The Benzophenone S<sub>1</sub>(n,π*) → T<sub>1</sub>(n,π*) States Intersystem Crossing Reinvestigated by Ultrafast Absorption Spectroscopy and Multivariate Curve Resolution

Aloïse, Stéphane; Ruckebusch, Cyril; Blanchet, Lionel; Réhault, Julien; Buntinx, G.; Huvenne, Jean‐Pierre

doi:10.1021/jp075829f

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The Benzophenone S1(n,π) → T1(n,π) States Intersystem Crossing Reinvestigated by Ultrafast Absorption Spectroscopy and Multivariate Curve Resolution

Published in The Journal of Physical Chemistry A • Dec 22, 2007

Authors:

Stéphane Aloïse

Cyril Ruckebusch

Lionel Blanchet

Abstract

The well-known benzophenone intersystem crossing from S(1)(n,pi*) to T(1)(n,pi*) states, for which direct transition is forbidden by El-Sayed rules, is reinvestigated by subpicosecond time-resolved absorption spectroscopy and effective data analysis for various excitation wavelengths and solvents. M...

Subject

Intersystem crossing

Chemistry

Benzophenone

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