Regio‐ and Stereoselective Olefination of Phenol Carbamates through C–H Bond Functionalization

Li, Bin; Ma, Jianfeng; Liang, Yujie; Wang, Nuancheng; Xu, Shansheng; Song, Haibin; Wang, Baiquan

doi:10.1002/ejoc.201201574

Public

Regio‐ and Stereoselective Olefination of Phenol Carbamates through C–H Bond Functionalization

Published in European Journal of Organic Chemistry • Feb 12, 2013

Authors:

Bin Li

Jianfeng Ma

Yujie Liang

Abstract

Abstract Two pathways that can be used to access ortho ‐olefinated phenol carbamate, including a ruthenium(II)‐catalyzed oxidative olefination of phenol carbamate with acrylates and a rhodium(III)‐catalyzed alkyne hydroarylation of phenol carbamate with internal alkynes through direct C–H activation...

Subject

Chemistry

Carbamate

Stereoselectivity

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