Enantioselective Chromatographic Resolution and One-Pot Synthesis of Enantiomerically Pure Sulfoxides over a Homochiral Zn−Organic Framework

L. Nuzhdin, Alexey; N. Dybtsev, Danil; P. Bryliakov, Konstantin; P. Talsi, Evgenii; P. Fedin, Vladimir

doi:10.1021/ja076276p

Public

Enantioselective Chromatographic Resolution and One-Pot Synthesis of Enantiomerically Pure Sulfoxides over a Homochiral Zn−Organic Framework

Published in Journal of the American Chemical Society • Oct 1, 2007

Authors:

Alexey L. Nuzhdin

Danil N. Dybtsev

Konstantin P. Bryliakov

Abstract

( R )- and ( S )- enantiomers of alkyl aryl sulfoxides can be obtained by chromatographic resolution of the racemic mixtures of the sulfoxides on a microporous homochiral Zn-organic polymer or by simultaneous catalytic oxidation of the corresponding sulfides with H 2 O 2 and enantioselective chromat...

Subject

Chemistry

Enantioselective synthesis

Microporous material

Finding related papers...

Discussions

(0)

No comments yet

Be the first to share your thoughts!