Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction

Nohra, B.; El Moll, Hani; Albelo, L.M.R.; Mialane, Pierre; Marrot, Jérôme; Mellot‐Draznieks, Caroline; O’Keeffe, M.; Ngo Biboum, Rosa; Lemaire, Joël; Keita, Bineta; Nadjo, Louis; Dolbecq, Anne

doi:10.1021/ja201165c

Public

Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction

Published in Journal of the American Chemical Society • Jul 21, 2011

Authors:

B. Nohra

Hani El Moll

L.M.R. Albelo

Abstract

The grafting of the triangular 1,3,5-benzene tricarboxylate linkers (denoted trim) on tetrahedral ε-Keggin polyoxometalates (POMs) capped by Zn(II) ions, formed in situ under hydrothermal conditions, has generated three novel POM-based metal organic frameworks (POMOFs). (TBA)(3)[PMo(V)(8)Mo(VI)(4)O(...

Subject

Polyoxometalate

Chemistry

Trim

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