Hybrid Polyoxotungstate/MIL-101 Materials: Synthesis, Characterization, and Catalysis of H<sub>2</sub>O<sub>2</sub>-Based Alkene Epoxidation

V. Maksimchuk, Nataliya; A. Kovalenko, Konstantin; S. Arzumanov, Sergey; A. Chesalov, Yu.; S. Mel’gunov, Maxim; G. Stepanov, Alexander; P. Fedin, Vladimir; A. Kholdeeva, Oxana

doi:10.1021/ic902459f

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Hybrid Polyoxotungstate/MIL-101 Materials: Synthesis, Characterization, and Catalysis of H2O2-Based Alkene Epoxidation

Published in Inorganic Chemistry • Feb 18, 2010

Authors:

Nataliya V. Maksimchuk

Konstantin A. Kovalenko

Sergey S. Arzumanov

Abstract

Polyoxotungstates [PW(4)O(24)](3-) (PW(4)) and [PW(12)O(40)](3-) (PW(12)) have been inserted into nanocages of the metal organic framework MIL-101. The hybrid materials PW(x)/MIL-101 (x = 4 or 12) containing 5-14 wt % of polyoxotungstate have been obtained and characterized by elemental analysis, N(...

Subject

Chemistry

Alkene

Catalysis

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