An Explanation for the Very Large Breathing Effect of a Metal–Organic Framework during CO<sub>2</sub> Adsorption

Serre, Christian; Bourrelly, Sandrine; Vimont, Alexandré; A. Ramsahye, Naseem; Maurin, Guillaume; L. Llewellyn, Philip; Daturi, Marco; Filinchuk, Y.; Leynaud, Olivier; Barnes, P.; Férey, Gérard

doi:10.1002/adma.200602645

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An Explanation for the Very Large Breathing Effect of a Metal–Organic Framework during CO2 Adsorption

Published in Advanced Materials • Aug 2, 2007

Authors:

Christian Serre

Sandrine Bourrelly

Alexandré Vimont

Abstract

The unusual adsorption behavior of CO2 in a nanoporous hybrid metal– organic solid is discussed (see figure). The results indicate that the gas adsorption–desorption step is related to a breathing phenomenon. This study also suggests that the main interactions responsible for the breathing phenomeno...

Subject

Adsorption

Nanoporous

Metal-organic framework

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