Unambiguous Identification of Möbius Aromaticity for<i>meso</i>-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1)

Sankar, Jeyaraman; Mori, Shigeki; Saito, Shohei; Rath, Harapriya; Suzuki, Masaaki; Inokuma, Yasuhide; Shinokubo, Hiroshi; Suk Kim, Kil; Seok Yoon, Zin; Shin, Jae‐Yoon; Min Lim, Jong; Matsuzaki, Yoichi; Matsushita, Osamu; Muranaka, Atsuya; Kobayashi, Nagao; Kim, Dongho; Osuka, Atsuhiro

doi:10.1021/ja801983d

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Unambiguous Identification of Möbius Aromaticity formeso-Aryl-Substituted [28]Hexaphyrins(1.1.1.1.1.1)

Published in Journal of the American Chemical Society • Sep 23, 2008

Authors:

Jeyaraman Sankar

Shigeki Mori

Shohei Saito

Abstract

meso-Aryl-substituted [28]hexaphyrins(1.1.1.1.1.1) have been examined by (1)H, (13)C, and (19)F NMR spectroscopies, UV-vis absorption spectroscopy, magnetic circular dichroism spectroscopy, and single-crystal X-ray diffraction analysis. All of these data consistently indicate that [28]hexaphyrins(1....

Subject

Chemistry

Antiaromaticity

Aromaticity

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