Time-resolved photoelectron imaging of large anionic methanol clusters: (Methanol)n−(n∼145–535)

The dynamics of an excess electron in size-selected methanol clusters is studied via pump-probe spectroscopy with resolution of approximately 120 fs. Following excitation, the excess electron undergoes internal conversion back to the ground state with lifetimes of 260-175 fs in (CH3OH)n- (n=145-535)... View More