Iridium Complexes with<i>N</i>-Allyl-Substituted Benzimidazol-2-ylidene Ligands and Their Application in Catalytic Transfer Hydrogenation

Ekkehardt Hahn, F.; Holtgrewe, C.; Pape, Tania; Martı́n, Marta; Sola, Eduardo; A. Oro, Luis

doi:10.1021/om0500873

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Iridium Complexes withN-Allyl-Substituted Benzimidazol-2-ylidene Ligands and Their Application in Catalytic Transfer Hydrogenation

Shared by NobleBlocks on Mar 31, 2005 • 12:00 AM UTC

Authors:

F. Ekkehardt Hahn

C. Holtgrewe

Tania Pape

Abstract

The reactions of [Ir(μ-OMe)(cod)]2 with the N-allyl-substituted benzimidazolium salts 1-methyl-3-(2-propenyl)benzimidazolium iodide (2) and 1,3-di(2-propenyl)benzimidazolium bromide (3) have been found to afford the five-coordinated Ir(I) complexes [IrX(cod)(η2-C-NHC)] (X = I, NHC = 1-methyl-3-(2-pr...

Subject

Chemistry

Iridium

Propenyl

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