The rational construction and operation of an ideal helical spring has been investigated. The infinite helices, [Ag(Py 2 O)]X (Py 2 O = 3,3‘-oxybispyridine; X - = NO 3 -, BF 4 -, ClO 4 -, and PF 6 - ), have been constructed in high yield via cooperative effects of the skewed conformer of Py 2 O and ...
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