Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts

Victoria Jiménez, M.; Fernández‐Tornos, Javier; J. Pérez‐Torrente, Jesús; Javier Modrego, F.; Winterle, S.; Cunchillos, C.; J. Lahoz, Fernando; A. Oro, Luis

doi:10.1021/om200747k

Public

Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts

Published in Organometallics • Sep 23, 2011

Authors:

M. Victoria Jiménez

Javier Fernández‐Tornos

Jesús J. Pérez‐Torrente

Abstract

A series of neutral and cationic rhodium and iridium(I) complexes based on hemilabile O-donor- and N-donor-functionalized NHC ligands having methoxy, dimethylamino, and pyridine as donor functions have been synthesized. The hemilabile fragment is coordinated to the iridium center in the cationic com...

Subject

Chemistry

Iridium

Cationic polymerization

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