Physical Properties and Cation Arrangement of Oxides with Spinel Structures I. Cation Arrangement in Spinels

J. W. Verwey, E.; L. Heilmann, E.

doi:10.1063/1.1746464

Public

Physical Properties and Cation Arrangement of Oxides with Spinel Structures I. Cation Arrangement in Spinels

Published in The Journal of Chemical Physics • Apr 1, 1947

Authors:

E. J. W. Verwey

E. L. Heilmann

Abstract

By means of a detailed x-ray study of a large number of oxides having a spinel structure, it has been established whether they crystallize in the ``normal'' spinel-type structure, XY2O4, or in the ``inversed'' type of structure, Y(XY)O4, discovered by Barth and Posnjak. Certain rules can be derived ...

Subject

Spinel

Ionic bonding

Chemical bond

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