Remendable thermosetting polymers for isocyanate-free adhesives: a preliminary study

Dolci, Elena; Michaud, Guillaume; Simon, Frédéric; Boutevin, Bernard; Fouquay, Stéphane; Caillol, Sylvain

doi:10.1039/c5py01213a

Public

Remendable thermosetting polymers for isocyanate-free adhesives: a preliminary study

Published in Polymer Chemistry • Jan 1, 2015

Authors:

Elena Dolci

Guillaume Michaud

Frédéric Simon

Abstract

Based on a model study, a new bis-cyclic monomer bearing a Diels–Alder adduct was synthesized. This monomer was polymerized with a diamine to yield a thermoresponsive polyhydroxyurethane (PHU). This PHU is remendable at around 100 °C by retro Diels–Alder reaction.

Subject

Thermosetting polymer

Monomer

Isocyanate

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