A Zr metal–organic framework based on tetrakis(4-carboxyphenyl) silane and factors affecting the hydrothermal stability of Zr-MOFs

Wang, Shufen; Wang, Jingjing; Cheng, Weiwei; Yang, Xiaowei; Zhang, Zaiyong; Xu, Yan; Liu, Hong‐Ke; Jun Wu, Yong; Fang, Min

doi:10.1039/c5dt00421g

Public

A Zr metal–organic framework based on tetrakis(4-carboxyphenyl) silane and factors affecting the hydrothermal stability of Zr-MOFs

Published in Dalton Transactions • Jan 1, 2015

Authors:

Shufen Wang

Jingjing Wang

Weiwei Cheng

Abstract

A new (4,8)-connected Zr-MOF porous zirconium metal-organic framework (Zr-MOF) with flu topology, Zr6(μ3-O)4(μ3-OH)4(TCPS)2(H2O)4(OH)4 (, TCPS = tetrakis(4-carboxyphenyl) silane) with a BET specific area of 1402 m(2) g(-1) has been constructed and fully characterized. is stable in air and acid media...

Subject

Hydrothermal circulation

Silane

Metal-organic framework

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