High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites

Lin, Xiang; Telepeni, I.; J. Blake, Alexander; Dailly, Anne; M. Brown, Craig; M. Simmons, Jason; Zoppi, Marco; S. Walker, Gavin; Mark Thomas, K.; J. Mays, Timothy; Hubberstey, Peter; R. Champness, Neil; Schröder, Martin

doi:10.1021/ja806624j

Public

High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites

Published in Journal of the American Chemical Society • Jan 21, 2009

Authors:

Xiang Lin

I. Telepeni

Alexander J. Blake

Abstract

A series of isostructural metal-organic framework polymers of composition [Cu2(L)(H2O)2] (L= tetracarboxylate ligands), denoted NOTT-nnn, has been synthesized and characterized. Single crystal X-ray structures confirm the complexes to contain binuclear Cu(II) paddlewheel nodes each bridged by four c...

Subject

Chemistry

Adsorption

Isostructural

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