Infrared Spectroscopic Study of CH<sub>3</sub>···OC Interaction during Poly(<scp>l</scp>-lactide)/Poly(<scp>d</scp>-lactide) Stereocomplex Formation

Zhang, Jianming; Sato, Harumi; Tsuji, Hideto; Noda, Isao; Ozaki, Yukihiro

doi:10.1021/ma047872w

Public

Infrared Spectroscopic Study of CH3···OC Interaction during Poly(l-lactide)/Poly(d-lactide) Stereocomplex Formation

Published in Macromolecules • Feb 3, 2005

Authors:

Jianming Zhang

Harumi Sato

Hideto Tsuji

Abstract

The nature of the “peculiarly strong” interaction between the poly( l -lactide) (PLLA) and poly( d -lactide) (PDLA) chains was investigated by real time infrared spectroscopy during the isothermal melt crystallization process of the PLLA/PDLA stereocomplex. A very small low-frequency shift (about 1 ...

Subject

Lactide

Crystallization

Nucleation

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