A unique copper-catalyzed cross-coupling reaction by hydrogen (H 2 ) removal for the stereoselective synthesis of 3-phosphoindoles

Zhou, An‐Xi; Mao, Liu‐Liang; Wang, Gang‐Wei; Yang, Shang‐Dong

doi:10.1039/c4cc01815j

Public

A unique copper-catalyzed cross-coupling reaction by hydrogen (H 2 ) removal for the stereoselective synthesis of 3-phosphoindoles

Published in Chemical Communications • Jan 1, 2014

Authors:

An‐Xi Zhou

Liu‐Liang Mao

Gang‐Wei Wang

Abstract

The first Cu(i)-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H2) ...

Subject

Stereoselectivity

Catalysis

Copper

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