Beta-diketiminate-stabilized magnesium(I) dimers and magnesium(II) hydride complexes: synthesis, characterization, adduct formation, and reactivity studies.

SJ, Bonyhady; C, Jones; S, Nembenna; A, Stasch; AJ, Edwards; GJ, McIntyre

doi:10.1002/chem.200902425

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Beta-diketiminate-stabilized magnesium(I) dimers and magnesium(II) hydride complexes: synthesis, characterization, adduct formation, and reactivity studies.

Shared by NobleBlocks on Jan 1, 2010 • 12:00 AM UTC

Authors:

Bonyhady SJ

Jones C

Nembenna S

Abstract

The preparation and characterization of a series of magnesium(II) iodide complexes incorporating beta-diketiminate ligands of varying steric bulk and denticity, namely, [(ArNCMe)(2)CH](-) (Ar=phenyl, ((Ph)Nacnac), mesityl ((Mes)Nacnac), or 2,6-diisopropylphenyl (Dipp, (Dipp)Nacnac)), [(DippNCtBu)(2)...

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