Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

C. Remsing, Richard; P. Swatloski, Richard; D. Rogers, Robin; Moyna, Guillermo

doi:10.1039/b600586c

Public

Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

Published in Chemical Communications • Jan 1, 2006

Authors:

Richard C. Remsing

Richard P. Swatloski

Robin D. Rogers

Abstract

13C and 35/37Cl NMR relaxation measurements on several model systems demonstrate that the solvation of cellulose by the ionic liquid (IL) 1-n-butyl-3-methylimidazolium chloride ([C4mim]Cl) involves hydrogen-bonding between the carbohydrate hydroxyl protons and the IL chloride ions in a 1 ratio 1 sto...

Subject

Ionic liquid

C4mim

Chloride

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