Million-Fold Electrical Conductivity Enhancement in Fe<sub>2</sub>(DEBDC) versus Mn<sub>2</sub>(DEBDC) (E = S, O)

Sun, Lei; H. Hendon, Christopher; A. Minier, Mikael; Walsh, Aron; Dincă, Mircea

doi:10.1021/jacs.5b02897

Public

Million-Fold Electrical Conductivity Enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)

Published in Journal of the American Chemical Society • May 1, 2015

Authors:

Lei Sun

Christopher H. Hendon

Mikael A. Minier

Abstract

Reaction of FeCl2 and H4DSBDC (2,5-disulfhydrylbenzene-1,4-dicarboxylic acid) leads to the formation of Fe2(DSBDC), an analogue of M2(DOBDC) (MOF-74, DOBDC(4-) = 2,5-dihydroxybenzene-1,4-dicarboxylate). The bulk electrical conductivity values of both Fe2(DSBDC) and Fe2(DOBDC) are ∼6 orders of magnit...

Subject

Chemistry

Fold (higher-order function)

Electrical resistivity and conductivity

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