Polyoxometalate-based metal organic frameworks (POMOFs): structural trends, energetics, and high electrocatalytic efficiency for hydrogen evolution reaction.

Nohra, Brigitte; El Moll, Hani; Marleny Rodriguez Albelo, L; Mialane, Pierre; Marrot, Jérôme; Mellot-Draznieks, Caroline; O'Keeffe, Michael; Ngo Biboum, Rosa; Lemaire, Joël; Keita, Bineta; Nadjo, Louis; Dolbecq, Anne

doi:10.1021/ja201165c

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Polyoxometalate-based metal organic frameworks (POMOFs): structural trends, energetics, and high electrocatalytic efficiency for hydrogen evolution reaction.

Shared by NobleBlocks on Aug 31, 2011 • 12:00 AM UTC

Authors:

Brigitte Nohra

Hani El Moll

L Marleny Rodriguez Albelo

Abstract

The grafting of the triangular 1,3,5-benzene tricarboxylate linkers (denoted trim) on tetrahedral ε-Keggin polyoxometalates (POMs) capped by Zn(II) ions, formed in situ under hydrothermal conditions, has generated three novel POM-based metal organic frameworks (POMOFs). (TBA)(3)[PMo(V)(8)Mo(VI)(4)O(...

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