The magnetic transitions in ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}$ ($x=0.25, 0.50$) were studied by synchrotron x-ray and neutron powder diffraction. For $x=0.25$ the large $\ensuremath{\Delta}V=0.13%$ at ${T}_{C}$ is due to the simultaneous insulator-to-metal...
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