Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX<sub>3</sub> Architecture

K. Jain, Prashant; Ramachandran, V.; J. Clark, Ronald; Zhou, Haidong; H. Toby, Brian; S. Dalal, Naresh; W. Kroto, Harold; K. Cheetham, Anthony

doi:10.1021/ja904156s

Public

Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture

Published in Journal of the American Chemical Society • Sep 2, 2009

Authors:

Prashant K. Jain

V. Ramachandran

Ronald J. Clark

Abstract

Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH(3))(2)NH(2)]M(HCOO)(3), where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K...

Subject

Multiferroics

Chemistry

Perovskite (structure)

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