Poly-2,3- and 2,7-Bicyclo[2.2.1]hept-2-enes: Preparation and Structures of Polynorbornenes

G. Gaylord, Norman; B. Deshpande, Achyut; M. Mandal, Broja; Martan, Michael

doi:10.1080/00222337708061307

Public

Poly-2,3- and 2,7-Bicyclo[2.2.1]hept-2-enes: Preparation and Structures of Polynorbornenes

Published in Journal of Macromolecular Science Part A - Chemistry • May 1, 1977

Authors:

Norman G. Gaylord

Achyut B. Deshpande

Broja M. Mandal

Abstract

The polymerization of norbornene in the presence of either radical catalysts having a short half-life at the polymerization temperature or ethylaluminum dichloride yields a saturated polymer having a rearranged structure with 2,7 linkages. Polymerization in the presence of either Pd(C6H5CN)2Cl2 or Z...

Subject

Norbornene

Polymerization

Polymer

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