Nuclear Spin Driven Quantum Tunneling of Magnetization in a New Lanthanide Single-Molecule Magnet:  Bis(Phthalocyaninato)holmium Anion

Ishikawa, Naoto; Sugita, Miki; Wernsdorfer, Wolfgang

doi:10.1021/ja0428661

Public

Nuclear Spin Driven Quantum Tunneling of Magnetization in a New Lanthanide Single-Molecule Magnet: Bis(Phthalocyaninato)holmium Anion

Published in Journal of the American Chemical Society • Feb 23, 2005

Authors:

Naoto Ishikawa

Miki Sugita

Wolfgang Wernsdorfer

Abstract

The first measurements of magnetization hysteresis loops on a diluted single crystal of [(Pc)2Ho]-.TBA+ (Pc = phthalocyaninato, TBA = tetrabutylammonium) in the subkelvin temperature range are reported. Characteristic staircase-like structure was observed, indicating the occurrence of the quantum tu...

Subject

Lanthanide

Magnetization

Chemistry

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