Electrochemical Behavior and Some Thermodynamic Properties of UCl[sub 4] and UCl[sub 3] Dissolved in a LiCl-KCl Eutectic Melt

А. Кузнецов, С.; Hayashi, Hirokazu; Minato, Kazuo; Gaune‐Escard, Marcelle

doi:10.1149/1.1864532

Public

Electrochemical Behavior and Some Thermodynamic Properties of UCl[sub 4] and UCl[sub 3] Dissolved in a LiCl-KCl Eutectic Melt

Published in Journal of The Electrochemical Society • Jan 1, 2005

Authors:

С. А. Кузнецов

Hirokazu Hayashi

Kazuo Minato

Abstract

The electrochemical behavior of and in LiCl-KCl eutectic melt was studied at 723-823 K by different electrochemical methods. Electroreduction of U(IV) in LiCl-KCl melt occurs via two successive steps involving transfer of one and three electrons. The diffusion coefficients of U(IV) and U(III) were d...

Subject

Chronoamperometry

Eutectic system

Electrochemistry

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