet to be properly elucidated. There is an essential relation between poverty and fluorosis as malnutrition is found to play an aggressive role in its severity.

This review is focused on the origin of dye pollutants, their ecotoxicological effects and adsorptive removal using various types of adsorbents.

This article reports or, the international Nanofluid Property Benchmark Exercise, or INPBE. in which the thermal conductivity of identical samples of colloidally stable dispersions of nanoparticles or "nanofluids", was measured by over 30 organizations worldwide, using, a variety of experimental approaches, including the transient hot wire method, steady-state methods, and optical methods. The nanofluids tested in the exercise were comprised of aqueous and nonaqueous basefluids, metal and metal oxide particles, near-spherical and elongated particles, at low and high particle concentrations. The data analysis reveals that the data from most organizations lie within a relatively narrow band (+/- 10% or less) about the sample average with only few outliers. The thermal conductivity of the nanofluids was found to increase with particle concentration and aspect ratio. as expected from classical theory. There are (small) systematic differences in the absolute values of the nanofluid thermal conductivity among the various experimental approaches; however. such differences tend to disappear when the data are normalized to the Measured thermal conductivity of the basefluid. The effective medium theory developed for dispersed particles by Maxwell in 1881 and recently generalized by Nan et al. [J. Appl. Phys. 81, 6692 (1997)], was found to be in good agreement with the experimental data, suggesting that no anomalous enhancement of thermal conductivity was achieved in the nanofluids tested in this exercise.

The December 2011 release of a draft United States Food and Drug Administration (FDA) guidance concerning regulatory classification of pharmaceutical cocrystals of active pharmaceutical ingredients (APIs) addressed two matters of topical interest to the crystal engineering and pharmaceutical science communities: (1) a proposed definition of cocrystals; (2) a proposed classification of pharmaceutical cocrystals as dissociable ``API-excipient'' molecular complexes. The Indo U.S. Bilateral Meeting sponsored by the Indo-U.S. Science and Technology Forum titled The Evolving Role of Solid State Chemistry in Pharmaceutical Science was held in Manesar near Delhi, India, from February 2-4, 2012. A session of the meeting was devoted to discussion of the FDA guidance draft. The debate generated strong consensus on the need to define cocrystals more broadly and to classify them like salts. It was also concluded that the diversity of API crystal forms makes it difficult to classify solid forms into three categories that are mutually exclusive. This perspective summarizes the discussion in the Indo-U.S. Bilateral Meeting and includes contributions from researchers who were not participants in the meeting.

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Silver and gold nanoparticles have been grown on calcium alginate gel beads using a green photochemical approach. The gel served as both a reductant and a stabilizer. The nanoparticles were characterized using UV-visible spectroscopy, X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM), energy dispersive X-ray (EDS), and selected area electron diffraction (SAED) analyses. The particles are spherical, crystalline, and the size ranges for both Ag and Au nanoparticles are <10 nm. It is noticed from the sorption experiment that the loading of gold on calcium alginate beads is much more compared to that of Ag. The effectiveness of the as-prepared dried alginate-stabilized Ag and Au nanoparticles as a solid phase heterogeneous catalyst has been evaluated, for the first time, on the well-known 4-nitrophenol (4-NP) reduction to 4-aminophenol (4-AP) in the presence of excess borohydride. The reduction was very efficient and followed zero-order kinetics for both Ag and Au nanocomposites. The effects of borohydride, initial 4-NP concentration, and catalyst dose were evaluated. The catalyst efficiency was examined on the basis of turnover frequency (TOF) and recyclability. The catalytic efficiency of alginate-based Ag catalyst was much more compared to that of the Au catalyst. The as-prepared new solid-phase biopolymer-based catalysts are very efficient, stable, easy to prepare, eco-friendly, and cost-effective, and they have the potential for industrial applications.

An outbreak of deadly COVID-19 virus has not only taken the lives of people but also severely crippled the economy. Due to strict lockdown, the manufacturing and logistics activities have been suspended, and it has affected the demand and supply of various products as a result of restrictions imposed on shopkeepers and retailers. Impacts of COVID-19 are observed ubiquitously in every type of units from different sectors. In this study, a simulation model of the public distribution system (PDS) network is developed with three different scenarios to demonstrate disruptions in the food supply chain. Difficulties have been increased in matching supply and demand in a vast network of PDS because of changing scenarios with the growth of infected cases and recovery. This paper also highlights the importance of a resilient supply chain during a pandemic. Our proposed simulation model can help in developing a resilient and responsive food supply chain to match the varying demand, and then further assist in providing decision-making support for rerouting the vehicles as per travel restrictions in areas. Paper has been summarised with significant highlights and including future research scope for developing a more robust food supply chain network.&#13;\n&#13;\n

Visible light-active TiO2 (m-TiO2) nanoparticles were obtained by an electron beam treatment of commercial TiO2 (p-TiO2) nanoparticles. The m-TiO2 nanoparticles exhibited a distinct red-shift in the UV-visible absorption spectrum and a much narrower band gap (2.85 eV) due to defects as confirmed by diffuse reflectance spectroscopy (DRS), photoluminescence (PL), X-ray diffraction, Raman spectroscopy, electron paramagnetic resonance, transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS) and linear scan voltammetry (LSV). The XPS revealed changes in the surface states, composition, Ti4+ to Ti3+ ratio, and oxygen deficiencies in the m-TiO2. The valence band XPS, DRS and PL results were carefully examined to understand the band gap reduction of m-TiO2. The visible light-responsive enhanced photocatalytic activity of m-TiO2 was demonstrated by degrading methylene blue and brilliant blue G. The EIS and LSV in the dark and under visible light irradiation further support the visible light-induced photocatalytic activities of the m-TiO2 due to a decrease in electron transfer resistance and an increase in photocurrent. This study confirms that m-TiO2 can be used effectively as a photocatalyst and photoelectrode material owing to its enhanced visible light-induced photocatalytic activity.

A generalized concept of philicity is introduced through a resolution of identity, encompassing electrophilic, nucleophilic, and radial reactions. Locally, a particular molecular site may be more prone to electrophilic attack or another may be more prone to nucleophilic attack, but the overall philicity of the whole molecule remains conserved. Local philicity is by far the most powerful concept of reactivity and selectivity when compared to the global electrophilicity index, Fukui function, local softness, or global softness because it contains information about almost all of the known global and local descriptors of chemical reactivity and selectivity.