Hexacyanometalate Molecular Chemistry: Heptanuclear Heterobimetallic Complexes; Control of the Ground Spin State

Following a bottom-up approach to nanomaterials, we present a rational synthetic route from hexacyanometalates [M(CN)(6)](3-) (M=Cr(III), Co(III)) cores to well-defined heptanuclear complexes. By changing the nature of the metallic cations and using a localised orbital model it is possible to contro... View More