Palladium Complexes of N‐Heterocyclic Carbenes as Catalysts for Cross‐Coupling Reactions—A Synthetic Chemist's Perspective

Assen B. Kantchev, Eric; J. O’Brien, Christopher; G. Organ, Michael

doi:10.1002/anie.200601663

Public

Palladium Complexes of N‐Heterocyclic Carbenes as Catalysts for Cross‐Coupling Reactions—A Synthetic Chemist's Perspective

Published in Angewandte Chemie International Edition • Apr 5, 2007

Authors:

Eric Assen B. Kantchev

Christopher J. O’Brien

Michael G. Organ

Abstract

Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popularity as ligands in Pd-mediated cross-coupling and related transformations because of their superior ...

Subject

Palladium

Catalysis

Steric effects

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