Photochromism, Electrical Properties, and Structural Investigations of a Series of Hydrated Methylviologen Halobismuthate Hybrids: Influence of the Anionic Oligomer Size and Iodide Doping on the Photoinduced Properties and on the Dehydration Process

Leblanc, Nicolas; Bi, Wenhua; Mercier, Nicolas; Auban‐Senzier, Pascale; Pasquier, Claude

doi:10.1021/ic901525p

Public

Photochromism, Electrical Properties, and Structural Investigations of a Series of Hydrated Methylviologen Halobismuthate Hybrids: Influence of the Anionic Oligomer Size and Iodide Doping on the Photoinduced Properties and on the Dehydration Process

Published in Inorganic Chemistry • Jun 1, 2010

Authors:

Nicolas Leblanc

Wenhua Bi

Nicolas Mercier

Abstract

Syntheses, X-ray structural analyses, thermal behaviors, photochromism, and electrical properties of a series of methylviologen (MV(2+)) halobismuthate hybrids, namely, (MV)(3)[Bi(4)Cl(18)](H(2)O)(y) (1a, y approximately = 1.7), (MV)(4)[Bi(6)Cl(26)](H(2)O)(y) (2a, y approximately = 1.7), (MV)(4)[Bi(...

Subject

Chemistry

Photochromism

Iodide

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