N-Heterocyclic Carbene Ligands as Modulators of Luminescence in Three-Coordinate Gold(I) Complexes with Spectacular Quantum Yields

Visbal, Renso; Ospino, Isaura; M. López‐de‐Luzuriaga, José; Laguna, Antonio; Concepción Gimeno, M.

doi:10.1021/ja401523x

Public

N-Heterocyclic Carbene Ligands as Modulators of Luminescence in Three-Coordinate Gold(I) Complexes with Spectacular Quantum Yields

Published in Journal of the American Chemical Society • Mar 13, 2013

Authors:

Renso Visbal

Isaura Ospino

José M. López‐de‐Luzuriaga

Abstract

The first three-coordinate gold(I) N-heterocyclic carbene (NHC) complexes have been prepared with the nido-carborane diphosphine. The complexes are brightly luminescent and present very high quantum yield values. The carbene ligand is able to modulate the energy of the emissions and, depending upon ...

Subject

Carbene

Chemistry

Phosphorescence

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