New Evidence against Hydroxyl Radicals as Reactive Intermediates in the Thermal and Photochemically Enhanced Fenton Reactions

H. Bossmann, Stefan; Oliveros, Esther; Göb, Sabine; Siegwart, Silvia; P. Dahlen, Elizabeth; M. Payawan, Leon; Straub, Matthias; Wörner, Michael; M. Braun, André

doi:10.1021/jp980129j

Public

New Evidence against Hydroxyl Radicals as Reactive Intermediates in the Thermal and Photochemically Enhanced Fenton Reactions

Published in The Journal of Physical Chemistry A • Apr 17, 1998

Authors:

Stefan H. Bossmann

Esther Oliveros

Sabine Göb

Abstract

During the oxidative degradation of 2,4-dimethylaniline (2,4-xylidine) by means of the H 2 O 2 /UV method, a series of hydroxylated aromatic amines are formed, this result confirming the role of the hydroxyl radical as an initiator of the oxidative chain reaction. Thermal or photochemically enhanced...

Subject

Chemistry

Radical

Photochemistry

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