Preparation, Crystal Structures, and Magnetic Features for a Series of Dinuclear [NiIILnIII] Schiff-Base Complexes: Evidence for Slow Relaxation of the Magnetization for the DyIII Derivative

Pasatoiu, T.D.; Sutter, Jean‐Pascal; M. Mădălan, Augustin; Fellah, F.Z.C.; Duhayon, Carine; Andruh, Marius

doi:10.1021/ic2004276

Public

Preparation, Crystal Structures, and Magnetic Features for a Series of Dinuclear [NiIILnIII] Schiff-Base Complexes: Evidence for Slow Relaxation of the Magnetization for the DyIII Derivative

Published in Inorganic Chemistry • Jun 2, 2011

Authors:

T.D. Pasatoiu

Jean‐Pascal Sutter

Augustin M. Mădălan

Abstract

A series of dinuclear [Ni(II)Ln(III)] Schiff-base complexes (using a Schiff-base dicompartmental ligand derived from o-vanillin [H(2)valpn = 1,3-propanediylbis(2-iminomethylene-6-methoxy-phenol)]) with Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and a hydroxo-bridged tetranuclear [Ni(II)Yb(III)...

Subject

Chemistry

Crystallography

Antiferromagnetism

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