Crystal field splitting of rovibrational transitions of water monomers isolated in solid parahydrogen

E. Fajardo, Mario; Michael Lindsay, C.

doi:10.1063/1.2816705

Public

Crystal field splitting of rovibrational transitions of water monomers isolated in solid parahydrogen

Published in The Journal of Chemical Physics • Jan 4, 2008

Authors:

Mario E. Fajardo

C. Michael Lindsay

Abstract

We report polarized infrared absorption spectra of water isotopologues isolated in solid parahydrogen (pH2) which reveal the crystal field induced splittings of the 1 01<--0 00 R(0) lines in the nu1 HDO, nu3 D2O, nu3 HDO, and nu3 H2O fundamental bands. For annealed pH2 solids, these spectra also rev...

Subject

Spin isomers of hydrogen

Spectral line

Solid hydrogen

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