Abstract The photophysical and electron transfer properties of the lowest excited state of nine ruthenium (polypyridine) complexes have been characterized. The complexes studied are Ru (bpy) 3‐n (LL) 2+ n , where n varies from 0 to 3, and LL is 4, 4′‐di‐ t ‐butyl‐2,2′‐bipyridine (DTB‐bpy), 3, 3′‐dim...
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