Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake

Ma, Shengqian; Sun, Daofeng; M. Simmons, Jason; D. Collier, Christopher; Yuan, Daqiang; Zhou, Hong‐Cai

doi:10.1021/ja0771639

Public

Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake

Published in Journal of the American Chemical Society • Dec 29, 2007

Authors:

Shengqian Ma

Daofeng Sun

Jason M. Simmons

Abstract

A microporous metal-organic framework, PCN-14, based on an anthracene derivative, 5,5'-(9,10-anthracenediyl)di-isophthalate (H4adip), was synthesized under solvothermal reaction conditions. X-ray single crystal analysis revealed that PCN-14 consists of nanoscopic cages suitable for gas storage. N2-a...

Subject

Chemistry

Methane

Anthracene

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