Kinetics and Mechanism of Controlled Free-Radical Polymerization of Styrene and <i>n</i>-Butyl Acrylate in the Presence of an Acyclic β-Phosphonylated Nitroxide

Benoit, Didier; Grimaldi, Sandra; Robin, Sophie; Finet, Jean‐Pierre; Tordo, Paul; Gnanou, Yves

doi:10.1021/ja991735a

Public

Kinetics and Mechanism of Controlled Free-Radical Polymerization of Styrene and n-Butyl Acrylate in the Presence of an Acyclic β-Phosphonylated Nitroxide

Published in Journal of the American Chemical Society • Jun 1, 2000

Authors:

Didier Benoit

Sandra Grimaldi

Sophie Robin

Abstract

This study investigates the kinetics of free radical polymerization of styrene and n -butyl acrylate carried out in the presence of N - tert -butyl- N -[1-diethylphosphono-(2,2-dimethylpropyl)] nitroxide (DEPN). With this stable radical as chain growth moderator, it is demonstrated that the polymeri...

Subject

Chemistry

Nitroxide mediated radical polymerization

Polymerization

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