Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra

Furukawa, Hiroyasu; Kim, Jaheon; Ockwig, N.W.; O’Keeffe, M.; M. Yaghi, Omar

doi:10.1021/ja803783c

Public

Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra

Published in Journal of the American Chemical Society • Aug 9, 2008

Authors:

Hiroyasu Furukawa

Jaheon Kim

N.W. Ockwig

Abstract

Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M2(CO2)4 (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and cr...

Subject

Polyhedron

Chemistry

Metal-organic framework

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