The Dodd-Walls Centre for Photonic and Quantum Technologies

The discovery of the enhancement of Raman scattering by molecules adsorbed on nanostructured metal surfaces is a landmark in the history of spectroscopic and analytical techniques. Significant experimental and theoretical effort has been directed toward understanding the surface-enhanced Raman scattering (SERS) effect and demonstrating its potential in various types of ultrasensitive sensing applications in a wide variety of fields. In the 45 years since its discovery, SERS has blossomed into a rich area of research and technology, but additional efforts are still needed before it can be routinely used analytically and in commercial products. In this Review, prominent authors from around the world joined together to summarize the state of the art in understanding and using SERS and to predict what can be expected in the near future in terms of research, applications, and technological development. This Review is dedicated to SERS pioneer and our coauthor, the late Prof. Richard Van Duyne, whom we lost during the preparation of this article.

The quest towards the integration of ultra-fast, high-precision optical clocks is reflected in the large number of high-impact papers on the topic published in the last few years. This interest has been catalysed by the impact that high-precision optical frequency combs (OFCs) have had on metrology and spectroscopy in the last decade [ [1] , [2] , [3] , [4] , [5] ]. OFCs are often referred to as optical rulers: their spectra consist of a precise sequence of discrete and equally-spaced spectral lines that represent precise marks in frequency. Their importance was recognised worldwide with the 2005 Nobel Prize being awarded to T.W. Hänsch and J. Hall for their breakthrough in OFC science [ 5 ]. They demonstrated that a coherent OFC source with a large spectrum – covering at least one octave – can be stabilised with a self-referenced approach, where the frequency and the phase do not vary and are completely determined by the source physical parameters. These fully stabilised OFCs solved the challenge of directly measuring optical frequencies and are now exploited as the most accurate time references available, ready to replace the current standard for time. Very recent advancements in the fabrication technology of optical micro-cavities [ 6 ] are contributing to the development of OFC sources. These efforts may open up the way to realise ultra-fast and stable optical clocks and pulsed sources with extremely high repetition-rates, in the form of compact and integrated devices. Indeed, the fabrication of high-quality factor (high-Q) micro-resonators, capable of dramatically amplifying the optical field, can be considered a photonics breakthrough that has boosted not only the scientific investigation of OFC sources [ [8] , [13] , [11] , [12] , [10] , [7] , [9] ] but also of optical sensors and compact light modulators [ [14] , [6] ]. In this framework, the demonstration of planar high-Q resonators, compatible with silicon technology [ [14] , [13] , [11] , [12] , [10] ], has opened up a unique opportunity for these devices to provide entirely new capabilities for photonic-integrated technologies. Indeed, it is well acknowledged by the electronics industry that future generations of computer processing chips will inevitably require an extremely high density of copper-based interconnections, significantly increasing the chip power dissipation to beyond practical levels [ [15] , [16] , [17] ]; hence, conventional approaches to chip design must undergo radical changes. On-chip optical networks, or optical interconnects, can offer high speed and low energy per-transferred-bit, and micro-resonators are widely seen as a key component to interface the electronic world with photonics. Many information technology industries have recently focused on the development of integrated ring resonators to be employed for electrically-controlled light modulators [ [14] , [15] , [16] , [17] ], greatly advancing the maturity of micro-resonator technology as a whole. Recently [ [13] , [11] , [12] ], the demonstration of OFC sources in micro-resonators fabricated in electronic (i.e. in complementary metal oxide semiconductor (CMOS)) compatible platforms has given micro-cavities an additional appeal, with the possibility of exploiting them as light sources in microchips. This scenario is creating fierce competition in developing highly efficient OFC generators based on micro-cavities which can radically change the nature of information transport and processing. Even in telecommunications, perhaps a more conventional environment for optical technologies, novel time-division multiplexed optical systems will require extremely stable optical clocks at ultra-high pulse repetition-rates towards the THz scale. Furthermore, arbitrary pulse generators based on OFC [ [18] , [19] ] are seen as one of the most promising solutions for this next generation of high-capacity optical coherent communication systems. This review will summarise the recent exciting achievements in the field of micro-combs, namely optical frequency combs based on high-Q micro-resonators, with a perspective on both the potential of this technology, as well as the open questions and challenges that remain.

We review phase-space techniques based on the Wigner representation that provide an approximate description of dilute ultra-cold Bose gases. In this approach the quantum field evolution can be represented using equations of motion of a similar form to the Gross–Pitaevskii equation but with stochastic modifications that include quantum effects in a controlled degree of approximation. These techniques provide a practical quantitative description of both equilibrium and dynamical properties of Bose gas systems. We develop versions of the formalism appropriate at zero temperature, where quantum fluctuations can be important, and at finite temperature where thermal fluctuations dominate. The numerical techniques necessary for implementing the formalism are discussed in detail, together with methods for extracting observables of interest. Numerous applications to a wide range of phenomena are presented.

Soliton explosions are among the most exotic dissipative phenomena studied in mode-locked lasers. In this regime, a dissipative soliton circulating in the laser cavity experiences an abrupt structural collapse, but within a few roundtrips returns to its original quasi-stable state. In this Letter, we report on the first observation, to the best of our knowledge, of such events in a fiber laser. Specifically, we identify clear explosion signatures in measurements of shot-to-shot spectra of a Yb-doped mode-locked fiber laser that is operating in a transition regime between stable and noise-like emission. The comparatively long, all-normal-dispersion cavity used in our experiments also permits direct time-domain measurements, and we show that the explosions manifest themselves as abrupt temporal shifts in the output pulse train. Our experimental results are in good agreement with realistic numerical simulations based on an iterative cavity map.

We report experimental observations and numerical simulations of the formation, dynamics, and lifetimes of single and multiply charged quantized vortex dipoles in highly oblate dilute-gas Bose-Einstein condensates (BECs). We nucleate pairs of vortices of opposite charge (vortex dipoles) by forcing superfluid flow around a repulsive Gaussian obstacle within the BEC. By controlling the flow velocity we determine the critical velocity for the nucleation of a single vortex dipole, with excellent agreement between experimental and numerical results. We present measurements of vortex dipole dynamics, finding that the vortex cores of opposite charge can exist for many seconds and that annihilation is inhibited in our trap geometry. For sufficiently rapid flow velocities, clusters of like-charge vortices aggregate into long-lived multiply charged dipolar flow structures.

Optical whispering gallery modes (WGMs) derive their name from a famous acoustic phenomenon of guiding a wave by a curved boundary observed nearly a century ago.This phenomenon has a rather general nature, equally applicable to sound and all other waves.It enables resonators of unique properties attractive both in science and engineering.Very high quality factors of optical WGM resonators persisting in a wide wavelength range spanning from radio frequencies to ultraviolet light, their small mode volume, and tunable in-and out-coupling make them exceptionally efficient for nonlinear optical applications.Nonlinear optics facilitates interaction of photons with each other and with other physical systems, and is of prime importance in quantum optics.In this paper we review numerous applications of WGM resonators in nonlinear and quantum optics.We outline the current areas of interest, summarize progress, highlight difficulties, and discuss possible future development trends in these areas.

Roadmap on optical rogue waves and extreme events, Akhmediev, Nail, Kibler, Bertrand, Baronio, Fabio, Belić, Milivoj, Zhong, Wei-Ping, Zhang, Yiqi, Chang, Wonkeun, Soto-Crespo, Jose M, Vouzas, Peter, Grelu, Philippe, Lecaplain, Caroline, Hammani, K, Rica, S, Picozzi, A, Tlidi, Mustapha, Panajotov, Krassimir, Mussot, Arnaud, Bendahmane, Abdelkrim, Szriftgiser, Pascal, Genty, Goery, Dudley, John, Kudlinski, Alexandre, Demircan, Ayhan, Morgner, Uwe, Amiraranashvili, Shalva, Bree, Carsten, Steinmeyer, Günter, Masoller, C, Broderick, Neil G R, Runge, Antoine F J, Erkintalo, Miro, Residori, S, Bortolozzo, U, Arecchi, F T, Wabnitz, Stefan, Tiofack, C G, Coulibaly, S, Taki, M

Polarization-based optical techniques have become increasingly popular in the field of biomedical diagnosis. In the current report we exploit the directional awareness of circularly and/or elliptically polarized light backscattered from turbid tissue-like scattering media. We apply circularly and elliptically polarized laser light which illuminates the samples of interest, and a standard optical polarimeter is used to observe the polarization state of light backscattered a few millimeters away from the point of incidence. We demonstrate that the Stokes vector of backscattered light depicted on a Poincaré sphere can be used to assess a turbid tissue-like scattering medium. By tracking the Stokes vector of the detected light on the Poincaré sphere, we investigate the utility of this approach for characterization of cancerous and non-cancerous tissue samples in vitro. The obtained results are discussed in the framework of a phenomenological model and the results of a polarization tracking Monte Carlo model, developed in house. Schematic illustration of the experimental approach utilizing circularly and elliptically polarized light for probing turbid tissue-like scattering media.

Reversible addition-fragmentation chain-transfer (RAFT) polymerization is a valuable tool for synthesizing macromolecules with controlled topologies and diverse chemical functionalities. However, the application of RAFT polymerization to additive-manufacturing processes has been prevented due to the slow polymerization rates of typical systems. In this work, we developed and optimized a rapid visible (green) light mediated RAFT polymerization process and applied it to an open-air 3D printing system. The reaction components are non-toxic, metal free and environmentally friendly, which tailors these systems toward biomaterial fabrication. The inclusion of RAFT agent in the photosensitive resin provided control over the mechanical properties of 3D printed materials and allowed these materials to be post-functionalized after 3D printing. Additionally, photoinduced spatiotemporal control of the network structure provided a one-pass approach to 4D printed materials. This RAFT-mediated 3D and 4D printing process should provide access to a range of new functional and stimuli-responsive materials.

Clustering vortices Many-body systems generally become more disordered as more energy is pumped into them. A curious exception to this rule was predicted in the context of turbulent flow by the physical chemist Lars Onsager. He suggested that the entropy of certain two-dimensional (2D) systems can decrease with increasing energy, corresponding to an effective negative temperature. Using 2D Bose-Einstein condensates of atoms, Gauthier et al. and Johnstone et al. put Onsager's theory to the test. They provided energy to the system by perturbing the condensate, creating vortices and antivortices. With increasing energy, the system became more ordered as clusters containing either only vortices or only antivortices emerged. Science , this issue p. 1264 , p. 1267

We consider the ground state properties of a trapped dipolar condensate under the influence of quantum fluctuations. We show that this system can undergo a phase transition from a low density condensate state to a high density droplet state, which is stabilized by quantum fluctuations. The energetically favored state depends on the geometry of the confining potential, the number of atoms, and the two-body interactions. We develop a simple variational ansatz and validate it against full numerical solutions. We produce a phase diagram for the system and present results relevant to current experiments with dysprosium and erbium condensates.

Theorists show that large photon fluxes can result in the breakdown of photon blockade, an analogy to Coulomb blockade for quantum-well electrons. This breakdown is due to a quantum phase transition in zero dimensions.

We propose a device for the reversible and quiet conversion of microwave photons to optical sideband photons that can reach 100% quantum efficiency. The device is based on an erbium-doped crystal placed in both an optical and microwave resonator. We show that efficient conversion can be achieved so long as the product of the optical and microwave cooperativity factors can be made large. We argue that achieving this regime is feasible with current technology and we discuss a possible implementation.

Optical tweezers use laser light to trap and move microscopic particles in space. Here we demonstrate a similar control over ultrashort light pulses, but in time. Our experiment involves temporal cavity solitons that are stored in a passive loop of optical fibre pumped by a continuous wave ‘holding’ laser beam. The cavity solitons are trapped into specific time slots through a phase modulation of the holding beam, and moved around in time by manipulating the phase profile. We report both continuous and discrete manipulations of the temporal positions of picosecond light pulses, with the ability to simultaneously and independently control several pulses within a train. We also study the transient drifting dynamics and show complete agreement with theoretical predictions. Our study demonstrates how the unique particle-like characteristics of cavity solitons can be leveraged to achieve unprecedented control over light. These results could have significant ramifications for optical information processing. Optical tweezing typically refers to the trapping and manipulation of particles using lasers. Here, Jang et al. demonstrate analogous manipulation of ultrashort cavity soliton-pulses in the time domain, trapped by the phase modulation of a continuous wave laser beam, and moved by modifying the phase profile.

A liquid droplet is a self-bound phase of matter that holds itself together in the absence of a container. Without a container a gas will normally expand to fill space. A method is proposed to produce a self-bound dilute quantum gaseous dipolar Bose-Einstein condensate.

Fluids subjected to suitable forcing will exhibit turbulence, with characteristics strongly affected by the fluid's physical properties and dimensionality. In this work, we explore two-dimensional (2D) quantum turbulence in an oblate Bose-Einstein condensate confined to an annular trapping potential. Experimentally, we find conditions for which small-scale stirring of the condensate generates disordered 2D vortex distributions that dissipatively evolve toward persistent currents, indicating energy transport from small to large length scales. Simulations of the experiment reveal spontaneous clustering of same-circulation vortices and an incompressible energy spectrum with k(-5/3) dependence for low wave numbers k. This work links experimentally observed vortex dynamics with signatures of 2D turbulence in a compressible superfluid.

Rapid antimicrobial susceptibility testing is needed to reduce prescription of inappropriate antibiotics. A rapid alternative to standard culture-based testing is to determine reductions in cell viability using the LIVE/DEAD® BacLightTM Bacterial Viability Kit. We optimised the kit protocol for this application, focusing on simplifying the process by minimising the steps involved and on determining the optimal analytical parameters for fluorescence measurements from the dyes SYTO 9 and propidium iodide (PI). We demonstrate that for our experimental system, the intensity of emissions should be integrated from 505-515 nm for SYTO 9 and 600-610 nm for PI, and the proportion of live cells calculated from a new dye ratio formula, termed the adjusted dye ratio. We show that the pre-staining washing step is not necessary if a non-fluorescent growth media is used; however, staining must be done for each sampling as prolonged exposure to the dyes negatively impacts cell viability. The optimised methodology was able to reproducibly detect reductions in culture viability when the proportion of live cells in a sample of 1 × 108 cells/ml fell below ~ 50% live in a media that supports the growth required for detecting antibiotic killing. Finally, we show that the interaction of fluorescence emission spectra from SYTO 9 and PI stained E. coli cells is influenced by the proportion of dead cells in a sample. The excitation of PI by SYTO 9 was found to occur in populations containing sufficient numbers of dead cells (> 25%), whereas in populations with low numbers of dead cells the dye interaction was additive in regard to red emissions, indicating that these dye interactions may offer another dimension to live/dead analysis. Fluorescence measurements from samples established according to the optimised protocol can be taken using a flow cytometer, spectrofluorometer, microplate reader, and the Optrode, a fibre-based spectroscopic system developed at the University of Auckland.

The Dicke model is a paradigm of collective behavior in quantum mechanics describing an ensemble of two-level atoms interacting with a single mode of the electromagnetic field. Here we simulate a spin-1 Dicke model using magnetic sublevels of the lowest =1 hyperfine level of 87Rb atoms confined to a high finesse cavity. Our implementation enables simple tuning of the model parameters over a large parameter space. We study this system under conditions of imbalanced driving, which is predicted to have a rich phase diagram of nonequilibrium phases and phase transitions. Exploring the system over a wide range of parameters, we obtain boundaries between normal, super-radiant, and oscillatory phases, and compare with a simple theoretical model. This study provides further understanding of the fundamental nature of the model and has technological applications such as superradiant lasers and storage of quantum information in collective atomic states.

Bright solitons are non-dispersive wave solutions, arising in a diverse range of nonlinear, one-dimensional systems, including atomic Bose-Einstein condensates with attractive interactions. In reality, cold-atom experiments can only approach the idealized one-dimensional limit necessary for the realization of true solitons. Nevertheless, it remains possible to create bright solitary waves, the three-dimensional analogue of solitons, which maintain many of the key properties of their one-dimensional counterparts. Such solitary waves offer many potential applications and provide a rich testing ground for theoretical treatments of many-body quantum systems. Here we report the controlled formation of a bright solitary matter-wave from a Bose-Einstein condensate of (85)Rb, which is observed to propagate over a distance of ∼1.1 mm in 150 ms with no observable dispersion. We demonstrate the reflection of a solitary wave from a repulsive Gaussian barrier and contrast this to the case of a repulsive condensate, in both cases finding excellent agreement with theoretical simulations using the three-dimensional Gross-Pitaevskii equation.

Organic photovoltaics (OPVs) promise cheap and flexible solar energy. Whereas light generates free charges in silicon photovoltaics, excitons are normally formed in organic semiconductors due to their low dielectric constants, and require molecular heterojunctions to split into charges. Recent record efficiency OPVs utilise the small molecule, Y6, and its analogues, which - unlike previous organic semiconductors - have low band-gaps and high dielectric constants. We show that, in Y6 films, these factors lead to intrinsic free charge generation without a heterojunction. Intensity-dependent spectroscopy reveals that 60-90% of excitons form free charges at AM1.5 light intensity. Bimolecular recombination, and hole traps constrain single component Y6 photovoltaics to low efficiencies, but recombination is reduced by small quantities of donor. Quantum-chemical calculations reveal strong coupling between exciton and CT states, and an intermolecular polarisation pattern that drives exciton dissociation. Our results challenge how current OPVs operate, and renew the possibility of efficient single-component OPVs.