Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption

Wu, Hui; Shen Chua, Yong; Krungleviciute, Vaiva; Tyagi, Madhusudan; Chen, Ping; Yildirim, Taner; Zhou, Wei

doi:10.1021/ja404514r

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Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption

Published in Journal of the American Chemical Society • Jun 28, 2013

Authors:

Hui Wu

Yong Shen Chua

Vaiva Krungleviciute

Abstract

UiO-66 is a highly important prototypical zirconium metal-organic framework (MOF) compound because of its excellent stabilities not typically found in common porous MOFs. In its perfect crystal structure, each Zr metal center is fully coordinated by 12 organic linkers to form a highly connected fram...

Subject

Linker

Chemistry

Metal-organic framework

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