High-resolution core- and valence-level photoemission spectra of Nb-doped ${\mathrm{TiO}}_{2}$ ceramics $({\mathrm{Ti}}_{1\ensuremath{-}x}{\mathrm{Nb}}_{x}{\mathrm{O}}_{2}$ with $0.01<x<0.8)$ have been measured using monochromatic x-ray excitation. Nb doping produces a well-defined photoemission pea...
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