Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster

Perruchas, Sandrine; Le Goff, X.F.; Maron, Sébastien; Maurin, Isabelle; Guillen, F.; Garcia, Alain; Gacoin, Thierry; Boilot, Jean‐Pierre

doi:10.1021/ja103431d

Public

Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster

Published in Journal of the American Chemical Society • Jul 26, 2010

Authors:

Sandrine Perruchas

X.F. Le Goff

Sébastien Maron

Abstract

The mechanochromic and thermochromic luminescence properties of a molecular copper(I) iodide cluster formulated [Cu(4)I(4)(PPh(2)(CH(2)CH=CH(2)))(4)] are reported. Upon mechanical grinding in a mortar, its solid-state emission properties are drastically modified as well as its thermochromic behavior...

Subject

Thermochromism

Chemistry

Luminescence

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