The spin state of a molecular adsorbate driven by the ferroelectric substrate polarization.

Zhang, Xin; Palamarciuc, Tatiana; Létard, Jean-François; Rosa, Patrick; Vega Lozada, Eduardo; Torres, Fernand; G Rosa, Luis; Doudin, Bernard; A Dowben, Peter

doi:10.1039/c3cc46892e

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The spin state of a molecular adsorbate driven by the ferroelectric substrate polarization.

Shared by NobleBlocks on Mar 4, 2014 • 12:00 AM UTC

Authors:

Xin Zhang

Tatiana Palamarciuc

Jean-François Létard

Abstract

The spin state of [Fe(H2B(pz)2)2(bipy)] thin films is mediated by changes in the electric field at the interface of organic ferroelectric polyvinylidene fluoride with trifluoroethylene (PVDF-TrFE). Signatures of the molecular crossover transition are evident in changes in the unoccupied states and t...

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