The spin state of a molecular adsorbate driven by the ferroelectric substrate polarization

Zhang, Xin; Palamarciuc, Tatiana; Létard, Jean‐François; Rosa, Patrick; Vega Lozada, Eduardo; Torres, Fernand; G. Rosa, Luis; Doudin, Bernard; A. Dowben, Peter

doi:10.1039/c3cc46892e

Public

The spin state of a molecular adsorbate driven by the ferroelectric substrate polarization

Published in Chemical Communications • Dec 3, 2013

Authors:

Xin Zhang

Tatiana Palamarciuc

Jean‐François Létard

Abstract

The spin state of [Fe(H2B(pz)2)2(bipy)] thin films is mediated by changes in the electric field at the interface of organic ferroelectric polyvinylidene fluoride with trifluoroethylene (PVDF-TrFE). Signatures of the molecular crossover transition are evident in changes in the unoccupied states and t...

Subject

Diamagnetism

Ferroelectricity

Spin crossover

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