Occurrence of a Rare 49·66 Structural Topology, Chirality, and Weak Ferromagnetism in the [NH4][MII(HCOO)3] (M = Mn, Co, Ni) Frameworks

Wang, Zhe‐Ming; Zhang, Bin; Inoue, Katsuya; Fujiwara, Hideki; Otsuka, Takeo; Kobayashi, Hayao; Kurmoo, Mohamedally

doi:10.1021/ic0610031

Public

Occurrence of a Rare 49·66 Structural Topology, Chirality, and Weak Ferromagnetism in the [NH4][MII(HCOO)3] (M = Mn, Co, Ni) Frameworks

Published in Inorganic Chemistry • Dec 14, 2006

Authors:

Zhe‐Ming Wang

Bin Zhang

Katsuya Inoue

Abstract

We report the synthesis, crystal structures, thermal, IR, UV-vis, and magnetic properties of a series of divalent transition metal formates, [NH4][M(HCOO)3], where M = divalent Mn, Co, or Ni. They crystallize in the hexagonal chiral space group P6(3)22. The structure consists of octahedral metal cen...

Subject

Chemistry

Crystallography

Magnetization

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